Spertiniite Explained

Spertiniite
Category:Oxide mineral
Formula:Cu(OH)2
Imasymbol:Sni[1]
Molweight:97.56 g/mol
Strunz:4.FD.05
Dana:6.2.4.1
System:Orthorhombic
Class:Pyramidal (mm2)
H-M symbol: (mm2)
Symmetry:Cmc21
Unit Cell:a = 2.95 Å, b = 10.59 Å
c = 5.27 Å; Z = 4
Color:Blue, blue-green
Habit:Flat tabular crystals occurring in radial to botryoidal aggregates
Cleavage:None
Tenacity:Brittle
Mohs:Soft
Luster:Vitreous
Diaphaneity:Transparent
Gravity:3.93
Opticalprop:Biaxial
Refractive:nα = 1.720, nβ= n.d., nγ = > 1.800
Pleochroism:Strong; X = colorless; Z = dark blue
Other:Decomposes in hot water (synthetic)
References:[2] [3] [4]

Spertiniite is a rare copper hydroxide mineral. Chemically, it is copper(II) hydroxide with the formula Cu(OH)2. It occurs as blue to blue-green tabular orthorhombic crystal aggregates in a secondary alkaline environment altering chalcocite. Associated minerals include chalcocite, atacamite, native copper, diopside, grossular, and vesuvianite.[3]

Discovery and occurrence

It was first described in 1981 for an occurrence in the Jeffrey quarry of the Johns-Manville mine, Asbestos, Estrie, Québec. It was named for mine geologist Francesco Spertini (born 1937).[2] [3] In addition to the type locality, it has also been reported from Mont Saint-Hilaire, Quebec; Ely, White Pine County, Nevada; and Bisbee, Cochise County, Arizona. It has been reported from Dzhezkazgan, Kazakhstan; from slag at Juliushutte, Astfeld, Harz Mountains, Germany; and from Tsumeb, Namibia.[3]

A 2006 study has produced evidence the blue mineral chrysocolla may be a microscopic mixture of spertiniite, amorphous silica and water.[5] [6]

Notes and References

  1. Warr. L. N. . 2021 . IMA–CNMNC approved mineral symbols . . 85 . 3 . 291–320 . 10.1180/mgm.2021.43 . 2021MinM...85..291W . 235729616 . free.
  2. https://.mindat.org/min-3724.html Spertiniite on Mindat
  3. https://rruff.geo.arizona.edu/doclib/hom/spertiniite.pdf Spertiniite
  4. https://webmineral.com/data/Spertiniite.shtml#.UFXq87IiZcg Spertiniite on Webmineral
  5. http://www.slac.stanford.edu/cgi-wrap/getdoc/slac-pub-12232.pdf François Farges, Karim Benzerara, Gordon E. Brown, Jr.; Chrysocolla Redefined as Spertiniite; SLAC-PUB-12232; 13th International Conference On X-Ray Absorption Fine Structure (XAFS13); July 9-14, 2006; Stanford, California
  6. http://www.mindat.org/min-1040.html Chrysocolla on Mindat