Tlapallite Explained

Tlapallite
Category:Tellurate minerals
Imasymbol:Tpl[1]
Strunz:4.JL.25
Dana:34.8.2.1
System:Monoclinic
P3 2 1
Unit Cell:a = 11.97 Å, b = 9.11 Å
c = 15.66 Å; Z = 4
Color:Green
Habit:Thin crusts or botryoidal aggregates
Cleavage:None
Mohs:3
Luster:Vitreous, Waxy
Streak:Pale green
Diaphaneity:Translucent
Gravity:5.38 (measured)5.05–5.465 (calculated)
Opticalprop:Biaxial (−)
Refractive:nα = 1.815 – 1.915 nβ = 1.960 – 2.115 nγ = 1.960 – 2.115
Birefringence:δ = 0.1450–0.2000
Pleochroism:Moderate, different shades of green
2V:0
Fluorescence:None
Fusibility:Fuses readily
Diagnostic:Thin green paint-like crusts
Solubility:Soluble in cold HCl
Slightly soluble in HNO3 unless heated

Tlapallite is a rare and complex tellurate mineral with the chemical formula . It has a Moh's hardness of 3 and it is green in colour. It was named after the Nahua word "Tlalpalli", which translates to paint, referring to the paint-like habit of the mineral. Its formula and crystal structure were redefined in 2019, showing it contained a mixed-valence phyllotellurate layer .[2]

Occurrence

It was discovered in 1972 the Bambollita mine (La Oriental), Moctezuma, Municipio de Moctezuma, Sonora, Mexico, a mine known for its tellurium deposits, and it was approved by the IMA in 1977. Here, it is found as thin paint-like crusts on rock fractures and next to thin veins running through rhyolite. It is often found as a thin film on quartz, sericite, calcite or baryte, but it also forms botryoidal aggregates. It is often found alone, but may be associated with other minerals, especially carlfriesite.[3] It has also been found in the emerald mine in Tombstone DistrictCochise County, Arizona in the United States.[4] [5] [6]

The habit of the mineral suggests it precipitates from rapidly drying acid solutions. It seems to form in the transitory phase when other tellurium minerals, like tlalocite, cesbronite, xocomecatlite, quetzalcoatlite, teineite and carlfriesite, start to break down.

See also

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Missen. Owen P.. Kampf. Anthony R.. Mills. Stuart J.. Housley. Robert M.. Spratt. John. Welch. Mark D.. Coolbaugh. Mark F.. Marty. Joe. Chorazewicz. Marek. Ferraris. Cristiano. 2019. The crystal structures of the mixed-valence tellurium oxysalts tlapallite.,, and carlfriesite, The crystal structures of the mixed-valence tellurium oxysalts tlapallite, (Ca,Pb)3CaCu6[Te4+3Te6+O12]2(Te4+O3)2(SO4)2·3H2O, and carlfriesite, CaTe4+2Te6+O8. Mineralogical Magazine. en. 83. 4. 539–549. 10.1180/mgm.2019.9. 135390072. 0026-461X. 2019. Missen. Owen P.. Kampf. Anthony R.. Mills. Stuart J.. Housley. Robert M.. Spratt. John. Welch. Mark D.. Coolbaugh. Mark F.. Marty. Joe. Chorazewicz. Marek. Ferraris. Cristiano. 2019MinM...83..539M.
  3. S.A. Williams and Marjorie Duggan. June 1978. Tlapallite, a new mineral from Moctezuma, Sonora, Mexico. Mineralogical Magazine. 42. 322. 183–186. 10.1180/minmag.1978.042.322.03. 1978MinM...42..183W. 10.1.1.615.5877. 53411207 .
  4. Web site: Tlapallite: Tlapallite mineral information and data.. www.mindat.org. 2016-09-15.
  5. Web site: Tlapallite Mineral Data. Barthelmy. Dave. www.webmineral.com. 2016-09-15.
  6. Web site: Handbook of Mineralogy.