Iron(III) acetate explained

Ferric acetate is the acetate salt of the coordination complex [Fe<sub>3</sub>O(OAc)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>]+ (OAc is CH3CO2). Commonly the salt is known as "basic iron acetate".[1] The formation of the red-brown complex was once used as a test for ferric ions.[2]

Structure and synthesis

Basic iron acetate forms on treating aqueous solutions of iron(III) sources with acetate salts.[3] A typical precursor is freshly precipitated iron oxide/hydroxide, which is halide-free.[4]

Early work showed that the cation is trinuclear.[5] The Fe centres are equivalent, each being octahedral, being bound to six oxygen ligands, including a triply bridging oxide at the center of the equilateral triangle.[6] The compound was an early example of a molecular complex of iron that features an oxide ligand. The cation has idealized D3h symmetry.

Reactions

The terminal aqua ligands on the trimetallic framework can be substituted with other ligands, such as pyridine and dimethylformamide. Many different salts are known by exchanging the anion, e.g. [Fe<sub>3</sub>(μ<sub>3</sub>-O)(OAc)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>]Cl. Reduction of the cation affords the neutral mixed-valence derivative that contains one ferrous and two ferric centers.[1] Mixed metal species are known such as [Fe<sub>2</sub>CoO(OAc)<sub>6</sub>(H<sub>2</sub>O)<sub>3</sub>].[7]

Related compounds

Chromium(III), ruthenium(III), vanadium(III), manganese(III) and rhodium(III) form analogous compounds. Iron(III) acetate (lacking the oxo ligand) has been claimed as a red coloured compound from the reaction of silver acetate and iron(III) chloride.[8]

Uses

Materials prepared by heating iron, acetic acid, and air, loosely described as basic iron acetates, are used as dyes and mordants.[1]

Iron acetate is often brushed upon untreated wood to give it an aged appearance.

See also

References

Notes and References

  1. Book: J. . Burgess . M. V. . Twigg . R. Bruce . King . J. . Wiley . Encyclopedia of inorganic chemistry . 2005 . Wiley . New York . 978-0-470-86078-6 . 2nd.
  2. Book: H. . Brearley . F. . Ibbotson . The Analysis of Steel-Works Materials . 1902 . Longmans, Green . London ; New York . dead . https://web.archive.org/web/20150418190528/http://www.clpdigital.org/jspui/handle/10493/809 . 2015-04-18.
  3. Book: W. . Simon . Manual of Chemistry . 978-1406733358 . 474. March 2007.
  4. Book: 1508. H. Lux. Basic Iron(III) Acetate. Handbook of Preparative Inorganic Chemistry. Georg Brauer. 1963.
  5. Weinland . R. . Dinkelacker . P. . Über Salze einer Hexaacetato(formiato)-trichrombase. II . Berichte der Deutschen Chemischen Gesellschaft . July 1909 . 42 . 3 . 2997–3018 . 10.1002/cber.19090420318.
  6. Figgis . B. N. . Robertson . G. B. . Crystal-Molecular Structure and Magnetic Properties of Cr3(CH3.COO)6OCl.5H2O . Nature . 13 February 1965 . 205 . 4972 . 694–695 . 10.1038/205694a0. 1965Natur.205..694F . 4283321. This paper describes the isostructure chromium and iron compounds.
  7. Blake . Antony B. . Yavari . Ahmad . Hatfield . William E. . Sethulekshmi . C. N. . Magnetic and spectroscopic properties of some heterotrinuclear basic acetates of chromium(III), iron(III), and divalent metal ions . Journal of the Chemical Society, Dalton Transactions . 1985 . 12 . 2509 . 10.1039/DT9850002509.
  8. Paul . Ram C. . Narula . Ramesh C. . Vasisht . Sham K. . Iron(III) acetates . Transition Metal Chemistry . December 1978 . 3 . 1 . 35–38 . 10.1007/BF01393501. 94447648.