Hydronium perchlorate explained

Hydronium perchlorate is an inorganic chemical compound with the chemical formula . It is an unusual salt due to it being a solid and stable hydronium salt. It consists of hydronium cations and perchlorate anions .

Production

Hydronium perchlorate is produced by the reaction of anhydrous perchloric acid and water in a 1:1 molar ratio:[1]

A more analytically reliable method was reported using the macrocyclic Schiff base of sodium 2,6-diformyl-4-methylphenolate and 2,6-diformyl-4-methylphenol as a chelating agent to sequester Cu(II): transmetallation of the macrocycle with copper(II) perchlorate yielded colorless crystals of hydronium perchlorate.

It can also be produced by the reaction of anhydrous nitric acid and perchloric acid.[2]

Notes and References

  1. C. E. Nordman . The crystal structure of hydronium perchlorate at -80°C . Acta Crystallographica . 1962 . 15 . 1. 18–23 . 10.1107/S0365110X62000055 . en. free. 1962AcCry..15...18N .
  2. Book: Kenneth Schofield . Aromatic nitration . 1980 . Cambridge University Press . 9780521233620 . 30 . en. 3.