Arsenide telluride explained
Arsenide tellurides or telluride arsenides are compounds containing anions composed of telluride (Te2−) and arsenide (As3−). They can be considered as mixed anion compounds. Related compounds include the arsenide sulfides, arsenide selenides, antimonide tellurides, and phosphide tellurides. Some are in the category of arsenopyrite-type compounds with As:Te of 1:1. Yet others are layered with As:Te of 1:2.
Arsenide telluride compounds can be made by heating the elements together.
List
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|
| TiAsTe | orthorhombic | Immm | a = 3.5730 b = 5.249 c = 12.794 | | | @153K; n-type metallic | [1] |
| FeAsTe | | | | | | | [2] |
| Fe5AsTe2 | rhombohedral | Rm | a=4.065788 c=29.7408 | | | cleavable layered | [3] |
| As2.8Te5.12Zr3.88 | orthorhombic | Immm | a=5.64 b=13.37 c=3.78 | 285 | 7.013 | Zr and Te deficient | [4] |
| zirconium arsenotelluride | Zr2.00As2.86Te0.92 | | | a = 3.82 c = 8.17 | | 7.14 | | [5] |
| ruthenium arsenide telluride | RuTeAs | monoclinic | | a=6.36 b=6.30 c=6.40 β=113.6° | | | natural mineral | [6] [7] |
| osmium arsenide telluride | OsAsTe | monoclinic | | a=6.37 b=6.31 c=6.42 β=113.1° | | | | [8] |
| ThAsTe | tetragonal | P4/nmm | a=4.260 c=8.812 Z=2 | | | metallic | [9] [10] |
| UAsTe | tetragonal | P4/nmm | a=4.167 c=8.764 | | | Curie temp 66K; metallic | |
| NpAsTe | tetragonal | P4/nmm | a=4.140 c=8.909 | | | Curie temp 25K | |
| PuAsTe | tetragonal | P4/nmm | | 165 | | Curie temp 125K | |
| AmAsTe | tetragonal | P4/nmm | a=4.238 c=9.087 | | | | | |
Notes and References
- Huang . Fu Qiang . Flaschenriem . Christine . Brazis . Paul . Kannewurf . Carl R. . Ibers . James A . 2003-05-01 . Synthesis, Structure, Electrical Properties, and Band Structure Calculations of TiAsTe . Inorganic Chemistry . en . 42 . 10 . 3194–3198 . 10.1021/ic020688b . 12739959 . 0020-1669.
- Banus . Mario D. . Lavine . Mary C. . September 1966 . High pressure synthesis of arsenopyrite-type ternary compounds . Materials Research Bulletin . en . 1 . 1 . 3–12 . 10.1016/0025-5408(66)90022-5.
- Verchenko . Valeriy Yu. . Stepanova . Anna V. . Bogach . Alexey V. . Mironov . Andrei V. . Shevelkov . Andrei V. . 2022-06-20 . Fe-Rich Ferromagnetic Cleavable Van der Waals Telluride Fe 5 AsTe 2 . Inorganic Chemistry . en . 61 . 24 . 9224–9230 . 10.1021/acs.inorgchem.2c00800 . 35658443 . 249395748 . 0020-1669.
- Mosset . A. . Jeannin . Y. . February 1972 . Sur un compose ternaire orthorhombique forme entre le zirconium, l'arsenic et le tellure . Journal of the Less Common Metals . fr . 26 . 2 . 285–292 . 10.1016/0022-5088(72)90048-3.
- Mosset . A. . Jeannin . Y. . June 1973 . Etude cristallographique de l'arsénotellurure de zirconium quadratique . Journal of Solid State Chemistry . fr . 7 . 2 . 124–131 . 10.1016/0022-4596(73)90144-8. 1973JSSCh...7..124M .
- Marchetto . Celina Maria Leite . 1990-08-01 . Platinum-group minerals in the O'Toole (Ni-Cu-Co) deposit, Brazil . Economic Geology . en . 85 . 5 . 921–927 . 10.2113/gsecongeo.85.5.921 . 1990EcGeo..85..921M . 1554-0774.
- Hulliger . F. . January 1964 . New Semiconducting Arsenopyrite-type Compounds . Nature . en . 201 . 4917 . 381–382 . 10.1038/201381a0 . 1964Natur.201..381H . 4278049 . 0028-0836.
- Book: Chukanov . Nikita V. . Infrared Spectroscopy of Minerals and Related Compounds . Chervonnyi . Alexandr D. . 2016-03-09 . Springer . 978-3-319-25349-7 . 1030 . en.
- Book: Kaczorowski, D. . Pnictides And Chalcogenides Iii: Ternary Actinide Pnictides And Chalcogenides.
- Hulliger . F. . New ternary thorium and uranium compounds MYX . Journal of the Less Common Metals . October 1968 . 16 . 2 . 113–117 . 10.1016/0022-5088(68)90068-4.
