Gold chalcogenides explained

Gold chalcogenides are compounds formed between gold and one of the chalcogens, elements from group 16 of the periodic table: oxygen, sulfur, selenium, or tellurium.

• Gold(III) oxide, Au₂O₃. Decomposes into gold and oxygen above 160 °C, and dissolves in concentrated alkalis to form solutions which probably contain the [Au(OH)₄]^- ion
• Gold(I) sulfide, Au₂S. Formed by reaction of hydrogen sulfide with gold(I) compounds.
• Gold(III) sulfide, Au₂S₃, claimed material but unsubstantiated.
• Gold tellurides: Au₂Te₃, Au₃Te₅, and AuTe₂ (approximate formulas) are known as non-stoichiometric compounds. They show metallic conductivity. Au₃Te₅ is a superconductor at 1.62 K.^[1]

Gold telluride minerals, such as calaverite and krennerite (AuTe₂), petzite (Ag₃AuTe₂), and sylvanite (AgAuTe₂), are minor ores of gold (and tellurium). See telluride minerals for more information.

Notes and References

1. Luo. H.L.. Merriam. M.F.. Hamilton. D.C.. Superconducting Metastable Compounds. Science. 1964. 145. 3632. 581–583. 10.1126/science.145.3632.581. 17735806. 1964Sci...145..581L. 41529555.