Freezing food preserves it from the time it is prepared to the time it is eaten. Since early times, farmers, fishermen, and trappers have preserved grains and produce in unheated buildings during the winter season.[1] Freezing food slows decomposition by turning residual moisture into ice, inhibiting the growth of most bacterial species. In the food commodity industry, there are two processes: mechanical and cryogenic (or flash freezing). The freezing kinetics is important to preserve the food quality and texture. Quicker freezing generates smaller ice crystals and maintains cellular structure. Cryogenic freezing is the quickest freezing technology available due to the ultra low liquid nitrogen temperature -196C.[2]
Preserving food in domestic kitchens during modern times is achieved using household freezers. Accepted advice to householders was to freeze food on the day of purchase. An initiative by a supermarket group in 2012 (backed by the UK's Waste & Resources Action Programme) promotes the freezing of food "as soon as possible up to the product's 'use by' date". The Food Standards Agency was reported as supporting the change, provided the food had been stored correctly up to that time.[3]
Frozen products do not require any added preservatives because microorganisms do not grow when the temperature of the food is below -9.5C, which is sufficient on its own in preventing food spoilage. Long-term preservation of food may call for food storage at even lower temperatures. Carboxymethylcellulose (CMC), a tasteless and odorless stabilizer, is typically added to frozen food because it does not adulterate the quality of the product.[4]
Natural food freezing (using winter frosts) had been in use by people in cold climates for centuries.
In 1861 Thomas Sutcliffe Mort established at Darling Harbour in Sydney, Australia, the world's first freezing works, which later became the New South Wales Fresh Food and Ice Company. Mort financed experiments by Eugene Dominic Nicolle, a French born engineer who had arrived in Sydney in 1853 and registered his first ice-making patent in 1861. The first trial shipment of frozen meat to London was in 1868. Although their machinery was never used in the frozen meat trade, Mort and Nicolle developed commercially viable systems for domestic trade. The financial return on that investment was minimal for Mort. Regular shipments of frozen meat from Australia and New Zealand to Europe began in 1881, with a consignment of frozen New Zealand sheep exported to London on board the Dunedin.
By 1885 a small number of chickens and geese were being shipped from Russia to London in insulated cases using this technique. By March 1899, the "British Refrigeration and Allied Interests" reported that a food importing business, "Baerselman Bros", was shipping some 200,000 frozen geese and chickens per week from three Russian depots to New Star Wharf, Lower Shadwell, London over three or four winter months. This trade in frozen food was enabled by the introduction of Linde cold air freezing plants in three Russian depots and the London warehouse. The Shadwell warehouse stored the frozen goods until they were shipped to markets in London, Birmingham, Liverpool and Manchester. The techniques were later expanded to the meat-packing industry.
From 1929, Clarence Birdseye introduced "flash freezing" to the American public. Birdseye first became interested in food freezing during fur-trapping expeditions to Labrador in 1912 and 1916, where he saw the natives use natural freezing to preserve foods.[5] A 1920s hunting trip to Canada, where he witnessed the traditional methods of the indigenous Inuit people, directly inspired Birdseye's food preserving method.[6]
The Icelandic Fisheries Commission was created in 1934 to initiate innovation in the industry, and encouraged fishermen to start quick-freezing their catch.Íshúsfélag Ísfirðinga, one of the first frozen fish companies, was formed in Ísafjörður, Iceland, by a merger in 1937.More advanced attempts include food frozen for Eleanor Roosevelt on her trip to Russia. Other experiments involving orange juice, ice cream and vegetables were conducted by the military near the end of World War II.
The freezing technique itself, just like the frozen food market, is developing to become faster, more efficient and more cost-effective. As demonstrated by Birdseye's work, faster freezing means smaller ice crystals and a better-preserved product.[7]
Birdseye's original cryogenic freezing approach using immersion in liquid nitrogen is still used.[8] Due to its cost, however, use is limited to fish fillets, seafood, fruits, and berries. It is also possible to freeze food by immersion in the warmer (at -70C), but cheaper, liquid carbon dioxide, which can be produced by mechanical freezing (see below).[7]
Most frozen food is instead frozen using a mechanical process using the vapor-compression refrigeration technology similar to ordinary freezers. Such a process is cheaper at scale, but is usually slower. (There is also more upfront investment in the form of construction.) Nevertheless, a wide variety of processes have been devised to achieve faster heat transfer from the food to the refrigerant:[7]
Individual Quick Freezing is a descriptive term that includes all forms of freezing that is "individual" (not in a whole block) and "quick" (taking a maximum of several minutes). It may correspond to cryogenic freezing, fluidized bed freezing, or any other technique that meets the definition.
Frozen food packaging must maintain its integrity throughout filling, sealing, freezing, storage, transportation, thawing, and often cooking.[9] As many frozen foods are cooked in a microwave oven, manufacturers have developed packaging that can go directly from freezer to the microwave.
In 1974, the first differential heating container (DHC) was sold to the public. A DHC is a sleeve of metal designed to allow frozen foods to receive the correct amount of heat. Various sized apertures were positioned around the sleeve. The consumer would put the frozen dinner into the sleeve according to what needed the most heat. This ensured proper cooking.[10]
Today there are multiple options for packaging frozen foods. Boxes, cartons, bags, pouches, Boil-in-Bags, lidded trays and pans, crystallized PET trays, and composite and plastic cans.[11]
Scientists continue to research new aspects of frozen food packaging. Active packaging offers many new technologies that can actively sense and then neutralize the presence of bacteria or other harmful species. Active packaging can extend shelf-life, maintain product safety, and help preserve the food over a longer period of time. Several functions of active packaging are being researched:
The process of flash freezing itself generally effectively retain the nutrient content of foodstuff with minor losses of vitamins, making them a cost-effective and nutritious substitute from fresh equivalents. However, pre-seasoned frozen food, such as packaged meals, may have a significant amounts of salt and fats added. It is therefore recommended to read the nutrition label and the ingredients list.[13]
Freezing is an effective form of food preservation because the pathogens that cause food spoilage are either killed or do not grow very rapidly at reduced temperatures. The process is less effective in food preservation than are thermal techniques, such as boiling, because pathogens are more likely to be able to survive cold temperatures rather than hot temperatures.[20] One of the problems surrounding the use of freezing as a method of food preservation is the danger that pathogens deactivated (but not killed) by the process will once again become active when the frozen food thaws.
Foods may be preserved for several months by freezing. Long-term frozen storage requires a constant temperature of -18C or less.[21]
To be used, many cooked foods that have been previously frozen require defrosting prior to consumption. Preferably, some frozen meats should be defrosted prior to cooking to achieve the best outcome: cooked through evenly and of good texture.
The defrost system in freezers helps the equipment to perform properly, without thick layers of ice developing, thus preventing the evaporator coil from absorbing heat and cooling the cabinet.
Ideally, most frozen foods should be defrosted in a refrigerator to avoid significant growth of pathogens. However, this can require considerable time.
Food is often defrosted in one of several ways:
People sometimes defrost frozen foods at room temperature because of time constraints or ignorance. Such foods should be promptly consumed after cooking or discarded and never be refrozen or refrigerated since pathogens are not killed by the refreezing process.
The speed of freezing has a direct impact on the size and the number of ice crystals formed within a food product's cells and extracellular space. Slow freezing leads to fewer but larger ice crystals while fast freezing leads to smaller but more numerous ice crystals. This difference in ice crystal size can affect the degree of residual enzymatic activity during frozen storage via the process of freeze concentration, which occurs when enzymes and solutes present in a fluid medium are concentrated between ice crystal formations.[24] Increased levels of freeze concentration, mediated by the formation of large ice crystals, can promote enzymatic browning.[25]
Large ice crystals can also puncture the walls of the cells of the food product which will cause a degradation of the texture of the product as well as the loss of its natural juices during thawing.[26] That is why there will be a qualitative difference observed between food products frozen by ventilated mechanical freezing, non-ventilated mechanical freezing or cryogenic freezing with liquid nitrogen.[27]
According to a 2007 study, an American consumes frozen food on average 71 times a year, most of which are pre-cooked frozen meals.