Forced degradation explained

Forced degradation or accelerated degradation is a process whereby the natural degradation rate of a product or material is increased by the application of an additional stress.

Introduction

Forced degradation studies are used to identify reactions which may occur to degrade a processed product. Usually conducted before final formulation, forced degradation uses external stresses to rapidly screen material stabilities.

Longer-term storage tests are usually used to measure similar properties when final formulations are involved because of the stringent FDA regulations. These tests are generally more expensive (because of the time involved) than forced degradation which is therefore used for rapid selection and elimination tests.

Common stresses

There are a number of common stresses which are used to

Chemical processes are often catalysed by the presence of acids and bases. The exposure of materials to these can therefore accelerate degradation reactions.

In accordance to arrhenius kinetics, increasing temperature increases the rate of any degradation process. Temperature is often used in conjunction with other stresses to increase reaction rates.

Methodologies

Standard methodologies include:

Application

To demonstrate the specificity when developing stability indicating method.To help to identify reactions that cause degradation of pharmaceutical product.As a part of method development strategy.Are designed to generate product related variants.

See also

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