Vanadiocarpholite Explained

Vanadiocarpholite
Category:Silicate mineral
Formula:Mn+2V+3AlSi2O6(OH)4
Imasymbol:Vcar[1]
Strunz:9.DB.05
System:Orthorhombic
Class:Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Symmetry:Ccca
Unit Cell:a = 13.83 Å, b = 20.681 Å
c = 5.188 Å; Z = 8
Color:Pale-straw yellow, honey-yellow to brown
Habit:Prismatic to acicular crystal clusters, vein fillings
Cleavage:Perfect on
Tenacity:Flexible
Luster:Vitreous, silky
Diaphaneity:Transparent
Opticalprop:Biaxial (+)
Refractive:nα=1.684, nβ=1.691, nγ=1.7
Birefringence:0.0160
References:[2] [3]

Vanadiocarpholite (Mn+2V+3AlSi2O6(OH)4) is straw yellow to brown silicate mineral. It crystallizes in the orthorhombic crystal system. It is the vanadium rich variety of carpholite (Mn+2Al2Si2O6(OH)4).

Discovery and occurrence

It was first described in 2005 for an occurrence in the Molinello Mine, Graveglia Valley, Genova Province, Liguria, Italy.[3] It occurs in chert in a manganese ore deposit as vein fillings in silicified wood.[2]

Chemical composition

It consists of:[2]

Manganese15.56%Mn20.09%MnO
Aluminium7.64%Al14.44%Al2O3
Vanadium14.43%V21.23%V2O3
Silicon15.91%Si34.04%SiO2
Hydrogen1.14%H10.21%H2O
Oxygen45.32%O

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://www.webmineral.com/data/Vanadiocarpholite.shtml Vanadiocarpholite data on Webmineral.com
  3. http://www.mindat.org/min-26774.html Vanadiocarpholite on Mindat.org