Thulium-170 Explained

Thulium-170
Symbol:Tm
Mass Number:170
Num Protons:69
Num Neutrons:101
Abundance:Synthetic
Spin:1
Decay Product:Ytterbium-170
Decay Mass:170
Decay Symbol:Yb
Decay Product2:Erbium-170
Decay Mass2:170
Decay Symbol2:Er
Decay Mode1:β
Decay Energy1:0.8838, 0.9686
Decay Mode2:EC
Decay Energy2:0.2341, 0.3122

Thulium-170 (170Tm or Tm-170) is a radioactive isotope of thulium proposed for use in radiotherapy and in radioisotope thermoelectric generators.

Properties

Thulium-170 has a binding energy of per nucleon and a half-life of . It decays by β decay to 170Yb about 99.869% of the time, and by electron capture to 170Er about 0.131% of the time. About 18.1% of β decays populate a narrow excited state of 170Yb at, and this is the main X-ray emission from 170Tm; lower bands are also produced through X-ray fluorescence at 7.42, 51.354, 52.389, 59.159, 59.383, and 60.962 keV.

The ground state of thulium-170 has a spin of 1. The charge radius is, the magnetic moment is, and the electric quadrupole moment is .[1]

Proposed applications

As a rare-earth element, thulium-170 can be used as the pure metal or thulium hydride, but most commonly thulium oxide due to the refractory properties of that compound. The isotope can be prepared in a medium-strength reactor by neutron irradiation of natural thulium, which has a high neutron capture cross section of .

Medicine

In 1953, the Atomic Energy Research Establishment introduced thulium-170 as a candidate for radiography in medical and steelmaking contexts,[2] but this was deemed unsuitable due to the predominant high-energy bremsstrahlung radiation, poor results on thin specimens, and long exposure times. However, 170Tm has been proposed for radiotherapy because the isotope is simple to prepare into a biocompatible form, and the low-energy radiation can selectively irradiate diseased tissue without causing collateral damage.

Radiothermal generator

As the oxide, thulium-170 has been proposed as a radiothermal source due to it being safer, cheaper, and more environmentally friendly than commonly used isotopes such as plutonium-238.[3] The heat output from a 170Tm source is initially much greater than from a 238Pu source relative to mass, but it declines rapidly due to its shorter half-life.

Notes and References

  1. Web site: Mertzimekis . Theo J. . NUMOR Nuclear Moments and Radii University of Athens since 2007 . magneticmoments.info . 12 November 2023.
  2. Hilbish . Theodore F. . Developments in diagnostic radiology . Public Health Reports . November 1954 . 69 . 11 . 1017–1027 . 10.2307/4588947 . 4588947 . 13215708 . 2024396 . 0094-6214.
  3. Book: Alderman . Carol J. . AIP Conference Proceedings . Thulium heat sources for space power application . 1993 . 271 . 1085–1091 . 10.1063/1.43194.