Trimethylhexamethylenediamine Explained

Trimethylhexamethylenediamine is the name used to refer to a mixture of two isomers of trimethyl-1,6-hexanediamine.The mixture is used as a monomer in nylon TMDT. It is available commercially under the trade name Vestamin TMD from the company Evonik Industries.

Trimethylhexamethylenediamine is synthesized from isophorone.[1] Isophorone is reduced by hydrogenation to the trimethylcyclohexanol, which is then oxidized with nitric acid (in the same fashion as adipic acid is synthesized from cyclohexane). The diacid, again a mixture of two "trimethyladipic acids", is converted to the diamine via the dinitrile.[2]

Uses

TMD is used as a component in certain curing agents for epoxy resins.[3]

Notes and References

  1. Encyclopedia: Hardo Siegel . Manfred Eggersdorfer . Ketones. Ullmann's Encyclopedia of Industrial Chemistry. 2005. Wiley-VCH. Weinheim. 10.1002/14356007.a15_077. 978-3-527-30673-2.
  2. Book: U. Rohde-Liebenau. Kohan. Melvin. Nylon Plastics Handbook. 1995. Hanser. Munich. 1-56990-189-9. 570. 13.10 PA-TMDT.
  3. Web site: Vestamin TMD.