Hydrogen infrastructure explained

A hydrogen infrastructure is the infrastructure of hydrogen pipeline transport, points of hydrogen production and hydrogen stations for distribution as well as the sale of hydrogen fuel,[1] and thus a crucial prerequisite before a successful commercialization of fuel cell technology.[2] The hydrogen infrastructure would consist mainly of industrial hydrogen pipeline transport and hydrogen-equipped filling stations. Hydrogen stations which were not situated near a hydrogen pipeline would get supply via hydrogen tanks, compressed hydrogen tube trailers, liquid hydrogen trailers, liquid hydrogen tank trucks or dedicated onsite production.

Pipelines are the cheapest way to move hydrogen over long distances compared to other options. Hydrogen gas piping is routine in large oil-refineries, because hydrogen is used to hydrocrack fuels from crude oil. The IEA recommends existing industrial ports be used for production and existing natural gas pipelines for transport: also international co-operation and shipping.

South Korea and Japan,[3] which as of 2019 lack international electrical interconnectors, are investing in the hydrogen economy.[4] In March 2020, the Fukushima Hydrogen Energy Research Field was opened in Japan, claiming to be the world's largest hydrogen production facility.[5] Much of the site is occupied by a solar array; power from the grid is also used for electrolysis of water to produce hydrogen fuel.[6]

Network

Hydrogen highways

A hydrogen highway is a chain of hydrogen-equipped filling stations and other infrastructure along a road or highway which allow hydrogen vehicles to travel.

Hydrogen stations

Hydrogen stations which are not situated near a hydrogen pipeline get supply via hydrogen tanks, compressed hydrogen tube trailers, liquid hydrogen trailers, liquid hydrogen tank trucks or dedicated onsite production. Some firms as ITM Power are also providing solutions to make your own hydrogen (for use in the car) at home.[7] Government supported activities to expand an hydrogen fuel infrastructure are ongoing in the US state of California, in some member states of the European Union (most notably in Germany) and in particular in Japan.

Hydrogen pipeline transport

Hydrogen pipeline transport is a transportation of hydrogen through a pipe as part of the hydrogen infrastructure. Hydrogen pipeline transport is used to connect the point of hydrogen production or delivery of hydrogen with the point of demand, pipeline transport costs are similar to CNG,[8] the technology is proven,[9] however most hydrogen is produced on the place of demand with every 50to an industrial production facility.[10], there are 900miles of low pressure hydrogen pipelines in the US and 930miles in Europe.

According to a 2024 research report, the United States has 1,600 miles (2,570 kilometers) of hydrogen pipelines; the global total stands at 2,800 miles (4,500 kilometers).[11] The World Economic Forum, in December 2023, estimated that Europe had approximately 1,600 kilometers of hydrogen pipelines.[12]

Hydrogen embrittlement (a reduction in the ductility of a metal due to absorbed hydrogen) is not a problem for hydrogen gas pipelines. Hydrogen embrittlement only happens with 'diffusible' hydrogen, i.e. atoms or ions. Hydrogen gas, however, is molecular (H2), and there is a very significant energy barrier to splitting it into atoms.[13]

Buffer for renewable energy

The National Renewable Energy Laboratory believes that US counties have the potential to produce more renewable hydrogen for fuel cell vehicles than the gasoline they consumed in 2002.[14]

As an energy buffer, hydrogen produced via water electrolysis and in combination with underground hydrogen storage or other large-scale storage technologies, could play an important role for the introduction of fluctuating renewable energy sources like wind or solar power.

Hydrogen production plants

98% of hydrogen production uses the steam reforming method. Methods such as electrolysis of water are also used.[15] The world's largest facility for producing electrolytic hydrogen fuel is claimed[16] to be the Fukushima Hydrogen Energy Research Field (FH2R), a 10MW-class hydrogen production unit, inaugurated on 7 March 2020, in Namie, Fukushima Prefecture.[17] The site occupies 180,000 square meters of land, much of which is occupied by a solar array; but power from the grid is also used to conduct electrolysis of water to produce hydrogen fuel.

Hydrogen pipeline transport

Hydrogen pipeline transport is a transportation of hydrogen through a pipe as part of the hydrogen infrastructure.

History

Economics

Hydrogen pipeline transport is used to transport hydrogen from the point of production or delivery to the point of demand. Although hydrogen pipeline transport is technologically mature,[22] [23] and the transport costs are similar to those of CNG,[24] most hydrogen is produced in the place of demand, with an industrial production facility every 50miles100miles[25]

Piping

For process metal piping at pressures up to 7000psi, high-purity stainless steel piping with a maximum hardness of 80 HRB is preferred.[26] This is because higher hardnesses are associated with lower fracture toughness so stronger, higher hardness steel is less safe.

Composite pipes are assessed like:

Fiber-Reinforced Polymer pipelines (or FRP pipeline) and reinforced thermoplastic pipes are researched.[27] [28] [29] [30]

Carrying hydrogen in steel pipelines (grades: API5L-X42 and X52; up to 1,000psi/7,000kPa, constant pressure/low pressure cycling) does not lead to hydrogen embrittlement.[31] Hydrogen is typically stored in steel cylinders without problems.Coal gas (also known as town gas) is 50% hydrogen and was carried in cast-iron pipes for half a century without any embrittlement issues.

Infrastructure

Hydrogen highway

A hydrogen highway is a chain of hydrogen-equipped public filling stations, along a road or highway, that allows hydrogen powered cars to travel.[32] William Clay Ford Jr. has stated that infrastructure is one of three factors (also including costs and manufacturability in high volumes) that hold back the marketability of fuel cell cars.

Supply issues, cost and pollution

Hydrogen fueling stations generally receive deliveries of hydrogen by tanker truck from hydrogen suppliers. An interruption at a hydrogen supply facility can shut down multiple hydrogen fueling stations.[33] A hydrogen fueling station costs between $1 million and $4 million to build.[34]

As of 2019, 98% of hydrogen is produced by steam methane reforming, which emits carbon dioxide.[35] The bulk of hydrogen is also transported in trucks, so pollution is emitted in its transportation.[36]

Hydrogen station

A hydrogen station is a storage or filling station for hydrogen fuel.[37] The hydrogen is dispensed by weight.[38] [39] There are two filling pressures in common use: H70 or 700 bar, and the older standard H35 or 350 bar.[40], around 550 filling stations were available worldwide. According to H2stations.org by Ludwig-Bölkow-Systemtechnik (LBST), as of the end of 2023, there were 921 hydrogen refueling stations globally,[41] although this number clearly conflicts with those published by AFDC. The distribution of these stations is highly uneven, with a concentration in East Asia, particularly in China, Japan and South Korea; Central Europe and California in the United States. Other regions have very few, if any, hydrogen refuelling stations.

Delivery methods

Hydrogen fueling stations can be divided into off-site stations, where hydrogen is delivered by truck or pipeline, and on-site stations that produce and compress hydrogen for the vehicles.[42] [43]

Types of recharging stations

Home hydrogen fueling station

Home hydrogen fueling stations are available to consumers.[44] A model that can produce 12 kilograms of hydrogen per day sells for $325,000.[45]

Solar powered water electrolysing hydrogen home stations are composed of solar cells, power converter, water purifier, electrolyzer, piping, hydrogen purifier,[46] oxygen purifier, compressor,[47] pressure vessels[48] and a hydrogen outlet.[49]

Disadvantages

Volatility

Hydrogen fuel is hazardous because of its low ignition energy, high combustion energy, and because it easily leaks from tanks.[50] Explosions at hydrogen filling stations have been reported.[51]

Supply

Hydrogen fuelling stations generally receive deliveries by truck from hydrogen suppliers. An interruption at a hydrogen supply facility can shut down multiple hydrogen fuelling stations due to an interruption of the supply of hydrogen.[52]

Costs

There are far fewer Hydrogen filling stations than gasoline fuel stations, which in the US alone numbered 168,000 in 2004.[53] Replacing the US gasoline infrastructure with hydrogen fuel infrastructure is estimated to cost a half trillion U.S. dollars.[54] A hydrogen fueling station costs between $1 million and $4 million to build.[55] In comparison, battery electric vehicles can charge at home or at public chargers. As of 2023, there are more than 60,000 public charging stations in the United States, with more than 160,000 outlets. A public Level 2 charger, which comprise the majority of public chargers in the US, costs about $2,000, and DC fast chargers, of which there are more than 30,000 in the U.S., generally cost between $100,000 and $250,000,[56] although Tesla superchargers are estimated to cost approximately $43,000.[57]

Freezing of the nozzle

During refueling, the flow of cold hydrogen can cause frost to form on the dispenser nozzle, sometimes leading to the nozzle becoming frozen to the vehicle being refueled.[58]

Locations

Consulting firm Ludwig-Bölkow-Systemtechnik tracks global hydrogen filling stations and publishes a map.[59]

Asia

In 2019, there were 178 publicly available hydrogen fuel stations in operation.[60]

, there are 167 publicly available hydrogen fuel stations in operation in Japan.[61] [62] In 2012 there were 17 hydrogen stations,[63] and in 2021, there were 137 publicly available hydrogen fuel stations in Japan.

By the end of 2023, China had built 354 hydrogen refueling stations.[64]

In 2019, there were 33 publicly available hydrogen fuel stations in operation in South Korea.[65] In November 2023, however, due to hydrogen supply problems and broken stations, most fueling stations in South Korea offered no hydrogen.[66] 41 out of the 159 hydrogen stations in the country were listed as open, and some of these were rationing supplies of hydrogen.[67]

Europe

In 2019, there were 177 stations in Europe.[68] [69] According to H2stations.org by Ludwig-Bölkow-Systemtechnik (LBST), there were 265 hydrogen refuelling stations in Europe by the end of 2023.[41]

there were 105 hydrogen fuel stations in Germany,[41] there were 5 publicly available hydrogen fuel stations in France, 3 publicly available hydrogen fuel stations in Iceland, one publicly available hydrogen fuel station in Italy, 4 publicly available hydrogen fuel stations in The Netherlands, 2 publicly available hydrogen fuel stations in Belgium, 4 publicly available hydrogen fuel stations in Sweden, 3 publicly available hydrogen fuel stations in Switzerland and 6 publicly available hydrogen fuel stations in Denmark. Everfuel, the only operator of hydrogen stations in Denmark, announced in 2023 the closure of all of its public hydrogen stations in the country.[70] [71]

there were 2 publicly available hydrogen fuel stations in Norway, both in the Oslo area.[72] Since the explosion at the hydrogen filling station in Sandvika in June 2019, the sale of hydrogen cars in Norway has halted.[73] In 2023, Everfuel announced the closure of its two public hydrogen stations in Norway and cancelled the opening of a third.[70]

there were 11 publicly available hydrogen fuel stations in the United Kingdom, but as of 2023, the number decreased to 5.[74] In 2022, Shell closed its three hydrogen stations in the UK.[75]

North America

Canada

As of July 2023, there were 10 fueling stations in Canada, 9 of which were open to the public:

United States

, there were 54 publicly accessible hydrogen refueling stations in the US, 53 of which were located in California, with one in Hawaii.[78]

Oceania

In 2021, the first Australian publicly available hydrogen fuel station opened in Canberra, operated by ActewAGL.[86]

Hydrogen tank

A hydrogen tank (other names- cartridge or canister) is used for hydrogen storage.[87] [88] [89] The first type IV hydrogen tanks for compressed hydrogen at 700bar were demonstrated in 2001, the first fuel cell vehicles on the road with type IV tanks are the Toyota FCHV, Mercedes-Benz F-Cell and the GM HydroGen4.

Low-pressure tanks

Various applications have allowed the development of different H2 storage scenarios.Recently, the Hy-Can[90] consortium has introduced a small one liter, 10bar format. Horizon Fuel Cells is now selling a refillable 3MPa metal hydride form factor for consumer use called HydroStik.[91]

Type I

Type II

Type III

Type IV

Type V

Tank testing and safety considerations

See main article: Hydrogen safety.

In accordance with ISO/TS 15869 (revised):

This specification was replaced by ISO 13985:2006 and only applies to liquid hydrogen tanks.

Actual Standard EC 79/2009

Metal hydride storage tank

Magnesium hydride

Using magnesium[98] for hydrogen storage, a safe but weighty reversible storage technology. Typically the pressure requirement are limited to 10bar.The charging process generates heat whereas the discharge process will require some heat to release the H2 contained in the storage material. To activate these types of hydrides, at the current state of development you need to reach approximately 300C. [99] [100] [101]

Other hydrides

See also sodium aluminium hydride

Research

See also

Sources

External links

Notes and References

  1. Web site: Hydrogen infrastructure project launches in USA . 14 May 2013.
  2. Web site: Fuel cell electric vehicles and hydrogen infrastructure: status 2012. Eberle. Ulrich. Bernd. Mueller. Rittmar. von Helmolt. . 23 December 2014.
  3. Web site: Japan's Hydrogen Strategy and Its Economic and Geopolitical Implications . live . https://web.archive.org/web/20190210050005/https://www.ifri.org/en/publications/etudes-de-lifri/japans-hydrogen-strategy-and-its-economic-and-geopolitical-implications . 10 February 2019 . 9 February 2019 . Etudes de l'Ifri.
  4. South Korea's Hydrogen Economy Ambitions . live . https://web.archive.org/web/20190209232214/https://thediplomat.com/2019/01/south-koreas-hydrogen-economy-ambitions/ . 9 February 2019 . 9 February 2019 . The Diplomat.
  5. Web site: 7 March 2020 . The world's largest-class hydrogen production, Fukushima Hydrogen Energy Research Field (FH2R) now is completed at Namie town in Fukushima. . live . https://web.archive.org/web/20200422195459/https://www.toshiba-energy.com/en/info/info2020_0307.htm . 22 April 2020 . 1 April 2020 . Toshiba Energy Press Releases . Toshiba Energy Systems and Solutions Corporations.
  6. Web site: Patel . Sonal . 2022-07-01 . Fukushima Hydrogen Energy Research Field Demonstrates Hydrogen Integration . 2023-10-05 . POWER Magazine . en-US.
  7. http://news.bbc.co.uk/2/hi/technology/7496644.stm Running on home-brewed hydrogen
  8. http://www.leightyfoundation.org/files/WHEC16-Lyon/WHEC16-Ref022.pdf Compressorless Hydrogen Transmission Pipelines
  9. https://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/hpwgw_airprod_remp.pdf DOE Hydrogen Pipeline Working Group Workshop
  10. http://www.hydrogenforecast.com/ArticleDetails.php?articleID=250 Every 50to
  11. Web site: Critical Review of ASME B31.12 for Pipeline Transmission of Hydrogen . . 2024-04-30 . 2024-08-20.
  12. Web site: Energy Transition Hydrogen pipelines are making progress around the world. These countries are leading the way . World Economic Forum . 2023-12-13 . 2024-08-20.
  13. Web site: Bhadhesia . Harry . Prevention of Hydrogen Embrittlement in Steels . live . https://web.archive.org/web/20201111174451/https://www.phase-trans.msm.cam.ac.uk/2016/preventing_hydrogen.pdf . 11 November 2020 . 17 December 2020 . Phase Transformations & Complex Properties Research Group, Cambridge University.
  14. Milibrand, A. and Mann, M. “Potential for Hydrogen Production from Key Renewable Resources in the United States”. “National Renewable Energy Laboratory”, February 2007. Retrieved 2 August 2011.
  15. Dincer. Ibrahim. Acar. Canan. 2015. Review and evaluation of hydrogen production methods for better sustainability. International Journal of Hydrogen Energy. 40. 34. 11096. 10.1016/j.ijhydene.2014.12.035. 2015IJHE...4011094D . 0360-3199.
  16. Web site: The world´s largest-class hydrogen production, Fukushima Hydrogen Energy Research Field (FH2R) now is completed at Namie town in Fukushima. . 7 March 2020 . Toshiba Energy Press Releases . Toshiba Energy Systems and Solutions Corporations . 1 April 2020 . 22 April 2020 . https://web.archive.org/web/20200422195459/https://www.toshiba-energy.com/en/info/info2020_0307.htm . dead .
  17. Web site: Opening Ceremony of Fukushima Hydrogen Energy Research Field (FH2R) Held with Prime Minister Abe and METI Minister Kajiyama . 9 March 2020 . METI News Releases . Ministry of Economy, Trade and Industry . 1 April 2020 .
  18. Web site: The Technological Steps of Hydrogen Introduction - pag 24 . 2008-08-29 . https://web.archive.org/web/20081029214321/http://www.storhy.net/train-in/PDF-TI/03_StorHy-Train-IN-Session-1_3_JToepler.pdf . 2008-10-29 . dead .
  19. Web site: rise.org - Pipelines . 2008-08-29 . 2009-07-28 . https://web.archive.org/web/20090728010121/http://www.rise.org.au/info/Res/hydrogen/index.html . dead .
  20. http://www.airliquide.com/file/otherelementcontent/pj/2006-press_kit_hydrogen-en58778.pdf 2006 - vector of clean energy - pag 15
  21. http://www.airproducts.com/PressRoom/CompanyNews/Archived/2009/02Mar2009.htm Hydrogen Pipeline Extension Strengthens Gulf Coast Network
  22. http://www1.eere.energy.gov/hydrogenandfuelcells/pdfs/hpwgw_airprod_remp.pdf 2005 DOE Hydrogen Pipeline Working Group Workshop
  23. Web site: Natural gas pipelines for hydrogen transportation . 27 February 2024 . 19 February 2024 . https://web.archive.org/web/20240219100020/https://www.cder.dz/A2H2/Medias/Download/Proc%20PDF/POSTERS/%5BGIV%5D%20Liquid%20%26%20gaseous%20storage%2C%20delidevy%2C%20safety%2C%20RCS/222.pdf . dead .
  24. http://www.leightyfoundation.org/wp-content/uploads/whec16-lyon/WHEC16-Ref022.pdf 2006 - Compressorless Hydrogen Transmission Pipelines Deliver Large-scale Stranded Renewable Energy at Competitive Cost
  25. http://www.hydrogenforecast.com/ArticleDetails.php?articleID=250 Every 50 to 100 miles
  26. http://avt.inel.gov/pdf/hydrogen/h2station_appendixc.pdf Idaho national Engineering Laboratory Recommendations for Piping for Gaseous Hydrogen
  27. Web site: 2007 - Fiber Fiber-Reinforced Polymer Pipelines . 27 February 2024 . 27 January 2017 . https://web.archive.org/web/20170127203440/https://www.hydrogen.energy.gov/pdfs/review07/pd_14_smith.pdf . dead .
  28. Web site: NEW, COMPOSITE POLYMERIC/METALLIC MATERIALS AND DESIGNS FOR HYDROGEN PIPELINES . 2008-08-29 . https://web.archive.org/web/20081008153102/http://www.hydrogendiscoveries.com/NHApipelinepaper.pdf . 2008-10-08 . dead .
  29. Web site: 2006 FRP Hydrogen Pipelines . 27 February 2024 . 7 February 2017 . https://web.archive.org/web/20170207084540/https://www.hydrogen.energy.gov/pdfs/progress06/iii_a_2_smith.pdf . dead .
  30. Web site: Lifetime Simulation Composite & Multilayer Pipelines . 2009-11-02 . https://web.archive.org/web/20120207024810/http://www.composite-agency.com/product.htm . 2012-02-07 . dead .
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  32. Al-Ahmed, Amir, Safdar Hossain, Bello Mukhtar et al. "Hydrogen highway: An overview", IEEE.org, December 2010
  33. Woodrow, Melanie. "Bay Area experiences hydrogen shortage after explosion", ABC news, June 3, 2019
  34. Review of Transportation Hydrogen Infrastructure Performance and Reliability . National Renewable Energy Laboratory. 2019. 10.1016/j.ijhydene.2019.03.027 . October 7, 2020 . Kurtz . Jennifer . Sprik . Sam . Bradley . Thomas H. . International Journal of Hydrogen Energy . 44 . 23 . 12010–12023 . 2019IJHE...4412010K .
  35. https://www.power-technology.com/comment/standing-at-the-precipice-of-the-hydrogen-economy "Realising the hydrogen economy"
  36. https://protium.aero/our-technology/transportable-hydrogen-dispensing "Transportable Hydrogen Dispensing"
  37. D. . Apostolou . G. . Xydis . 2019 . A literature review on hydrogen refuelling stations and infrastructure. Current status and future prospects . Renewable and Sustainable Energy Reviews . 113 . 109292 . 10.1016/j.rser.2019.109292. 2019RSERv.11309292A . 201240559 .
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  39. Web site: SAE International -- mobility engineering. 4 October 2016.
  40. Can Samsun . Remzi . Antoni . Laurent . Rex . Michael . Stolten . Detlef . 2021 . Deployment Status of Fuel Cells in Road Transport: 2021 Update . International Energy Agency (IEA) Advanced Fuel Cells Technology Collaboration Programme (AFC TCP) . Forschungszentrum Jülich.
  41. Web site: Infrastructure 37 new H2 refuelling stations built in Europe in 2023 . Electrive.com . 2024-01-02 . Chris Randall. 2024-08-19 .
  42. https://protium.aero/our-technology/transportable-hydrogen-dispensing "Transportable Hydrogen Dispensing"
  43. Another off-site concept, by Bioenergy Concept GmbH, which has not been commercialized, involves filling hydrogen in cartridges and transporting them to a filling station, where the empty cartridges are replaced with new ones. See Web site: Bioenergy Concept GmbH - Your Expert for Bioenergy Projects . 2022-04-08 . Bioenergy Concept GmbH. and News: Patent für Wasserstofftankstelle . It is hoped that this process would save about 33% of energy (Kwh/KgH2) used by conventional transportation. See Web site: DOE Hydrogen and Fuel Cells Program Record .
  44. https://www.hydrogencarsnow.com/index.php/home-hydrogen-fueling-stations/ Hydrogenics HomeFueler as a home hydrogen fueling station
  45. https://residentialhydrogenpower.com/wp-content/uploads/2019/08/Specification-8-2019-MRE-SHFA-Model-300.pdf "SHFA Model 300"
  46. Hydrogen Purification . 67 . 42 . Home Power . dead . https://web.archive.org/web/20060813154525/http://www.homepower.com/files/Hp67p42.pdf . 2006-08-13 .
  47. Web site: Pressure Products Industries, Inc. . Diaphragm Compressors . 2007-06-23 . dead . https://web.archive.org/web/20070921020954/http://www.gotoppi.com/compressors/compressors.html . 2007-09-21 .
  48. See, for example, Lincoln Composites Tuffshell tanks, as recommended by Roy McAlister in the "Hydrogen Car and Multi Fuel Engine" DVD
  49. Solar Hydrogen Production by Electrolysis . Home Power . 39 . February–March 1994 . 2007-06-23.
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  51. News: Exploding hydrogen station leads to FCV halt. EV Talk. Geoff. Dobson. 12 June 2019.
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  53. Web site: How many gas stations are there in the U.S?. 4 October 2016.
  54. Book: Romm, Joseph . 2004 . The Hype about Hydrogen, Fact and Fiction in the Race to Save the Climate . registration . New York . Island Press . 978-1-55963-703-9. Chapter 5
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