Fluocerite Explained

Fluocerite-(La)
Formula:(La,Ce)F3
Molweight:196.02
Strunz:03.AC.15 (03)
Dana:09.03.04.02 (09)
System:Trigonal
Class:Hexagonal scalenohedral
Symmetry:Pc1 (No. 165)
Unit Cell:328.80 ų (Calculated from Unit Cell)
Colour:Greenish-yellow
Habit:Platy, tabular
Cleavage:Indistinct, Imperfect
Mohs:4-5
Luster:Vitreous
Streak:White
Diaphaneity:Transparent to translucent
Density:5.93
Birefringence:0.006
Fluocerite-(Ce)
Formula:(La,Ce)F3
Molweight:196.99
Strunz:3/A.10-20
Dana:9.3.4.1
System:Trigonal
Class:Hexagonal Scalenohedral
Unit Cell:320.86 ų (Calculated from Unit Cell)
Colour:Light yellow; darkening to yellow- and red-brown; colourless to pale pink (transmitted light)
Habit:Massive, Primsatic
Cleavage:Distinct/Good
Fracture:Irregular/Uneven, Splintery, Sub-Conchoidal
Tenacity:Brittle
Mohs:4.5-5
Luster:Vitreous, Resinous, Pearly
Streak:Yellow-white
Diaphaneity:Transparent to translucent
Gravity:5.93 - 6.14
Density:5.93 - 6.14 g/cm3 (Measured)
Birefringence:0.005 - 0.007

Fluocerite, also known as tysonite, is a mineral consisting of cerium and lanthanum fluorides, with the chemical formula .[1] [2] The end members are classified as two different mineral types depending on the cation, fluocerite-(Ce) and fluocerite-(La), corresponding respectively to lanthanum trifluoride and cerium trifluoride. Both crystallize in the trigonal system.[3]

Fluocerite-(Ce) was first described (without the Ce) in 1845 from hydrothermal veins in granite in Sweden.[4] Fluocerite-(La) was first described in 1969 from the type locality in central Kazakhstan. The name tysonite was given in 1880 to the same type of mineral found in Colorado.[5] [6] Tysonite-type structure is used for rare-earth fluorides with the P3c1 space group structure.[7]

References

  1. Web site: Fluocerite-(La) Mineral Data. 2021-02-12. webmineral.com.
  2. Web site: Fluocerite-(Ce) Mineral Data. 2021-02-12. webmineral.com.
  3. Web site: Fluocerite-(La). 2021-02-12. www.mindat.org.
  4. Web site: Fluocerite-(Ce). 2021-02-12. www.mindat.org.
  5. Geijer. Per. 1921-01-01. On Fluocerite and Tysonite. Geologiska Föreningen i Stockholm Förhandlingar. 43. 1–2. 19–23. 10.1080/11035892109443886. 0016-786X.
  6. Allen, Oscar D., and W. J. Comstock. "Bastnaesite and tysonite from Colorado." American Journal of Science 3.113 (1880): 390-393.
  7. Book: Dudney. Nancy J.. Handbook Of Solid State Batteries. West. William C.. Nanda. Jagjit. 2015-07-09. World Scientific. 978-981-4651-91-2. en. Second.