Quinuclidine Explained

Quinuclidine is an organic compound with the formula . It is a bicyclic amine that can be viewed as a tied back version of triethylamine. It is a colorless solid. It is used as a reagent (base) and catalyst. It can be prepared by reduction of quinuclidone.

Structure and chemical properties

Regarding its structure, quinuclidine is unusual in that the methylene hydrogen atoms are eclipsed within each of the three ethylene linkages. Furthermore, the cyclohexane rings, of which there are three, adopt the boat conformations, not the usual chair conformations.[1]

Quinuclidine is a relatively strong organic base with pKa of the conjugate acid of 11.3.[2] The basicity of other quinuclidines have been evaluated:3-hydroxy- quinuclidine (9.9), 3-acetoxyquinuclidine (9.3), 3-chloroquinuclidine (8.9), DABCO (8.7), and 3-quinuclidone (7.2).[3]

It forms adducts with a variety of Lewis acids. Because of its compact structure, quinuclidine binds to trimethylborane more tightly than does triethylamine.[4]

Derivatives and analogues

left|190px|thumb|Quinine is a quinuclidine derivative.Quinuclidine is structurally related to DABCO, in which the other bridgehead is also nitrogen, and to tropane, which has a slightly different carbon frame. Cinchona alkaloids, e.g. quinine, feature quinuclidine substituents.[4] Aceclidine, a simple quinuclidine derivative, is a drug used for treatment of glaucoma.

References

  1. 10.1021/jo00384a013 . Charge-Rransfer Interactions of Amines with Tetrahalomethanes. X-Ray Crystal Structures of the Donor-Acceptor Complexes of Quinuclidine and Diazabicyclo [2.2.2]Octane with Carbon Tetrabromide . 1987 . Blackstock . S. C. . Lorand . J. P. . Kochi . J. K. . The Journal of Organic Chemistry . 52 . 8 . 1451–1460 .
  2. Azatriquinanes: Synthesis, Structure, and Reactivity . Hext, N. M. . Hansen, J. . Blake, A. J. . Hibbs, D. E. . Hursthouse, M. B. . Shishkin, O. V. . Mascal, M. . J. Org. Chem. . 1998 . 63 . 17 . 6016–6020 . 10.1021/jo980788s . 11672206.
  3. 10.1021/jo026671s . Correlation between pKa and Reactivity of Quinuclidine-Based Catalysts in the Baylis−Hillman Reaction: Discovery of Quinuclidine as Optimum Catalyst Leading to Substantial Enhancement of Scope . 2003 . Aggarwal . Varinder K. . Emme . Ingo . Fulford . Sarah Y. . The Journal of Organic Chemistry . 68 . 3 . 692–700 . 12558387 .
  4. 10.1002/jhet.5570430601 . Chemistry of quinuclidines as nitrogen bicyclic bridged-ring structures . 2006 . Hamama . Wafaa S. . El-Magid . Osama. M. Abd . Zoorob . Hanafi H. . Journal of Heterocyclic Chemistry . 43 . 6 . 1397–1420 . free .