Potassium niobate explained

Potassium niobate (KNbO₃) is an inorganic compound with the formula KNbO₃. A colorless solid, it is classified as a perovskite ferroelectric material.^[1] It exhibits nonlinear optical properties, and is a component of some lasers.^[2] Nanowires of potassium niobate have been used to produce tunable coherent light.

Structure

On cooling from high temperature, KNbO₃ undergoes a series of structural phase transitions. At 435 °C, the crystal symmetry changes from cubic centrosymmetric (Pmm) to tetragonal non-centrosymmetric (P4mm). On further cooling, at 225 °C the crystal symmetry changes from tetragonal (P4mm) to orthorhombic (Amm2) and at −50 °C from orthorhombic (Amm2) to rhombohedral (R3m).

Applications and research

In addition to research in electronic memory storage, potassium niobate is used in resonant doubling. This technique allows small infrared lasers to convert output into blue light, a critical technology for the production of blue lasers and technology dependent upon them.

Potassium niobate has been found useful in many different areas of materials science,^[3] including properties of lasers,^[4] quantum teleportation,^[5] and it has been used to study the optical properties of particulate composite materials.^[6]

Safety

The for potassium niobate is 3000 mg/kg (oral, rat).

Notes and References

1. Hewat . A W . 1973-03-28 . Soft modes and the structure, spontaneous polarization and Curie constants of perovskite ferroelectrics: tetragonal potassium niobate . Journal of Physics C: Solid State Physics . en . 6 . 6 . 1074–1084 . 10.1088/0022-3719/6/6/020 . 1973JPhC....6.1074H . 0022-3719.
2. Book: Palik, Edward D.. Handbook of Optical Constants of Solids 3. 13 December 2012. 1998. Academic Press. 978-0-12-544423-1. 821.
3. 10.2307/3931381. 62. 17. 264–265. In Science Fields. The Science News-Letter. 1952-10-25. 3931381.
4. 267. 5206. 1920. Regalado. Antonio. Blue-Light Special. Science. New Series. 1995-03-31. 2886437. 10.1126/science.267.5206.1920. 17770099. 1995Sci...267.1920R.
5. 282. 5389. 706–709. Furusawa. A.. J. L. Sørensen . S. L. Braunstein . C. A. Fuchs . H. J. Kimble . E. S. Polzik . Unconditional Quantum Teleportation. Science. New Series. 1998-10-23. 2899257 . 10.1126/science.282.5389.706. 1998Sci...282..706F . 9784123.
6. 463. 2078. 583–592. Lakhtakia. Akhlesh. Tom G. Mackay . Electrical Control of the Linear Optical Properties of Particulate Composite Materials. Proceedings of the Royal Society A. 2007-02-08. 20209136 . 10.1098/rspa.2006.1783. physics/0607274. 2007RSPSA.463..583L. 119419605.