Iodide hydride explained

Iodide hydrides are mixed anion compounds containing hydride and iodide anions.Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.

List

formulasystemspace groupunit cell Åvolumedensitycommentreference
(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac)
KHI[1] [2]
[LZnI(η<sup>2</sup>-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine[3]
Sr2H3ItrigonalPm1a = 4.260 c = 7.749 Z=1121.774.16transparent[4]
YIHC=31.033metallic[5]
YIH2P3m1a = 3.8579, c = 10.997light green
Nb6I11HD10/2ha = 11.317; b = 15.471 ; c = 13.431[6]
Nb6I11HImma = 11.317; b = 15.471 ; c = 13.431black
Nb6(H)I9StriclinicP1a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2[7] [8]
HCsNb6I11[9]
Ba2H3ItrigonalPm1a= 4.519 c= 8.1184transparent[10]
Ba5H2I4O2orthorhombicCmcma =17.210, b = 14.525 c = 6.3903 Z=41597.445.11transparent
LaI2HhexagonalP63/mmca=4.2158 c=15.508[11] [12]
NdI2H[13]
Gd2ICH0.73P63mca=3.8128 C=14.844 Z=28.071[14]
Eu2H3Idark red[15]
Eu5H2O2I4orthorhombicCmcma = 16.3697, b = 13.6954, c = 6.0436, Z = 4dark red
Tb2ICH
DyI2H
[(η<sup>5</sup>-C<sub>5</sub>H<sub>5</sub>)W(NO)IH]2[16]
(η5-C5H5)W(NO)I(H)(P(OPh)3)
Ir(η2-H2)(H)2I(PiPr3)2[17] [18]
Ir(η2-H2)(H)2I(PiPr3)2•C10H8triclinicPa=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=215K

Notes and References

  1. Mills . R . November 2001 . Minimum heat of formation of potassium iodo hydride . International Journal of Hydrogen Energy . 26 . 11 . 1199–1208 . 10.1016/S0360-3199(01)00051-9.
  2. Mills . R . December 2000 . Synthesis and characterization of potassium iodo hydride . International Journal of Hydrogen Energy . en . 25 . 12 . 1185–1203 . 10.1016/S0360-3199(00)00037-9.
  3. Book: Lummis, Paul Ashley . Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis . University of Alberta . 2015.
  4. Reckeweg . Olaf . DiSalvo . Francis J. . 2011-01-01 . AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2 . Zeitschrift für Naturforschung B . en . 66 . 1 . 21–26 . 10.1515/znb-2011-0104 . 27301598 . 1865-7117. free .
  5. Ryazanov . Mikhail . Simon . Arndt . Mattausch . Hansjürgen . August 2004 . YIH n : A New Family of Metal-rich Hydride Halides . Zeitschrift für anorganische und allgemeine Chemie . en . 630 . 10 . 1401–1407 . 10.1002/zaac.200400094 . 0044-2313.
  6. Simon . Arndt . Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8] . Zeitschrift für anorganische und allgemeine Chemie . December 1967 . 355 . 5–6 . 311–322 . 10.1002/zaac.19673550511.
  7. Meyer . H. Juergen . Corbett . John D. . October 1992 . Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S) . Inorganic Chemistry . en . 31 . 21 . 4276–4280 . 10.1021/ic00047a013 . 0020-1669.
  8. Meyer . H. Juergen . Corbett . John D. . March 1991 . Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride . Inorganic Chemistry . en . 30 . 5 . 963–967 . 10.1021/ic00005a017 . 0020-1669.
  9. Simon . Arndt . March 1985 . Empty, filled, and condensed metal clusters . Journal of Solid State Chemistry . en . 57 . 1 . 2–16 . 10.1016/S0022-4596(85)80055-4. 1985JSSCh..57....2S .
  10. Reckeweg . Olaf . DiSalvo . Francis J. . 2011-11-01 . Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I . Zeitschrift für Naturforschung B . en . 66 . 11 . 1087–1091 . 10.1515/znb-2011-1101 . 40246199 . 1865-7117. free .
  11. Imoto . Hideo . Corbett . John D. . February 1981 . Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures . Inorganic Chemistry . en . 20 . 2 . 630–633 . 10.1021/ic50216a062 . 0020-1669.
  12. Ryazanov . M . Simon . A . Mattausch . Hj . Kremer . R.K . July 2004 . The structural change of lanthanum diiodide upon hydrogenation . Journal of Alloys and Compounds . en . 374 . 1–2 . 142–145 . 10.1016/j.jallcom.2003.11.072.
  13. Bochkarev . M. N. . Logunov . A. A. . Burin . M. E. . October 2007 . Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H . Russian Chemical Bulletin . en . 56 . 10 . 1953–1955 . 10.1007/s11172-007-0303-x . 93943595 . 1066-5285.
  14. Ruck . M. . Simon . A. . November 1992 . Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen . Zeitschrift für anorganische und allgemeine Chemie . de . 617 . 11 . 7–18 . 10.1002/zaac.19926170102 . 0044-2313.
  15. Rudolph . Daniel . Wylezich . Thomas . Netzsch . Philip . Blaschkowski . Björn . Höppe . Henning A. . Goldner . Philippe . Kunkel . Nathalie . Hoslauer . Jean-Louis . Schleid . Thomas . 2023-10-07 . Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence . International Journal of Molecular Sciences . en . 24 . 19 . 14969 . 10.3390/ijms241914969 . 1422-0067 . 10573458 . 37834417 . free .
  16. Book: Oxley, Jimmie Carol . Nitrosyl Hydrides and Cations of Group VI Transition Metals . California State University Northridge . 20 April 1978.
  17. Bau . Robert . Drabnis . Mary H. . June 1997 . Structures of transition metal hydrides determined by neutron diffraction . Inorganica Chimica Acta . en . 259 . 1–2 . 27–50 . 10.1016/S0020-1693(97)89125-6.
  18. Eckert . Juergen . Jensen . Craig M. . Koetzle . Thomas F. . Husebo . Trang Le . Nicol . Jacqueline . Wu . Ping . Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands . Journal of the American Chemical Society . July 1995 . 117 . 27 . 7271–7272 . 10.1021/ja00132a038.

This article is licensed under the GNU Free Documentation License. It uses material from the Wikipedia article "Iodide hydride".

Except where otherwise indicated, Everything.Explained.Today is © Copyright 2009-2024, A B Cryer, All Rights Reserved. Cookie policy.