Norethisterone enanthate explained

Norethisterone enanthate (NETE), also known as norethindrone enanthate, is a form of hormonal birth control which is used to prevent pregnancy in women.[1] [2] It is used both as a form of progestogen-only injectable birth control and in combined injectable birth control formulations. It may be used following childbirth, miscarriage, or abortion. The failure rate per year in preventing pregnancy for the progestogen-only formulation is 2 per 100 women. Each dose of this form lasts two months with only up to two doses typically recommended.

Side effects include breast pain, headaches, depression, irregular menstrual periods, and pain at the site of injection.[3] Use in those with liver disease is not recommended as is use during pregnancy due to risk of birth defects. Use appears to be okay during breastfeeding. It does not protect against sexually transmitted infections.[4] NETE is an ester and prodrug of norethisterone,[5] through which it works.[4] It works as a method of birth control by stopping ovulation.[4]

Norethisterone was patented in 1951 and NETE came into medical use in 1957.[6] It is on the World Health Organization's List of Essential Medicines.[7] It has been approved by itself in more than 60 countries including the United Kingdom and some in Europe, Central America, and Africa, and in combination with estradiol valerate in at least 36 countries mainly in Latin America.[8] [9] It is not available in the United States.[10]

Medical uses

NETE is used on its own as a long-lasting progestogen-only injectable contraceptive in women.[4] [3] It is administered via intramuscular injection once every two months.

Side effects

Side effects of NETE may include breast pain, headaches, depression, irregular menstrual periods, and pain at the site of injection. It can cause birth defects in the fetus if used during pregnancy.

Pharmacology

Pharmacodynamics

NETE is a prodrug of norethisterone in the body.[11] Upon reaching circulation, it is rapidly converted into norethisterone by esterases. Hence, as a prodrug of norethisterone, NETE has essentially the same effects as norethisterone, acting as a potent progestogen with additional weak androgenic and estrogenic activity (the latter via its metabolite ethinylestradiol).[12] NETA has some progestogenic activity of its own, but it is unclear if NETE does similarly.

NETE is of about 38% higher molecular weight than norethisterone due to the presence of its C17β enanthate ester.

A single intramuscular injection of estradiol valerate/norethisterone enanthate (5 mg/50 mg) (Mesigyna) has been found to strongly suppress testosterone levels in men.[13] Levels of testosterone decreased from ~503 ng/dL at baseline to ~30 ng/dL at the lowest point (–94%).

Pharmacokinetics

A single intramuscular injection of 50 to 200 mg NETE in oil solution has been found to have a duration of action of 11 to 52 days in terms of clinical biological effect in the uterus and on body temperature in women.[14]

Similarly to oral norethisterone and norethisterone acetate, intramuscular NETE has been found to form ethinylestradiol as an active metabolite.[15] With a single intramuscular injection of 200 mg NETE in premenopausal women, the mean maximum concentration of ethinylestradiol was 32% of that of a combined oral contraceptive containing 30 μg ethinylestradiol, the maximum equivalent oral dose of ethinylestradiol observed in the first few days of exposure was 20.3 μg/day, and the mean equivalent oral dose of ethinylestradiol over 8 weeks was 4.41 μg/day. As such, the exposure to ethinylestradiol was described as markedly lower than that of an oral contraceptive containing 30 μg ethinylestradiol. The estimated conversion rate of NETE into ethinylestradiol was 0.1%, which was much lower than that observed for oral norethisterone and norethisterone enanthate (0.2–1.0%), likely due to the lack of the first pass through the liver with parenteral administration. In accordance with the low levels of ethinylestradiol produced, no increase rates of thromboembolism or hepatic adenoma have been observed in post-authorization data of intramuscular NETE, and the medication does not resemble combined oral contraceptives containing ethinylestradiol in its safety profile.

Chemistry

See also: List of progestogens, Progestogen ester, List of progestogen esters and List of androgens/anabolic steroids.

NETE, also known as norethinyltestosterone enanthate, as well as 17α-ethynyl-19-nortestosterone 17β-enanthate or 17α-ethynylestr-4-en-17β-ol-3-one 17β-enanthate, is a progestin, or synthetic progestogen, of the 19-nortestosterone group, and a synthetic estrane steroid. It is the C17β enanthate ester of norethisterone. NETE is a derivative of testosterone with an ethynyl group at the C17α position, the methyl group at the C19 position removed, and an enanthate ester attached at the C17β position. In addition to testosterone, it is a combined derivative of nandrolone (19-nortestosterone) and ethisterone (17α-ethynyltestosterone). Esters related to NETE include norethisterone acetate and levonorgestrel butanoate.

History

NETE was introduced by Schering as Noristerat in 1957.[16] It was the second long-acting progestogen to be used clinically, after hydroxyprogesterone caproate.[17] The medication was the first progestogen-only injectable contraceptive, preceding medroxyprogesterone acetate (Depo-Provera).[16]

Society and culture

Generic names

Norethisterone enantate is the generic name of the drug and its and .[18] [19] [20] It is also spelled as norethisterone enanthate and is also known as norethindrone enanthate (the of norethisterone being norethindrone). NETE is known by its former developmental code name SH-393 as well.

Brand names

NETE has been marketed alone as a progestogen-only injectable contraceptive under the brand names Depocon, Doryxas, NET-EN, Noristat, Noristerat, Norigest, and Nur-Isterate, and in combination with estradiol valerate as a combined injectable contraceptive under the brand names Chinese Injectable No. 3,, Ginediol, Mesigyna, Mesilar, Meslart, Mesocept, Mesygest, Nofertyl, Nofertyl Lafrancol, Noregyna, Norestrin, Norifam, Norigynon, Nostidyn, Sexseg, and Solouna.[21]

Availability

NETE has been approved for use alone as a progestogen-only injectable contraceptive in more than 60 countries throughout the world including in Europe, Latin America, Asia, and Africa. Specific countries in which NETE as a standalone medication is or has been available include Bangladesh, France, Germany, India, Italy, Malaysia, Mexico, the Philippines, Singapore, South Africa, Thailand, and the United Kingdom.

NETE has been approved for use in combination with estradiol valerate as a combined injectable contraceptive in at least 36 countries, mostly in Latin America but also in Africa.[22] It is or has been available in combination with estradiol valerate in Argentina, the Bahamas, Barbados, Bolivia, Brazil, Chile, Colombia, Costa Rica, the Dominican Republic, Ecuador, Egypt, El Salvador, Ghana, Grenada, Guatemala, Guyana, Haiti, Honduras, Jamaica, Kenya, Mexico, Nicaragua, Panama, Paraguay, Peru, St. Lucia, Turkey, Uruguay, Venezuela, and Zimbabwe.

NETE is not available in any form in the United States.

Research

NETE was studied by Schering for use as a progestogen-only injectable contraceptive at a dose of 25 mg once a month but produced poor cycle control with this regimen and was not marketed.[23]

NETE has been studied for use as a potential male hormonal contraceptive in combination with testosterone in men.[24]

See also

External links

Notes and References

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  2. Book: Index Nominum 2000: International Drug Directory . 30 May 2012 . 2000 . Taylor & Francis US . 978-3-88763-075-1 . 750 . live . https://web.archive.org/web/20130528233641/http://books.google.com/books?id=5GpcTQD_L2oC&pg=PA750 . 28 May 2013.
  3. Book: WHO Model Formulary 2008 . 2009 . 9789241547659 . ((World Health Organization)) . Stuart MC, Kouimtzi M, Hill SR . 10665/44053 . World Health Organization . World Health Organization . free . 370.
  4. Web site: Noristerat 200mg, solution for intramuscular injection - Summary of Product Characteristics (SPC) - (eMC). www.medicines.org.uk. 31 December 2016. dead. https://web.archive.org/web/20161231170329/https://www.medicines.org.uk/emc/medicine/1835. 31 December 2016.
  5. Wu L, Janagam DR, Mandrell TD, Johnson JR, Lowe TL . Long-acting injectable hormonal dosage forms for contraception . Pharmaceutical Research . 32 . 7 . 2180–91 . 2015 . 25899076 . 10.1007/s11095-015-1686-2 . 12856674.
  6. Book: Fischer J, Ganellin CR . Analogue-based Drug Discovery. 2006. John Wiley & Sons. 9783527607495. 478. en. live. https://web.archive.org/web/20161220144449/https://books.google.ca/books?id=FjKfqkaKkAAC&pg=PA478. 2016-12-20.
  7. Book: ((World Health Organization)) . World Health Organization model list of essential medicines: 21st list 2019 . 2019 . 10665/325771 . World Health Organization . World Health Organization . Geneva . WHO/MVP/EMP/IAU/2019.06. License: CC BY-NC-SA 3.0 IGO . free.
  8. Book: Mastroianni L, Donaldson PJ, Kane TT . Committee on Contraceptive Development (U.S.). Developing New Contraceptives: Obstacles and Opportunities. registration. 1 January 1990. National Academies. 38–. 9780309041478. NAP:14119.
  9. Bagade O, Pawar V, Patel R, Patel B, Awasarkar V, Diwate S . Increasing use of long-acting reversible contraception: safe, reliable, and cost-effective birth control . World J Pharm Pharm Sci . 3 . 10 . 364–392 . 2014 . 2278-4357 . 2018-08-02 . https://web.archive.org/web/20170810000242/http://www.wjpps.com/download/article/1412071798.pdf . 2017-08-10 . dead .
  10. Book: Whitaker A, Gilliam M . Contraception for Adolescent and Young Adult Women. 27 June 2014. Springer. 978-1-4614-6579-9. 96. live. https://web.archive.org/web/20171105201625/https://books.google.com/books?id=vMQkBAAAQBAJ&pg=PA96. 5 November 2017.
  11. Hapgood JP, Koubovec D, Louw A, Africander D . Not all progestins are the same: implications for usage . Trends Pharmacol. Sci. . 25 . 11 . 554–7 . November 2004 . 15491776 . 10.1016/j.tips.2004.09.005.
  12. Book: IARC Working Group on the Evaluation of Carcinogenic Risks to Humans. World Health Organization. International Agency for Research on Cancer. Combined Estrogen-progestogen Contraceptives and Combined Estrogen-progestogen Menopausal Therapy. 2007. World Health Organization. 978-92-832-1291-1. 417, 432. Norethisterone and its acetate and enanthate esters are progestogens that have weak estrogenic and androgenic properties.. live. https://web.archive.org/web/20171105201625/https://books.google.com/books?id=aGDU5xibtNgC&pg=PA417. 2017-11-05.
  13. MSc . del Cisne Valle Alvarez D . Efecto de una Dosis de 50 mg de Enantato de Noretisterona y 5 mg de Valerato de Estradiol en los Niveles de Testosterona Total en Hombres Mexicanos Sanos . Effect of a Dose of 50 mg of Norethisterone Enanthate and 5 mg of Estradiol Valerate on Total Testosterone Levels in Healthy Mexican Men . 11 May 2011 . National Polytechnic Institute of Mexico .
  14. Book: Ferin J . Effects, Duration of Action and Metabolism in Man . 13–24 . Tausk M . Pharmacology of the Endocrine System and Related Drugs: Progesterone, Progestational Drugs and Antifertility Agents . II . September 1972 . Pergamon Press . 978-0080168128 . 278011135.
  15. Friedrich C, Berse M, Klein S, Rohde B, Höchel J . In Vivo Formation of Ethinylestradiol After Intramuscular Administration of Norethisterone Enantate . J Clin Pharmacol . 58. 6. 781–789. March 2018 . 29522253 . 10.1002/jcph.1079 . 3813229.
  16. Book: Bullough VL . Encyclopedia of Birth Control. 2001. ABC-CLIO. 978-1-57607-181-6. 145–. live. https://web.archive.org/web/20171105201625/https://books.google.com/books?id=XuX-MGTZnJoC&pg=PA145. 2017-11-05.
  17. Boschann HW . Observations of the role of progestational agents in human gynecologic disorders and pregnancy complications . Ann. N. Y. Acad. Sci. . 71 . 5 . 727–52 . July 1958 . 13583829 . 10.1111/j.1749-6632.1958.tb46803.x . 1958NYASA..71..727B.
  18. Book: Morton IK, Hall JM . Concise Dictionary of Pharmacological Agents: Properties and Synonyms. 6 December 2012. Springer Science & Business Media. 978-94-011-4439-1. 201–.
  19. Web site: Norethisterone.
  20. Book: Sweetman SC . Sex hormones and their modulators . Martindale: The Complete Drug Reference . 36th . 2009 . 2082 . Pharmaceutical Press . London. 978-0-85369-840-1. https://www.medicinescomplete.com/mc/martindale/.
  21. Web site: Micromedex Products: Please Login.
  22. Newton JR, D'arcangues C, Hall PE . A review of "once-a-month" combined injectable contraceptives . J Obstet Gynaecol (Lahore) . 4 . Suppl 1 . S1–34 . 1994 . 12290848 . 10.3109/01443619409027641.
  23. Toppozada M . The clinical use of monthly injectable contraceptive preparations . Obstet Gynecol Surv . 32 . 6 . 335–47 . June 1977 . 865726 . 10.1097/00006254-197706000-00001.
  24. Nieschlag E . Clinical trials in male hormonal contraception . Contraception . 82 . 5 . 457–70 . 2010 . 20933120 . 10.1016/j.contraception.2010.03.020 .