Terphenylquinones Explained

Terphenylquinones are fungal dyes from the group of phenyl-substituted p-benzoquinones having the following general structure.

General chemical structure of terphenylquinones
Also derivatives with a central o-benzoquinone structure are known.

Biosynthesis

The biosynthesis of terphenylquinones is carried out by dimerization of substituted oxophenylpropanoic acids (phenylpyruvic acids).

Occurrence

Terphenylquinones are typical constituents of the Boletales.

Examples

NameStructureCAS-Nr.Origin
Polyporic acid548-59-4Polypore of the order Aphyllophorales, lichen Yarrumia coronata
Atromentin519-67-5Paxillus atrotomentosus (Basidiomycota)
Aurantiacin548-32-3Hydnellum aurantiacum (Basidiomycota)
Phlebiarubron7204-23-1Cultures of Phlebia strigosozonata and Punctularia atropurpurascens (Basidiomycota)
Spiromentin B121254-56-6Tapinella atrotomentosa (Basidiomycota) and cultures of Tapinella panuoides

See also