Pinene synthase explained
pinene synthase |
Ec Number: | 4.2.3.14 |
Go Code: | 0050550 |
In enzymology, a pinene synthase is an enzyme that catalyzes the chemical reaction
geranyl diphosphate
pinene + diphosphate
Hence, this enzyme has one substrate, geranyl diphosphate, and two products, pinene and diphosphate.
This enzyme belongs to the family of lyases, specifically those carbon-oxygen lyases acting on phosphates. The systematic name of this enzyme class is geranyl-diphosphate diphosphate-lyase (cyclizing, pinene-forming). Other names in common use include beta-geraniolene synthase, (−)-(1S,5S)-pinene synthase, and geranyldiphosphate diphosphate lyase (pinene forming). This enzyme participates in monoterpenoid biosynthesis.
References
- Bohlmann J, Steele CL, Croteau R . 1997 . Monoterpene synthases from grand fir (Abies grandis). cDNA isolation, characterization, and functional expression of myrcene synthase, (−)-(4S)-limonene synthase, and (−)-(1S,5S)-pinene synthase . J. Biol. Chem. . 272 . 21784–21792 . 9268308 . 10.1074/jbc.272.35.21784 . 35 . free .
- Gijzen M, Lewinsohn E, Croteau R . 1991 . Characterization of the constitutive and wound-inducible monoterpene cyclases of grand fir (Abies grandis) . Arch. Biochem. Biophys. . 289 . 267–273 . 1898071 . 10.1016/0003-9861(91)90471-T . 2 .
- Wagschal KC, Pyun HJ, Coates RM, Croteau R . 1994 . Monoterpene biosynthesis: isotope effects associated with bicyclic olefin formation catalyzed by pinene synthases from sage (Salvia officinalis) . Arch. Biochem. Biophys. . 308 . 477–487 . 8109978 . 10.1006/abbi.1994.1068 . 2 .