Voronkovite Explained

Voronkovite
Category:Silicate mineral, Cyclosilicate
Formula: (original form)
Imasymbol:Vrk[1]
Strunz:9.CO.10
System:Trigonal
Class:Pyramidal (3)
H-M symbol: (3)
Symmetry:R3
Unit Cell:a = 14.21, c = 30.27 [Å]; Z = 3
Color:Light brown
Habit:Rounded crystals
Fracture:Conchoidal
Tenacity:Brittle
Mohs:5
Luster:Vitreous
Streak:White
Diaphaneity:Transparent
Density:2.95 g/cm3 (calculated)
Opticalprop:Uniaxial (+)
Pleochroism:Lemon yellow (X), brownish pink (Y)

Voronkovite is a very rare mineral[2] of the eudialyte group with the chemical formula .[3] The formula is based on the simplified original one; it does not show the presence of cyclic silicate groups, but two M3- and M4-site silicon atoms are shown separately (basing on the nomenclature of the eudialyte group[4]). Voronkovite has lowered symmetry (space group R3, instead of more specific for the group R3m one), similarly to some other eudialyte-group members: aqualite, labyrinthite, oneillite and raslakite. The specific feature of voronkovite is, among others, strong enrichment in sodium.

Occurrence and association

Voronkovite comes from an ultra-alkaline pegmatite of Mt. Alluaiv, Lovozero Massif, Kola Peninsula, Russia. It occurs with aegirine, lomonosovite, manganoneptunite, microcline, nepheline, shkatulkalite, sodalite, terskite, sphalerite and vuonnemite.

Notes on chemistry

Voronkovite has additional impurities, not given in the formula. They include strontium, fluorine, potassium, lanthanum, neodymium (at the Mn site), niobium, and minor hafnium and aluminium.

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Mindat, Voronkovite, http://www.mindat.org/min-32199.html
  3. Khomyakov, A.P., Nechelyustov, G.N., and Rastsvetaeva, R.K., 2010, Voronkovite,, a new mineral species of the eudialyte group from the Lovozero alkaline pluton, Kola Peninsula, Russia. Geology of Ore Deposits 51(8), 750–756
  4. Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794