Laser cooling includes several techniques where atoms, molecules, and small mechanical systems are cooled with laser light. The directed energy of lasers is often associated with heating materials, e.g. laser cutting, so it can be counterintuitive that laser cooling often results in sample temperatures approaching absolute zero. It is a routine step in many atomic physics experiments where the laser-cooled atoms are then subsequently manipulated and measured, or in technologies, such as atom-based quantum computing architectures. Laser cooling relies on the change in momentum when an object, such as an atom, absorbs and re-emits a photon (a particle of light). For example, if laser light illuminates a warm cloud of atoms from all directions and the laser's frequency is tuned below an atomic resonance, the atoms will be cooled. This common type of laser cooling relies on the Doppler effect where individual atoms will preferentially absorb laser light from the direction opposite to the atom's motion. The absorbed light is re-emitted by the atom in a random direction. After repeated emission and absorption of light the net effect on the cloud of atoms is that they will expand more slowly. The slower expansion reflects a decrease in the velocity distribution of the atoms, which corresponds to a lower temperature and therefore the atoms have been cooled. For an ensemble of particles, their thermodynamic temperature is proportional to the variance in their velocity, therefore the lower the distribution of velocities, the lower temperature of the particles.
The 1997 Nobel Prize in Physics was awarded to Claude Cohen-Tannoudji, Steven Chu, and William Daniel Phillips "for development of methods to cool and trap atoms with laser light".[1]
Radiation pressure is the force that electromagnetic radiation exerts on matter. In 1873 Maxwell published his treatise on electromagnetism in which he predicted radiation pressure.[2] The force was experimentally demonstrated for the first time by Lebedev and reported at a conference in Paris in 1900,[3] and later published in more detail in 1901.[4] Following Lebedev's measurements Nichols and Hull also demonstrated the force of radiation pressure in 1901,[5] with a refined measurement reported in 1903.[6] [7]
In 1933, Otto Frisch deflected an atomic beam of sodium atoms with light.[8] This was the first realization of radiation pressure acting on a resonant absorber.
The introduction of lasers in atomic physics experiments was the precursor to the laser cooling proposals in the mid 1970s. Laser cooling was proposed separately in 1975 by two different research groups: Hänsch and Schawlow,[9] and Wineland and Dehmelt.[10] Both proposals outlined the simplest laser cooling process, known as Doppler cooling, where laser light tuned below an atom's resonant frequency is preferentially absorbed by atoms moving towards the laser and after absorption a photon is emitted in a random direction. This process is repeated many times and in a configuration with counterpropagating laser cooling light the velocity distribution of the atoms is reduced.[11]
In 1977 Ashkin submitted a paper which describes how Doppler cooling could be used to provide the necessary damping to load atoms into an optical trap.[12] In this work he emphasized how this process could allow for long spectroscopic measurements without the atoms escaping the trap and proposed the overlapping of optical traps in order to study interactions between different atoms.
Following the laser cooling proposals, in 1978 two research groups that Wineland, Drullinger and Walls of NIST, and Neuhauser, Hohenstatt, Toscheck and Dehmelt of the University of Washington succeeded in laser cooling atoms. The NIST group wanted to reduce the effect of Doppler broadening on spectroscopy. They cooled magnesium ions in a Penning trap to below 40 K. The Washington group cooled barium ions. The research from both groups served to illustrate the mechanical properties of light. Around this time, laser cooling techniques had allowed for temperatures lowered to around .
Influenced by the Wineland's work on laser cooling ions, William Phillips applied the same principles to laser cool neutral atoms. In 1982, he published the first paper where neutral atoms were laser cooled.[13] The process used is now known as the Zeeman slower and is a standard technique for slowing an atomic beam.
The Doppler cooling limit for electric dipole transitions is typically in the hundreds of microkelvins. In the 1980s this limit was seen as the lowest achievable temperature. It was a surprise then when sodium atoms were cooled to 43 microkelvin when their Doppler cooling limit is 240 microkelvin,[14] this unforeseen low temperature was explained by considering the interaction of polarized laser light with more atomic states and transitions. Previous conceptions of laser cooling were decided to have been too simplistic.[15] The major laser cooling breakthroughs in the 70s and 80s led to several improvements to preexisting technology and new discoveries with temperatures just above absolute zero. The cooling processes were utilized to make atomic clocks more accurate and to improve spectroscopic measurements, and led to the observation of a new state of matter at ultracold temperatures.[16] The new state of matter, the Bose–Einstein condensate, was observed in 1995 by Eric Cornell, Carl Wieman, and Wolfgang Ketterle.[17]
In 2010, a team at Yale successfully laser-cooled a diatomic molecule.[18] In 2016, a group at MPQ successfully cooled formaldehyde to via optoelectric Sisyphus cooling.[19] In 2022, a group at Harvard successfully laser cooled and trapped CaOH to in a magneto-optical trap.[20]
Starting in the 2000s, laser cooling was applied to small mechanical systems, ranging from small cantilevers to the mirrors used in the LIGO observatory. These devices are connected to a larger substrate, such as a mechanical membrane attached to a frame, or they are held in optical traps, in both cases the mechanical system is a harmonic oscillator. Laser cooling reduces the random vibrations of the mechanical oscillator, removing thermal phonons from the system.
In 2007, an MIT team successfully laser-cooled a macro-scale (1 gram) object to 0.8 K.[21] In 2011, a team from the California Institute of Technology and the University of Vienna became the first to laser-cool a (10 μm × 1 μm) mechanical object to its quantum ground state.[22]
The first example of laser cooling, and also still the most common method (so much so that it is still often referred to simply as 'laser cooling') is Doppler cooling.
See main article: Doppler cooling. Doppler cooling, which is usually accompanied by a magnetic trapping force to give a magneto-optical trap, is by far the most common method of laser cooling. It is used to cool low density gases down to the Doppler cooling limit, which for rubidium-85 is around 150 microkelvins.
In Doppler cooling, initially, the frequency of light is tuned slightly below an electronic transition in the atom. Because the light is detuned to the "red" (i.e., at lower frequency) of the transition, the atoms will absorb more photons if they move towards the light source, due to the Doppler effect. Thus if one applies light from two opposite directions, the atoms will always scatter more photons from the laser beam pointing opposite to their direction of motion. In each scattering event the atom loses a momentum equal to the momentum of the photon. If the atom, which is now in the excited state, then emits a photon spontaneously, it will be kicked by the same amount of momentum, but in a random direction. Since the initial momentum change is a pure loss (opposing the direction of motion), while the subsequent change is random, the probable result of the absorption and emission process is to reduce the momentum of the atom, and therefore its speed - provided its initial speed was larger than the recoil speed from scattering a single photon. If the absorption and emission are repeated many times, the average speed, and therefore the kinetic energy of the atom, will be reduced. Since the temperature of a group of atoms is a measure of the average random internal kinetic energy, this is equivalent to cooling the atoms.
The idea for anti-Stokes cooling was first advanced by Pringsheim in 1929.[23] While Doppler cooling lowers the translational temperature of a sample, anti-Stokes cooling decreases the vibrational or phonon excitation of a medium. This is accomplished by pumping a substance with a laser beam from a low-lying energy state to a higher one with subsequent emission to an even lower-lying energy state. The principal condition for efficient cooling is that the anti-Stokes emission rate to the final state be significantly larger than that to other states as well as the nonradiative relaxation rate. Because vibrational or phonon energy can be many orders of magnitude larger than the energy associated with Doppler broadening, the efficiency of heat removal per laser photon expended for anti-Stokes cooling can be correspondingly larger than that for Doppler cooling. The anti-Stokes cooling effect was first demonstrated by Djeu and Whitney in CO2 gas.[24] The first anti-Stokes cooling in a solid was demonstrated by Epstein et al. in 1980, in a ytterbium doped fluoride glass sample.[25]
Potential practical applications for anti-Stokes cooling of solids include radiation balanced solid state lasers and vibration-free optical refrigeration.[26] [27]
Other methods of laser cooling include:
Laser cooling is very common in the field of atomic physics. Reducing the random motion of atoms has several benefits, including the ability to trap atoms with optical or magnetic fields. Spectroscopic measurements of a cold atomic sample will also have reduced systematic uncertainties due to thermal motion.
Often multiple laser cooling techniques are used in a single experiment to prepare a cold sample of atoms, which is then subsequently manipulated and measured. In a representative experiment a vapor of strontium atoms is generated in a hot oven that exit the oven as an atomic beam. After leaving the oven the atoms are Doppler cooled in two dimensions transverse to their motion to reduce loss of atoms due to divergence of the atomic beam. The atomic beam is then slowed and cooled with a Zeeman slower to optimize the atom loading efficiency into a magneto-optical trap (MOT), which Doppler cools the atoms, that operates on the with lasers at 461 nm. The MOT transitions from using light at 461 nm to using light at 689 nm to drive the, which is a narrow transition, to realize even colder atoms. The atoms are then transferred into an optical dipole trap where evaporative cooling gets them to temperatures where they can be effectively loaded into an optical lattice.
Laser cooling is important for quantum computing efforts based on neutral atoms and trapped atomic ions. In an ion trap Doppler cooling reduces the random motion of the ions so they form a well-ordered crystal structure in the trap. After Doppler cooling the ions are often cooled to their motional ground state to reduce decoherence during quantum gates between ions.