Topaquinone Explained

Topaquinone (TPQ) is a redox cofactor derived from the amino acid tyrosine. Its name derives from 2,4,5-trihydroxyphenylalanine-quinone. Its structure was first identified in 1990.[1] It is used by copper amine oxidases which contain a tyrosine residue near the active site. This residue catalyses its own transition, first to dopaquinone and then to topaquinone, in a Cu2+ dependent manner.

References

  1. Structure and biogenesis of topaquinone and related cofactors . Journal of Biological Inorganic Chemistry . Feb 1999. 0949-8257. 10499097. 1–11. 4. 1. D. M.. Dooley. 10.1007/s007750050283 . 10104769 .