Katayamalite Explained

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Formula:KLi3Ca7Ti2(SiO3)12(OH)2
Imasymbol:Kyl[1]
Strunz:9.CJ.25
System:Monoclinic
Dana:61.01.04.02
Class:Prismatic
H-M symbol: 2/m
Symmetry:B2/b
Unit Cell:3,179.12
Color:White
Habit:Tabular, common twinning
Cleavage:Perfect on
Mohs:3.5 - 4
Luster:Vitreous, pearly
Opticalprop:Biaxial (+)
Refractive:nα = 1.670
nβ = 1.671
nγ = 1.677
2V:Measured: 32
Calculated: 46
Dispersion:Strong
r > v
Fluorescence:brilliant blue-white under SW
Streak:White
Density:2.91
Other: Radioactive

Katayamalite is a cyclosilicate mineral that was named in honor of mineralogist and professor Nobuo Katayama. It was approved in 1982 by the International Mineralogical Association, and was first published a year later.

Relation with baratovite

Katayamalite is the hydroxyl analogue of baratovite and the hydroxyl end member of the series,[2] but was first described as a fluor-dominant mineral. Some scientists claim it to be rather hydroxyl- than fluor dominant, which would make baratovite isostructural with it. It would make the two minerals the same species, with baratovite having priority. As the case hadn't been clarified, katayamalite remains an IMA-approved mineral until this day.[3]

Chemical properties

Katayamalite mainly consists of oxygen (43.16%), silicon (24.25%), calcium (20.18%), but otherwise contains titanium (6.89%), potassium (2.81%), lithium (1.50%). It has trace amounts of fluorine (0.68%), sodium (0.41%) and hydrogen (0.11%) in its composition as well. It has a barely detectable radioactivity, 40.21 measured in Gamma Ray American Petroleum Institute Units. The concentration of it in percentage is 2.49. It was originally described as having a triclinic symmetry in 1985, but the structure was redetermined to be monoclinic in 2013. It has a radiant blue-white fluorescence, and platy morphology.

Occurrence

The mineral is associated with sugilite, albite and aegirine. Crystals are usually twinned. This mineral can be found in aegirine syenite.

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Web site: Katayamalite Mineral Data. 2021-08-08. webmineral.com.
  3. Web site: Katayamalite. 2021-08-08. www.mindat.org.