Greenalite Explained

Greenalite
Category:Phyllosilicates
Kaolinite-serpentine group
Formula:(Fe2+,Fe3+)2-3Si2O5(OH)4
Imasymbol:Gre[1]
Strunz:9.ED.15
System:Monoclinic
Class:Domatic (m)
(same H-M symbol)
Symmetry:Cm
Unit Cell:a = 5.54, b = 9.55
c = 7.44 [Å]; β = 104.2°; Z = 2
Color:Green, light yellow-green
Habit:Rare minute crystals, rounded grains common; as porphyroblasts, oolites
Cleavage:None
Mohs:2.5
Luster:Dull, earthy
Streak:Greenish-gray
Diaphaneity:Translucent to subopaque
Gravity:2.85 - 3.15
Opticalprop:Biaxial (+)
Refractive:nα = 1.650 - 1.675 nβ = 1.674 nγ = 1.674
Birefringence:δ = 0.024
Pleochroism:X = pale yellow, Y and Z = green
Other:Magnetic
References:[2] [3]

Greenalite is a mineral in the kaolinite-serpentine group with the chemical composition (Fe2+,Fe3+)2-3Si2O5(OH)4.[4] [5] It is a member of the serpentine group.[2]

Occurrence

Greenalite was first described in 1903 for an occurrence in the Mesabi Range near Biwabik, St. Louis County, Minnesota and named for its green color.[2]

Greenalite occurs as a primary mineral in banded iron formations. Rocks which contain greenalite are usually bright green, pale green or pale brown. Greenalite occurs with quartz, stilpnomelane, siderite, chamosite, pyrite and minnesotaite. It is commonly oolitic.[4]

Effect on early life

Greenalite, which is common in Archean rocks, formed rapidly in Archean seawater removing zinc, copper and vanadium in the process. This left the seawater rich in manganese, molybdenum, and cadmium, which are metals favoured by lifeforms at that time. Experiments have shown that the removed metals would have been removed permanently, having a significant effect on early seawater.[6]

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://www.mindat.org/min-1745.html Greenalite on Mindat.org
  3. http://www.webmineral.com/data/Greenalite.shtml Greenalite on Webmineral
  4. http://rruff.geo.arizona.edu/doclib/hom/greenalite.pdf Handbook of Mineralogy
  5. Sleep N.H., Bird D.K. (2007): Niches of the pre-photosynthetic biosphere and geologic preservation of Earth’s earliest ecology. Geobiology 5, 101-117
  6. Web site: Recreation of ancient seawater reveals which nutrients shaped the evolution of early life . University of Oxford . 13 November 2023 . 2023-11-20 . www.ox.ac.uk . en.