A spectrometer is a scientific instrument used to separate and measure spectral components of a physical phenomenon. Spectrometer is a broad term often used to describe instruments that measure a continuous variable of a phenomenon where the spectral components are somehow mixed. In visible light a spectrometer can separate white light and measure individual narrow bands of color, called a spectrum. A mass spectrometer measures the spectrum of the masses of the atoms or molecules present in a gas. The first spectrometers were used to split light into an array of separate colors. Spectrometers were developed in early studies of physics, astronomy, and chemistry. The capability of spectroscopy to determine chemical composition drove its advancement and continues to be one of its primary uses. Spectrometers are used in astronomy to analyze the chemical composition of stars and planets, and spectrometers gather data on the origin of the universe.
Examples of spectrometers are devices that separate particles, atoms, and molecules by their mass, momentum, or energy. These types of spectrometers are used in chemical analysis and particle physics.
See main article: Optical spectrometer.
Optical spectrometers (often simply called "spectrometers"), in particular, show the intensity of light as a function of wavelength or of frequency. The different wavelengths of light are separated by refraction in a prism or by diffraction by a diffraction grating. Ultraviolet–visible spectroscopy is an example.
These spectrometers utilize the phenomenon of optical dispersion. The light from a source can consist of a continuous spectrum, an emission spectrum (bright lines), or an absorption spectrum (dark lines). Because each element leaves its spectral signature in the pattern of lines observed, a spectral analysis can reveal the composition of the object being analyzed.[1]
A spectrometer that is calibrated for measurement of the incident optical power is called a spectroradiometer. [2]
Optical emission spectrometers (often called "OES or spark discharge spectrometers"), is used to evaluate metals to determine the chemical composition with very high accuracy. A spark is applied through a high voltage on the surface which vaporizes particles into a plasma. The particles and ions then emit radiation that is measured by detectors (photomultiplier tubes) at different characteristic wavelengths.
See main article: Electron spectroscopy. Some forms of spectroscopy involve analysis of electron energy rather than photon energy. X-ray photoelectron spectroscopy is an example.
See main article: Mass spectrometry. A mass spectrometer is an analytical instrument that is used to identify the amount and type of chemicals present in a sample by measuring the mass-to-charge ratio and abundance of gas-phase ions.[3]
The energy spectrum of particles of known mass can also be measured by determining the time of flight between two detectors (and hence, the velocity) in a time-of-flight spectrometer. Alternatively, if the particle-energy is known, masses can be determined in a time-of-flight mass spectrometer.
When a fast charged particle (charge q, mass m) enters a constant magnetic field B at right angles, it is deflected into a circular path of radius r, due to the Lorentz force. The momentum p of the particle is then given by
p=mv=qBr
Since Danysz' time, many types of magnetic spectrometers more complicated than the semicircular type have been devised.
Generally, the resolution of an instrument tells us how well two close-lying energies (or wavelengths, or frequencies, or masses) can be resolved. Generally, for an instrument with mechanical slits, higher resolution will mean lower intensity.