Solid-state electrolyte explained

A solid-state electrolyte (SSE) is a solid ionic conductor and electron-insulating material and it is the characteristic component of the solid-state battery. It is useful for applications in electrical energy storage (EES) in substitution of the liquid electrolytes found in particular in lithium-ion battery.[1] [2] The main advantages are the absolute safety, no issues of leakages of toxic organic solvents, low flammability, non-volatility, mechanical and thermal stability, easy processability, low self-discharge, higher achievable power density and cyclability.[3] This makes possible, for example, the use of a lithium metal anode in a practical device, without the intrinsic limitations of a liquid electrolyte thanks to the property of lithium dendrite suppression in the presence of a solid-state electrolyte membrane. The use of a high capacity anode and low reduction potential, like lithium with a specific capacity of 3860 mAh g−1 and a reduction potential of -3.04 V vs SHE, in substitution of the traditional low capacity graphite, which exhibits a theoretical capacity of 372 mAh g−1 in its fully lithiated state of LiC6,[4] is the first step in the realization of a lighter, thinner and cheaper rechargeable battery.[5] Moreover, this allows the reach of gravimetric and volumetric energy densities, high enough to achieve 500 miles per single charge in an electric vehicle.[6] Despite the promising advantages, there are still many limitations that are hindering the transition of SSEs from academia research to large-scale production, depending mainly on the poor ionic conductivity compared to that of liquid counterparts. However, many car OEMs (Toyota, BMW, Honda, Hyundai) expect to integrate these systems into viable devices and to commercialize solid-state battery-based electric vehicles by 2025.[7] [8]

History

The first inorganic solid-state electrolytes were discovered by Michael Faraday in the nineteenth century, these being silver sulfide (Ag2S) and lead(II) fluoride (PbF2).[9] The first polymeric material able to conduct ions at the solid-state was PEO, discovered in the 1970s by V. Wright. The importance of the discovery was recognized in the early 1980s.[10] [11]

However, unresolved fundamental issues remain in order to fully understand the behavior of all-solid batteries, especially in the area of electrochemical interfaces.[12] In recent years the needs of safety and performance improvements with respect to the state-of-the-art Li-ion chemistry are making solid-state batteries very appealing and are now considered an encouraging technology to satisfy the need for long range battery electric vehicles of the near future.

In March 2020, the Samsung Advanced Institute of Technology (SAIT) published research on an all-solid-state battery (ASSB) using an argyrodite-based solid-state electrolyte with a demonstrated energy density of 900 Wh L−1 and a stable cyclability of more than 1000 cycles, reaching for the first time a value close to the 1000 Wh L−1.[13]

Properties

For Solid State Batteries (SSBs) / Solid Electrolytes (SEs) to become a major market challenger it must meet some key performance measurements.[14] [15] [16] The major criteria that an SSB/SE should have are:[17]

It is hard for one material to fulfill all the above criteria, hence a number of other approaches can be used for example a hybrid electrolyte system which combines the advantages of inorganic and polymer electrolytes.

Categories

SSEs have the same role of a traditional liquid electrolyte and they are classified into all-solid-state electrolyte and quasi-solid-state electrolyte (QSSE). All-solid-state electrolytes are furthermore divided into inorganic solid electrolyte (ISE), solid polymer electrolyte (SPE) and composite polymer electrolyte (CPE). On the other hand, a QSSE, also called gel polymer electrolyte (GPE), is a freestanding membrane that contains a certain amount of liquid component immobilized inside the solid matrix. In general the nomenclatures SPE and GPE are used interchangeably but they have a substantially different ionic conduction mechanism: SPEs conducts ions through the interaction with the substitutional groups of the polymer chains, while GPEs conducts ions mainly in the solvent or plasticizer.[23]

All-solid-state electrolyte

All-solid-state electrolytes are divided into inorganic solid electrolyte (ISE), solid polymer electrolyte (SPE) and composite polymer electrolyte (CPE). They are solid at room temperature and the ionic movement occurs at the solid-state. Their main advantage is the complete removal of any liquid component aimed to a greatly enhanced safety of the overall device. The main limitation is the ionic conductivity that tends to be much lower compared to a liquid counterpart.[24]

Inorganic solid electrolyte (ISE)

Inorganic solid electrolyte (ISE) are a particular type of all-solid-state electrolyte that is constituted by an inorganic material in the crystalline or glassy state, that conducts ions by diffusion through the lattice.[25] The main advantages of this class of solid-state electrolyte are the high ionic conductivity (of the order of a few mS cm−2 at room-temperature), high modulus (of the order of GPa) and high transfer number compared to other classes of SSEs.[26] They are generally brittle and with this comes a low compatibility and stability towards the electrode, with a rapidly increasing interfacial resistance and a complicated scale-up from academic to industry.[27] They can be oxides, sulfides or phosphates-based and the crystalline structures include LISICON (lithium superionic conductor) (e.g. LGPS, LiSiPS, LiPS), argyrodite-like (e.g. Li6PS5X, X = Cl, Br, I),[28] garnets (LLZO),[29] NASICON (sodium superionic conductor) (e.g. LTP, LATP, LAGP),[30] lithium nitrides (e.g. Li3N),[31] lithium hydrides (LiBH4),[32] lithium phosphidotrielates [33] and phoshidotetrelates,[34] perovskites (e.g. lithium lanthanum titanate, "LLTO"),[35] lithium halides (LYC, LYB).,[36] RbAg4I5.[37] [38] Some ISEs can be glass ceramics assuming an amorphous state instead of a regular crystalline structure. Popular examples are lithium phosphorus oxynitride (LIPON)[39] and the lithium thiophosphates (Li2S–P2S5).[40]

Solid polymer electrolyte (SPE)

Solid polymer electrolyte (SPE) are defined as a solvent-free salt solution in a polymer host material that conducts ions through the polymer chains. Compared to ISEs, SPEs are much easier to process, generally by solution casting, making them greatly compatible with large-scale manufacturing processes. Moreover, they possess higher elasticity and plasticity giving stability at the interface, flexibility and improved resistance to volume changes during operation.[23] A good dissolution of Li salts, low glass transition temperature (Tg), electrochemical compatibility with most common electrode materials, a low degree of crystallinity, mechanical stability, low temperature sensitivity are all characteristics for the ideal SPE candidate.[41] In general though the ionic conductivity is lower than the ISEs and their rate capability is restricted, limiting fast charging.[42] PEO-based SPE is the first solid-state polymer in which ionic conductivity was demonstrated both through inter and intra molecular through ion hopping, thanks to the segmental motion of the polymeric chains[43] because of the great ion complexation capability of the ether groups, but they suffer from the low room-temperature ionic conductivity (10−5 S cm−1)[44] due to the high degree of crystallinity. The main alternatives to polyether-based SPEs are polycarbonates,[45] polyesters,[46] polynitriles (e.g. PAN),[47] polyalcohols (e.g. PVA),[48] polyamines (e.g. PEI),[49] polysiloxane (e.g. PDMS)[50] [51] and fluoropolymers (e.g. PVDF, PVDF-HFP).[52] Bio-polymers like lignin,[53] chitosan[54] and cellulose[55] are also gaining a lot of interest as standalone SPEs or blended with other polymers, on one side for their environmentally friendliness and on the other for their high complexation capability on the salts. Furthermore, different strategies are considered to increase the ionic conductivity of SPEs and the amorphous-to-crystalline ratio.[56]

With the introduction of particles as fillers inside the polymer solution, a composite polymer electrolyte (CPE) is obtained, the particles can be inert to the Li+ conduction (Al2O3, TiO2, SiO2, MgO, zeolite, montmorillonite, ...),[57] [58] [59] with the sole purpose of reducing the crystallinity, or active (LLTO, LLZO, LATP...)[60] [61] if ISE's particles are dispersed and depending on the polymer/inorganic ratio the nomenclature ceramic-in-polymer and polymer-in-ceramic is often used.[62] Copolymerization,[63] crosslinking,[64] interpenetration,[65] and blending[66] may also be used as polymer/polymer coordination to tune the properties of the SPEs and achieve better performances, introducing in the polymeric chains polar groups like ethers, carbonyls or nitriles drastically improve the dissolution of the lithium salts.

Quasi-solid-state electrolyte

Quasi solid-state electrolytes (QSSEs) are a wide class of composite compounds consisting of a liquid electrolyte and a solid matrix. This liquid electrolyte serves as a percolating pathway of ion conduction while the solid matrix adds mechanical stability to the material as a whole. As the name suggests, QSSEs can have a range of mechanical properties from strong solid-like materials to those in a paste form.[67] [68] [69] QSSEs can be subdivided into a number of categories including gel polymer electrolytes (GPEs), Ionogel electrolytes,[70] and gel electrolytes (also known as "soggy sand" electrolytes). The most common QSSE, GPEs have a substantially different ionic conduction mechanism than SPEs, which conduct ions through the interaction with the substitutional groups of the polymer chains. Meanwhile, GPEs conduct ions mainly in the solvent, which acts as plasticizer.[71] The solvent acts to increase the ionic conductivity of the electrolyte as well as soften the electrolyte for improved interfacial contact. The matrix of GPEs consist of a polymer network swollen in a solvent that contains the active ions (e.g., Li+, Na+, Mg2+, etc.). This allows for the composite to contain both the mechanical properties of solids and the high transport properties of liquids. A number of polymer hosts have been used in GPEs, including PEO, PAN, PMMA, PVDF-HFP, etc. The polymers are synthesized with increased porosity to incorporate solvents such as ethylene carbonate (EC), propylene carbonate (PC), diethyl carbonate (DEC), and dimethyl carbonate (DMC).[72] [73] [74] Low molecular weight poly(ethylene glycol) (PEG) or other ethers or aprotic organic solvents with high dielectric constant like dimethylsulfoxide (DMSO) can also be mixed the SPE matrix.[75] [76] UV and thermal cross-linking are useful ways to polymerize in-situ the GPE directly in contact with the electrodes for a perfectly adherent interface.[77] Values of ionic conductivity on the order of 1 mS cm−1 can be easily achieved with GPEs, as demonstrate the numerous research articles published.[78]

Emerging subclasses of QSSEs use matrix materials and solvents. Ionogels, for example use ionic liquids as a solvent that has improved safety including non-flammability and stability at high temperatures.[70] [79] Matrix materials in ionogels can vary from polymer materials[80] to inorganic nano-materials. These matrix materials (as with all QSSEs) provide mechanical stability with a storage moduli up to 1 MPa or higher. Meanwhile, these materials can provide ionic conductivities on the order of 1 mS cm−1 without using flammable solvents. However, gel electrolytes (i.e. "soggy sand" electrolytes) can achieve liquid-like ionic conductivities (~ 10 mS cm−1) while being in the solid state. Matrix materials such as SiO2 nanoparticles are typically paired with low viscosity solvents (e.g., ethylene carbonate (EC)) to create a gel, whose properties can be modified based on the matrix loading.[81] Matrix content ranging from 10 to 40 wt% can shift the mechanical properties of the electrolyte from a soft paste into a hard gel. However, a tradeoff between mechanical strength and ionic conductivity as one goes up with changing matrix content the other suffers.[82] Despite this, matrix content in these materials can have added benefits including enhanced lithium transference number due to functionalized matrix materials.[83] These new classes of QSSEs are an active area of research to develop the optimal combination of matrix and solvent.

Opportunities

The versatility and properties of the solid-state electrolyte widen the possible applications towards high energy density and cheaper battery chemistries that are otherwise prevented by the current state-of-the-art of Li-ion batteries. Indeed, by introducing a SSE in the battery architecture there's the possibility to use metallic lithium as anode material, with the possibility to achieve a high energy density battery thanks to its high specific capacity of 3860 mAh g−1.[84] The use of a lithium metal anode(LMA) is prevented in a liquid electrolyte above all because of the dendritic growth of a pure Li electrode that easily cause short circuits after few cycles; other related issues are volume expansions, solid-electrolyte-interface (SEI) reactivity and 'dead' lithium.[85] The usage of a SSE guarantees a homogeneous contact with the metallic lithium electrode and possess the mechanical properties to impede the uncontrolled deposition of Li+ ions during the charging phase. At the same time, a SSE finds very promising application in lithium-sulfur batteries solving the key issue of the polysulfide "shuttle" effect by blocking the dissolution of polysulfide species in the electrolyte that rapidly causes a reduction of capacity.[86]

See also

External links

Notes and References

  1. Web site: Japanese Government Partners With Manufacturers On Solid State Battery Research . CleanTechnica . 7 May 2018.
  2. Web site: German Federal Government Invests In Solid State Battery Research . CleanTechnica . 29 October 2018.
  3. Chen . Zhen . Kim . Guk-Tae . Wang . Zeli . Bresser . Dominic . Qin . Bingsheng . Geiger . Dorin . Kaiser . Ute . Wang . Xuesen . Shen . Ze Xiang . Passerini . Stefano . 4-V flexible all-solid-state lithium polymer batteries . Nano Energy . October 2019 . 64 . 103986 . 10.1016/j.nanoen.2019.103986. 10356/149966 . 201287650 . free .
  4. https://pubs.acs.org/doi/full/10.1021/acsami.0c12376 Polymer-Derived SiOC Integrated with a Graphene Aerogel As a Highly Stable Li-Ion Battery Anode
  5. Wang . Renheng . Cui . Weisheng . Chu . Fulu . Wu . Feixiang . Lithium metal anodes: Present and future . Journal of Energy Chemistry . September 2020 . 48 . 145–159 . 10.1016/j.jechem.2019.12.024. free .
  6. Web site: Baldwin . Roberto . Samsung Reveals Breakthrough: Solid-State EV Battery with 500-Mile Range . Car and Driver . 12 March 2020.
  7. Kim . Taehoon . Song . Wentao . Son . Dae-Yong . Ono . Luis K. . Qi . Yabing . Lithium-ion batteries: outlook on present, future, and hybridized technologies . Journal of Materials Chemistry A . 2019 . 7 . 7 . 2942–2964 . 10.1039/c8ta10513h. 104366580 .
  8. Web site: Solid-State Batteries . FutureBridge . 6 July 2019.
  9. Book: Solid State Electrochemistry . Cambridge University Press . 9780511524790.
  10. Wright . Peter V. . Electrical conductivity in ionic complexes of poly(ethylene oxide) . British Polymer Journal . September 1975 . 7 . 5 . 319–327 . 10.1002/pi.4980070505.
  11. GRAY . F . MACCALLUM . J . VINCENT . C . Poly(ethylene oxide) - LiCF3SO3 - polystyrene electrolyte systems . Solid State Ionics . January 1986 . 18-19 . 282–286 . 10.1016/0167-2738(86)90127-X.
  12. Janek . Jürgen . Zeier . Wolfgang G. . A solid future for battery development . Nature Energy . 8 September 2016 . 1 . 9 . 16141 . 10.1038/nenergy.2016.141. 2016NatEn...116141J .
  13. Lee . Yong-Gun . Fujiki . Satoshi . Jung . Changhoon . Suzuki . Naoki . Yashiro . Nobuyoshi . Omoda . Ryo . Ko . Dong-Su . Shiratsuchi . Tomoyuki . Sugimoto . Toshinori . Ryu . Saebom . Ku . Jun Hwan . Watanabe . Taku . Park . Youngsin . Aihara . Yuichi . Im . Dongmin . Han . In Taek . High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes . Nature Energy . 9 March 2020 . 5 . 4 . 299–308 . 10.1038/s41560-020-0575-z. 2020NatEn...5..299L . 216386265 .
  14. Robinson. Arthur L.. Janek. Jürgen. December 2014. Solid-state batteries enter EV fray. MRS Bulletin. en. 39. 12. 1046–1047. 10.1557/mrs.2014.285. 2014MRSBu..39.1046R. 0883-7694. free.
  15. Janek. Jürgen. Zeier. Wolfgang G.. 2016-09-08. A solid future for battery development. Nature Energy. en. 1. 9. 16141. 10.1038/nenergy.2016.141. 2016NatEn...116141J. 2058-7546.
  16. Hu. Yong-Sheng. 2016-04-07. Batteries: Getting solid. Nature Energy. en. 1. 4. 16042. 10.1038/nenergy.2016.42. 2016NatEn...116042H. 2058-7546.
  17. Agrawal . R C . Pandey . G P . Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview . Journal of Physics D: Applied Physics . 21 November 2008 . 41 . 22 . 223001 . 10.1088/0022-3727/41/22/223001. 94704160 .
  18. Sundaramahalingam . K. . Muthuvinayagam . M. . Nallamuthu . N. . Vanitha . D. . Vahini . M. . 104442538 . Investigations on lithium acetate-doped PVA/PVP solid polymer blend electrolytes . Polymer Bulletin . 1 January 2019 . 76 . 11 . 5577–5602 . 10.1007/s00289-018-02670-2.
  19. Appetecchi . G. B. . A New Class of Advanced Polymer Electrolytes and Their Relevance in Plastic-like, Rechargeable Lithium Batteries . Journal of the Electrochemical Society . 1996 . 143 . 1 . 6–12 . 10.1149/1.1836379. 1996JElS..143....6A .
  20. Zheng. Feng. Kotobuki. Masashi. Song. Shufeng. Lai. Man On. Lu. Li. June 2018. Review on solid electrolytes for all-solid-state lithium-ion batteries. Journal of Power Sources. 389. 198–213. 2018JPS...389..198Z. 10.1016/j.jpowsour.2018.04.022. 104174202.
  21. Zheng . Feng . Kotobuki . Masashi . Song . Shufeng . Lai . Man On . Lu . Li . Review on solid electrolytes for all-solid-state lithium-ion batteries . Journal of Power Sources . June 2018 . 389 . 198–213 . 10.1016/j.jpowsour.2018.04.022. 2018JPS...389..198Z . 104174202 .
  22. Agostini . Marco . Lim . Du Hyun . Sadd . Matthew . Fasciani . Chiara . Navarra . Maria Assunta . Panero . Stefania . Brutti . Sergio . Matic . Aleksandar . Scrosati . Bruno . Stabilizing the Performance of High-Capacity Sulfur Composite Electrodes by a New Gel Polymer Electrolyte Configuration . ChemSusChem . 11 September 2017 . 10 . 17 . 3490–3496 . 10.1002/cssc.201700977. 28731629 .
  23. Mindemark . Jonas . Lacey . Matthew J. . Bowden . Tim . Brandell . Daniel . Beyond PEO—Alternative host materials for Li + -conducting solid polymer electrolytes . Progress in Polymer Science . June 2018 . 81 . 114–143 . 10.1016/j.progpolymsci.2017.12.004. 102876830 .
  24. Mauger . A. . Armand . M. . Julien . C.M. . Zaghib . K. . Challenges and issues facing lithium metal for solid-state rechargeable batteries . Journal of Power Sources . June 2017 . 353 . 333–342 . 10.1016/j.jpowsour.2017.04.018. 2017JPS...353..333M . 99108693 .
  25. Bachman . John Christopher . Muy . Sokseiha . Grimaud . Alexis . Chang . Hao-Hsun . Pour . Nir . Lux . Simon F. . Paschos . Odysseas . Maglia . Filippo . Lupart . Saskia . Lamp . Peter . Giordano . Livia . Shao-Horn . Yang . Inorganic Solid-State Electrolytes for Lithium Batteries: Mechanisms and Properties Governing Ion Conduction . Chemical Reviews . 29 December 2015 . 116 . 1 . 140–162 . 10.1021/acs.chemrev.5b00563. 26713396 . 1721.1/109539 . free .
  26. Zhao . Qing . Stalin . Sanjuna . Zhao . Chen-Zi . Archer . Lynden A. . 211028485 . Designing solid-state electrolytes for safe, energy-dense batteries . Nature Reviews Materials . 5 February 2020 . 5 . 3 . 229–252 . 10.1038/s41578-019-0165-5. 2020NatRM...5..229Z .
  27. Han . Xiaogang . Gong . Yunhui . Fu . Kun (Kelvin) . He . Xingfeng . Hitz . Gregory T. . Dai . Jiaqi . Pearse . Alex . Liu . Boyang . Wang . Howard . Rubloff . Gary . Mo . Yifei . Thangadurai . Venkataraman . Wachsman . Eric D. . Hu . Liangbing . Negating interfacial impedance in garnet-based solid-state Li metal batteries . Nature Materials . 19 December 2016 . 16 . 5 . 572–579 . 10.1038/nmat4821. 27992420 . 1433807 .
  28. Kraft . Marvin A. . Ohno . Saneyuki . Zinkevich . Tatiana . Koerver . Raimund . Culver . Sean P. . Fuchs . Till . Senyshyn . Anatoliy . Indris . Sylvio . Morgan . Benjamin J. . Zeier . Wolfgang G. . Inducing High Ionic Conductivity in the Lithium Superionic Argyrodites Li P Ge S I for All-Solid-State Batteries . Journal of the American Chemical Society . November 2018 . 140 . 47 . 16330–16339 . 10.1021/jacs.8b10282. 30380843 . 207195755 .
  29. Liu . Qi . Geng . Zhen . Han . Cuiping . Fu . Yongzhu . Li . Song . He . Yan-bing . Kang . Feiyu . Li . Baohua . Challenges and perspectives of garnet solid electrolytes for all solid-state lithium batteries . Journal of Power Sources . June 2018 . 389 . 120–134 . 10.1016/j.jpowsour.2018.04.019. 2018JPS...389..120L . 104174556 .
  30. DeWees . Rachel . Wang . Hui . Synthesis and Properties of NaSICON‐type LATP and LAGP Solid Electrolytes . ChemSusChem . 24 July 2019 . 12 . 16 . 3713–3725 . 10.1002/cssc.201900725. 31132230 . 167209150 .
  31. Beister . Heinz Jürgen . Haag . Sabine . Kniep . Rüdiger . Strössner . Klaus . Syassen . Karl . Phase Transformations of Lithium Nitride under Pressure . Angewandte Chemie International Edition in English . August 1988 . 27 . 8 . 1101–1103 . 10.1002/anie.198811011.
  32. de Jongh . P. E. . Blanchard . D. . Matsuo . M. . Udovic . T. J. . Orimo . S. . 53402745 . Complex hydrides as room-temperature solid electrolytes for rechargeable batteries . Applied Physics A . 3 March 2016 . 122 . 3 . 251 . 10.1007/s00339-016-9807-2. 2016ApPhA.122..251D . free .
  33. Restle . Tassilo M. F. . Strangmüller . Stefan . Baran . Volodymyr . Senyshyn . Anatoliy . Kirchhain . Holger . Klein . Wilhelm . Merk . Samuel . Müller . David . Kutsch . Tobias . van Wüllen . Leo . Fässler . Thomas F. . November 2022 . Super‐Ionic Conductivity in ω‐ Li 9 Tr P 4 (Tr = Al, Ga, In) and Lithium Diffusion Pathways in Li 9 AlP 4 Polymorphs . Advanced Functional Materials . en . 32 . 46 . 2112377 . 10.1002/adfm.202112377 . 1616-301X. free .
  34. Strangmüller . Stefan . Eickhoff . Henrik . Müller . David . Klein . Wilhelm . Raudaschl-Sieber . Gabriele . Kirchhain . Holger . Sedlmeier . Christian . Baran . Volodymyr . Senyshyn . Anatoliy . Deringer . Volker L. . van Wüllen . Leo . Gasteiger . Hubert A. . Fässler . Thomas F. . 2019-09-11 . Fast Ionic Conductivity in the Most Lithium-Rich Phosphidosilicate Li 14 SiP 6 . Journal of the American Chemical Society . en . 141 . 36 . 14200–14209 . 10.1021/jacs.9b05301 . 0002-7863.
  35. Li . Yutao . Xu . Henghui . Chien . Po-Hsiu . Wu . Nan . Xin . Sen . Xue . Leigang . Park . Kyusung . Hu . Yan-Yan . Goodenough . John B. . A Perovskite Electrolyte That Is Stable in Moist Air for Lithium-Ion Batteries . Angewandte Chemie International Edition . 9 July 2018 . 57 . 28 . 8587–8591 . 10.1002/anie.201804114. 29734500 . free .
  36. Asano . Tetsuya . Sakai . Akihiro . Ouchi . Satoru . Sakaida . Masashi . Miyazaki . Akinobu . Hasegawa . Shinya . Solid Halide Electrolytes with High Lithium-Ion Conductivity for Application in 4 V Class Bulk-Type All-Solid-State Batteries . Advanced Materials . November 2018 . 30 . 44 . 1803075 . 10.1002/adma.201803075. 30216562 . 205288274 .
  37. Wang . Yuchen . Akin . Mert . Qiao . Xiaoyao . Yan . Zhiwei . Zhou . Xiangyang . Greatly enhanced energy density of all‐solid‐state rechargeable battery operating in high humidity environments . International Journal of Energy Research . September 2021 . 45 . 11 . 16794–16805 . 10.1002/er.6928. 236256757 . free .
  38. Akin . Mert . Wang . Yuchen . Qiao . Xiaoyao . Yan . Zhiwei . Zhou . Xiangyang . Effect of relative humidity on the reaction kinetics in rubidium silver iodide based all-solid-state battery . Electrochimica Acta . September 2020 . 355 . 136779 . 10.1016/j.electacta.2020.136779. 225553692 .
  39. Senevirathne . Keerthi . Day . Cynthia S. . Gross . Michael D. . Lachgar . Abdessadek . Holzwarth . N.A.W. . A new crystalline LiPON electrolyte: Synthesis, properties, and electronic structure . Solid State Ionics . February 2013 . 233 . 95–101 . 10.1016/j.ssi.2012.12.013.
  40. Mizuno . F. . Hayashi . A. . Tadanaga . K. . Tatsumisago . M. . New, Highly Ion-Conductive Crystals Precipitated from Li2S-P2S5 Glasses . Advanced Materials . 4 April 2005 . 17 . 7 . 918–921 . 10.1002/adma.200401286. 95505293 .
  41. Hallinan . Daniel T. . Balsara . Nitash P. . Polymer Electrolytes . . July 2013 . 43 . 1 . 503–525 . 10.1146/annurev-matsci-071312-121705. 2013AnRMS..43..503H .
  42. Manuel Stephan . A. . Nahm . K.S. . Review on composite polymer electrolytes for lithium batteries . Polymer . July 2006 . 47 . 16 . 5952–5964 . 10.1016/j.polymer.2006.05.069. free .
  43. Fenton . D.E. . Parker . J.M. . Wright . P.V. . Complexes of alkali metal ions with poly(ethylene oxide) . Polymer . November 1973 . 14 . 11 . 589 . 10.1016/0032-3861(73)90146-8.
  44. Payne . D.R. . Wright . P.V. . Morphology and ionic conductivity of some lithium ion complexes with poly(ethylene oxide) . Polymer . May 1982 . 23 . 5 . 690–693 . 10.1016/0032-3861(82)90052-0.
  45. Sun . Bing . Mindemark . Jonas . Edström . Kristina . Brandell . Daniel . Polycarbonate-based solid polymer electrolytes for Li-ion batteries . Solid State Ionics . September 2014 . 262 . 738–742 . 10.1016/j.ssi.2013.08.014.
  46. Webb . Michael A. . Jung . Yukyung . Pesko . Danielle M. . Savoie . Brett M. . Yamamoto . Umi . Coates . Geoffrey W. . Balsara . Nitash P. . Wang . Zhen-Gang . Miller . Thomas F. . Systematic Computational and Experimental Investigation of Lithium-Ion Transport Mechanisms in Polyester-Based Polymer Electrolytes . ACS Central Science . 10 July 2015 . 1 . 4 . 198–205 . 10.1021/acscentsci.5b00195. 27162971 . 4827473 .
  47. Hu . Pu . Chai . Jingchao . Duan . Yulong . Liu . Zhihong . Cui . Guanglei . Chen . Liquan . Progress in nitrile-based polymer electrolytes for high performance lithium batteries . Journal of Materials Chemistry A . 2016 . 4 . 26 . 10070–10083 . 10.1039/C6TA02907H.
  48. Mindemark . Jonas . Sun . Bing . Törmä . Erik . Brandell . Daniel . High-performance solid polymer electrolytes for lithium batteries operational at ambient temperature . Journal of Power Sources . December 2015 . 298 . 166–170 . 10.1016/j.jpowsour.2015.08.035. 2015JPS...298..166M .
  49. Zhang . Lei . Wang . Shi . Li . Jingyu . Liu . Xu . Chen . Pingping . Zhao . Tong . Zhang . Liaoyun . A nitrogen-containing all-solid-state hyperbranched polymer electrolyte for superior performance lithium batteries . Journal of Materials Chemistry A . 2019 . 7 . 12 . 6801–6808 . 10.1039/C9TA00180H. 104471195 .
  50. Wang . Qinglei . Zhang . Huanrui . Cui . Zili . Zhou . Qian . Shangguan . Xuehui . Tian . Songwei . Zhou . Xinhong . Cui . Guanglei . Siloxane-based polymer electrolytes for solid-state lithium batteries . Energy Storage Materials . December 2019 . 23 . 466–490 . 10.1016/j.ensm.2019.04.016. 149575379 .
  51. Rohan . Rupesh . Pareek . Kapil . Chen . Zhongxin . Cai . Weiwei . Zhang . Yunfeng . Xu . Guodong . Gao . Zhiqiang . Cheng . Hansong . A high performance polysiloxane-based single ion conducting polymeric electrolyte membrane for application in lithium ion batteries . Journal of Materials Chemistry A . 2015 . 3 . 40 . 20267–20276 . 10.1039/c5ta02628h.
  52. Jacob . M . Effect of PEO addition on the electrolytic and thermal properties of PVDF-LiClO4 polymer electrolytes . Solid State Ionics . 11 December 1997 . 104 . 3–4 . 267–276 . 10.1016/S0167-2738(97)00422-0.
  53. Liu . Bo . Huang . Yun . Cao . Haijun . Song . Amin . Lin . Yuanhua . Wang . Mingshan . Li . Xing . 103666062 . A high-performance and environment-friendly gel polymer electrolyte for lithium ion battery based on composited lignin membrane . Journal of Solid State Electrochemistry . 28 October 2017 . 22 . 3 . 807–816 . 10.1007/s10008-017-3814-x.
  54. Yahya . M.Z.A. . Arof . A.K. . Effect of oleic acid plasticizer on chitosan–lithium acetate solid polymer electrolytes . European Polymer Journal . May 2003 . 39 . 5 . 897–902 . 10.1016/S0014-3057(02)00355-5.
  55. Zhao . Lingzhu . Fu . Jingchuan . Du . Zhi . Jia . Xiaobo . Qu . Yanyu . Yu . Feng . Du . Jie . Chen . Yong . High-strength and flexible cellulose/PEG based gel polymer electrolyte with high performance for lithium ion batteries . Journal of Membrane Science . January 2020 . 593 . 117428 . 10.1016/j.memsci.2019.117428. free .
  56. Berthier . C. . Gorecki . W. . Minier . M. . Armand . M.B. . Chabagno . J.M. . Rigaud . P. . Microscopic investigation of ionic conductivity in alkali metal salts-poly(ethylene oxide) adducts . Solid State Ionics . September 1983 . 11 . 1 . 91–95 . 10.1016/0167-2738(83)90068-1.
  57. Lin. Dingchang. Liu. Wei. Liu. Yayuan. Yayuan Liu. Lee. Hye Ryoung. Hsu. Po-Chun. Liu. Kai. Cui. Yi. December 2015. High Ionic Conductivity of Composite Solid Polymer Electrolyte via In Situ Synthesis of Monodispersed SiO Nanospheres in Poly(ethylene oxide). Nano Letters. 16. 1. 459–465. 10.1021/acs.nanolett.5b04117. 26595277.
  58. Kumar . B . Polymer ceramic composite electrolytes: conductivity and thermal history effects . Solid State Ionics . 2 September 1999 . 124 . 3–4 . 239–254 . 10.1016/S0167-2738(99)00148-4.
  59. Kumar . Binod . Scanlon . Lawrence . Marsh . Richard . Mason . Rachel . Higgins . Robert . Baldwin . Richard . Structural evolution and conductivity of PEO:LiBF4–MgO composite electrolytes . Electrochimica Acta . March 2001 . 46 . 10–11 . 1515–1521 . 10.1016/S0013-4686(00)00747-7.
  60. Liang . Xinghua . Han . Di . Wang . Yunting . Lan . Lingxiao . Mao . Jie . Preparation and performance study of a PVDF–LATP ceramic composite polymer electrolyte membrane for solid-state batteries . RSC Advances . 2018 . 8 . 71 . 40498–40504 . 10.1039/C8RA08436J. 35557886 . 9091465 . 2018RSCAd...840498L . free .
  61. Keller . Marlou . Appetecchi . Giovanni Battista . Kim . Guk-Tae . Sharova . Varvara . Schneider . Meike . Schuhmacher . Jörg . Roters . Andreas . Passerini . Stefano . Electrochemical performance of a solvent-free hybrid ceramic-polymer electrolyte based on Li 7 La 3 Zr 2 O 12 in P(EO) 15 LiTFSI . Journal of Power Sources . June 2017 . 353 . 287–297 . 10.1016/j.jpowsour.2017.04.014. 2017JPS...353..287K .
  62. Chen . Long . Li . Yutao . Li . Shuai-Peng . Fan . Li-Zhen . Nan . Ce-Wen . Goodenough . John B. . PEO/garnet composite electrolytes for solid-state lithium batteries: From "ceramic-in-polymer" to "polymer-in-ceramic" . Nano Energy . April 2018 . 46 . 176–184 . 10.1016/j.nanoen.2017.12.037. free .
  63. Bouchet . Renaud . Maria . Sébastien . Meziane . Rachid . Aboulaich . Abdelmaula . Lienafa . Livie . Bonnet . Jean-Pierre . Phan . Trang N. T. . Bertin . Denis . Gigmes . Didier . Devaux . Didier . Denoyel . Renaud . Armand . Michel . Single-ion BAB triblock copolymers as highly efficient electrolytes for lithium-metal batteries . Nature Materials . 31 March 2013 . 12 . 5 . 452–457 . 10.1038/nmat3602. 23542871 . 2013NatMa..12..452B .
  64. Zhang . Yuhang . Lu . Wei . Cong . Lina . Liu . Jia . Sun . Liqun . Mauger . Alain . Julien . Christian M. . Xie . Haiming . Liu . Jun . Cross-linking network based on Poly(ethylene oxide): Solid polymer electrolyte for room temperature lithium battery . Journal of Power Sources . April 2019 . 420 . 63–72 . 10.1016/j.jpowsour.2019.02.090. 2019JPS...420...63Z . 107653475 .
  65. Liu . Xiaochen . Ding . Guoliang . Zhou . Xinhong . Li . Shizhen . He . Weisheng . Chai . Jingchao . Pang . Chunguang . Liu . Zhihong . Cui . Guanglei . An interpenetrating network poly(diethylene glycol carbonate)-based polymer electrolyte for solid state lithium batteries . Journal of Materials Chemistry A . 2017 . 5 . 22 . 11124–11130 . 10.1039/C7TA02423A.
  66. Rajendran . S . Sivakumar . M . Subadevi . R . Investigations on the effect of various plasticizers in PVA–PMMA solid polymer blend electrolytes . Materials Letters . February 2004 . 58 . 5 . 641–649 . 10.1016/S0167-577X(03)00585-8.
  67. Hyun. Woo Jin. Thomas. Cory M.. Hersam. Mark C.. 2020. Nanocomposite Ionogel Electrolytes for Solid-State Rechargeable Batteries. Advanced Energy Materials. en. 10. 36. 2002135. 10.1002/aenm.202002135. 1614-6840. free.
  68. Chen. Nan. Zhang. Haiqin. Li. Li. Chen. Renjie. Guo. Shaojun. April 2018. Ionogel Electrolytes for High-Performance Lithium Batteries: A Review. Advanced Energy Materials. en. 8. 12. 1702675. 10.1002/aenm.201702675. 102749351 .
  69. Manuel Stephan. A.. January 2006. Review on gel polymer electrolytes for lithium batteries. European Polymer Journal. en. 42. 1. 21–42. 10.1016/j.eurpolymj.2005.09.017.
  70. Tripathi. Alok Kumar. 2021. Ionic liquid–based solid electrolytes (ionogels) for application in rechargeable lithium battery. Materials Today Energy. en. 20. 100643. 10.1016/j.mtener.2021.100643. 233581904.
  71. Liang . Shishuo . Yan . Wenqi . Wu . Xu . Zhang . Yi . Zhu . Yusong . Wang . Hongwei . Wu . Yuping . Gel polymer electrolytes for lithium ion batteries: Fabrication, characterization and performance . Solid State Ionics . May 2018 . 318 . 2–18 . 10.1016/j.ssi.2017.12.023.
  72. Book: Lithium batteries : new materials, developments, and perspectives . 1994 . Elsevier . 9780444899576.
  73. Watanabe . Masayoshi . Kanba . Motoi . Nagaoka . Katsuro . Shinohara . Isao . Ionic conductivity of hybrid films based on polyacrylonitrile and their battery application . Journal of Applied Polymer Science . November 1982 . 27 . 11 . 4191–4198 . 10.1002/app.1982.070271110.
  74. Appetecchi . G.B. . Croce . F. . Scrosati . B. . Kinetics and stability of the lithium electrode in poly(methylmethacrylate)-based gel electrolytes . Electrochimica Acta . June 1995 . 40 . 8 . 991–997 . 10.1016/0013-4686(94)00345-2.
  75. Ahmed . Hawzhin T. . Jalal . Viyan J. . Tahir . Dana A. . Mohamad . Azhin H. . Abdullah . Omed Gh. . Effect of PEG as a plasticizer on the electrical and optical properties of polymer blend electrolyte MC-CH-LiBF4 based films . Results in Physics . December 2019 . 15 . 102735 . 10.1016/j.rinp.2019.102735. 2019ResPh..1502735A . free .
  76. Verdier . Nina . Lepage . David . Zidani . Ramzi . Prébé . Arnaud . Aymé-Perrot . David . Pellerin . Christian . Dollé . Mickaël . Rochefort . Dominic . Cross-Linked Polyacrylonitrile-Based Elastomer Used as Gel Polymer Electrolyte in Li-Ion Battery . ACS Applied Energy Materials . 27 December 2019 . 3 . 1 . 1099–1110 . 10.1021/acsaem.9b02129. free .
  77. Gerbaldi . C. . Nair . J.R. . Meligrana . G. . Bongiovanni . R. . Bodoardo . S. . Penazzi . N. . UV-curable siloxane-acrylate gel-copolymer electrolytes for lithium-based battery applications . Electrochimica Acta . January 2010 . 55 . 4 . 1460–1467 . 10.1016/j.electacta.2009.05.055.
  78. Bi . Haitao . Sui . Gang . Yang . Xiaoping . Studies on polymer nanofibre membranes with optimized core–shell structure as outstanding performance skeleton materials in gel polymer electrolytes . Journal of Power Sources . December 2014 . 267 . 309–315 . 10.1016/j.jpowsour.2014.05.030. 2014JPS...267..309B .
  79. Lewandowski. Andrzej. Świderska-Mocek. Agnieszka. December 2009. Ionic liquids as electrolytes for Li-ion batteries—An overview of electrochemical studies . Journal of Power Sources. en. 194. 2. 601–609. 10.1016/j.jpowsour.2009.06.089. 2009JPS...194..601L.
  80. Osada. Irene. de Vries. Henrik. Scrosati. Bruno. Passerini. Stefano. 2016-01-11. Ionic-Liquid-Based Polymer Electrolytes for Battery Applications. Angewandte Chemie International Edition. en. 55. 2. 500–513. 10.1002/anie.201504971. 26783056.
  81. Pfaffenhuber. C.. Göbel. M.. Popovic. J.. Maier. J.. 2013-10-09. Soggy-sand electrolytes: status and perspectives. Physical Chemistry Chemical Physics. en. 15. 42. 18318–18335. 10.1039/C3CP53124D. 24080900. 2013PCCP...1518318P. 1463-9084.
  82. Hyun. Woo Jin. de Moraes. Ana C. M.. Lim. Jin-Myoung. Downing. Julia R.. Park. Kyu-Young. Tan. Mark Tian Zhi. Hersam. Mark C.. 2019-08-27. High-Modulus Hexagonal Boron Nitride Nanoplatelet Gel Electrolytes for Solid-State Rechargeable Lithium-Ion Batteries. ACS Nano. en. 13. 8. 9664–9672. 10.1021/acsnano.9b04989. 31318524. 197665200. 1936-0851.
  83. Kim. Donggun. Liu. Xin. Yu. Baozhi. Mateti. Srikanth. O'Dell. Luke A.. Rong. Qiangzhou. Chen. Ying (Ian). April 2020. Amine‐Functionalized Boron Nitride Nanosheets: A New Functional Additive for Robust, Flexible Ion Gel Electrolyte with High Lithium‐Ion Transference Number. Advanced Functional Materials. en. 30. 15. 1910813. 10.1002/adfm.201910813. 1616-301X. free. 10536/DRO/DU:30135199. free.
  84. Yuan . Huadong . Nai . Jianwei . Tian . He . Ju . Zhijin . Zhang . Wenkui . Liu . Yujing . Tao . Xinyong . Lou . Xiong Wen (David) . 212739571 . An ultrastable lithium metal anode enabled by designed metal fluoride spansules . Science Advances . 6 March 2020 . 6 . 10 . eaaz3112 . 10.1126/sciadv.aaz3112. 32181364 . 7060059 . 2020SciA....6.3112Y . free .
  85. Li . Linlin . Li . Siyuan . Lu . Yingying . Suppression of dendritic lithium growth in lithium metal-based batteries . Chemical Communications . 2018 . 54 . 50 . 6648–6661 . 10.1039/C8CC02280A. 29796542 .
  86. Long . Canghai . Li . Libo . Zhai . Mo . Shan . Yuhang . Facile preparation and electrochemistry performance of quasi solid-state polymer lithium–sulfur battery with high-safety and weak shuttle effect . Journal of Physics and Chemistry of Solids . November 2019 . 134 . 255–261 . 10.1016/j.jpcs.2019.06.017. 2019JPCS..134..255L . 197395956 .

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