Ferrokentbrooksite Explained

Ferrokentbrooksite
Category:Cyclosilicate
Formula: (original form)
Imasymbol:Fktb[1]
Strunz:9.CO.10 (10 ed)
8/E.23-15 (8 ed)
Dana:64.1.2.2
System:Trigonal
Class:Ditrigonal pyramidal (3m)
H-M symbol: (3m)
Symmetry:R3m
Unit Cell:a = 14.25, c = 30.03 [Å] (approximated); Z = 3
Color:Reddish brown to red
Habit:Pseudo-octahedra
Cleavage:No
Fracture:Uneven to conchoidal
Luster:Vitreous
Streak:White
Diaphaneity:Transparent
Refractive:nω = 1.62, nε = 1.62 (approximated)
Impurities:REE (mainly Ce and Y), K, Sr

Ferrokentbrooksite is a moderately rare mineral of the eudialyte group,[2] with formula .[3] The original formula was extended form to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group.[4] As suggested by its name, it is the (ferrous) iron analogue of kentbrooksite. When compared to the latter, it is also chlorine-dominant instead of being fluorine-dominant. The original (holotype) material is also relatively enriched in rare earth elements, including cerium and yttrium.

Occurrence and association

Ferrokentbrooksite was discovered in Mont Saint-Hilaire, Quebec, Canada – a site wealth in rare alkaline minerals.[5] At the site ferrokentbrooksite coexists with aegirine, albite, ancylite-(Ce), calcite, catapleiite, fluorite, fluorapatite, gonnardite, microcline, natrolite, nepheline, rhodochrosite, and serandite.

Notes on chemistry

Beside fluorine, ferrokentbrooksite has admixtures of rare earth elements (including cerium, yttrium, lanthanum, neodymium and some gadolinium and samarium), potassium, strontium, and contains minor admixtures of titanium, hafnium, and tantalum.

Notes on structure

Iron in ferrokentbrooksite has coordination number 5.

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Mindat, Ferrokentbrooksite, http://www.mindat.org/min-7106.html
  3. Johnsen, O., Grice, J.D., and Gault, R.A., 2003: Ferrokentbrooksite, a new member of the eudialyte group from Mont Saint-Hilaire, Quebec, Canada. The Canadian Mineralogist 41(1), 55–60
  4. Johnsen, O., Ferraris, G., Gault, R.A., Grice, D.G., Kampf, A.R., and Pekov, I.V., 2003. The nomenclature of eudialyte-group minerals. The Canadian Mineralogist 41, 785–794
  5. Web site: Poudrette quarry (Demix quarry; Uni-Mix quarry; Desourdy quarry; Carrière Mont Saint-Hilaire), Mont Saint-Hilaire, La Vallée-du-Richelieu RCM, Montérégie, Québec, Canada - Mindat.org . Mindat.org . 2016-03-11.