Piezomagnetism is a phenomenon observed in some antiferromagnetic and ferrimagnetic crystals. It is characterized by a linear coupling between the system's magnetic polarization and mechanical strain. In a piezomagnetic material, one may induce a spontaneous magnetic moment by applying mechanical stress, or a physical deformation by applying a magnetic field.
Piezomagnetism differs from the related property of magnetostriction; if an applied magnetic field is reversed in direction, the strain produced changes signs. Additionally, a non-zero piezomagnetic moment can be produced by mechanical strain alone, at zero fields, which is not true of magnetostriction.[1] According to the Institute of Electrical and Electronics Engineers (IEEE):
"Piezomagnetism is the linear magneto-mechanical effect analogous to the linear electromechanical effect of piezoelectricity. Similarly, magnetostriction and electrostriction are analogous second-order effects. These higher-order effects can be represented as effectively first-order when variations in the system parameters are small compared with the initial values of the parameters".[2]
The piezomagnetic effect is made possible by an absence of certain symmetry elements in a crystal structure; specifically, symmetry under time reversal forbids the property.[3]
The first experimental observation of piezomagnetism was made in 1960, in the fluorides of cobalt and manganese.[4]
The strongest piezomagnet known is uranium dioxide, with magnetoelastic memory switching at magnetic fields near 180,000 Oe at temperatures below 30 kelvins.[5]