Dimethyl-sulfide monooxygenase explained

Dimethyl-sulfide monooxygenase
Ec Number:1.14.13.131

Dimethyl-sulfide monooxygenase (dimethylsulfide monooxygenase) is an enzyme with systematic name dimethyl sulfide,NADH:oxygen oxidoreductase.[1] This enzyme catalyses the following chemical reaction

dimethyl sulfide + O2 + NADH + H+

\rightleftharpoons

methanethiol + formaldehyde + NAD+ + H2O

Dimethyl-sulfide monooxygenase has lower activity with diethyl sulfide and other short-chain alkyl methyl sulfides.[2] [3]

Notes and References

  1. Book: Ulrike . Kappler . Hendrik . Schäfer . Peter M.H. . Kroneck . Martha E. Sosa . Torres . vanc . The Metal-Driven Biogeochemistry of Gaseous Compounds in the Environment . Metal Ions in Life Sciences . 14 . 2014 . Springer . Chapter 11. Transformations of Dimethylsulfide . 279–313 . 10.1007/978-94-017-9269-1_11 . 25416398 .
  2. Dimethyl sulphoxide and dimethyl sulphide as a carbon, sulphur and energy source for growth of Hyphomicrobium S . De Bont . J.A.M. . Van Dijken . J.P. . Harder . W. . vanc . J. Gen. Microbiol. . 1981 . 127 . 2 . 315–323 . 10.1099/00221287-127-2-315.
  3. Boden R, Borodina E, Wood AP, Kelly DP, Murrell JC, Schäfer H . Purification and characterization of dimethylsulfide monooxygenase from Hyphomicrobium sulfonivorans . Journal of Bacteriology . 193 . 5 . 1250–8 . March 2011 . 21216999 . 3067575 . 10.1128/JB.00977-10 .