Delay composition explained

Delay composition, also called delay charge or delay train, is a pyrotechnic composition, a sort of pyrotechnic initiator, a mixture of oxidizer and fuel that burns in a slow, constant rate that should not be significantly dependent on temperature and pressure. Delay compositions are used to introduce a delay into the firing train, e.g. to properly sequence firing of fireworks, to delay firing of ejection charges in e.g. model rockets, or to introduce a few seconds of time between triggering a hand grenade and its explosion. Typical delay times range between several milliseconds and several seconds.

A popular delay charge is a tube of pressed black powder. The mechanical assembly prevents the outright detonation of the charge.

While delay compositions are principally similar to other fuel-oxidizer compositions, larger grain sizes and less aggressively reacting chemicals are used. Many of the compositions generate little or no gas during burning. Typical materials used are:

• Fuels: silicon, boron, manganese, tungsten, antimony, antimony trisulfide, zirconium, zirconium - nickel alloy, zinc, magnesium, etc.
• Oxidizers: lead dioxide, iron oxides, barium chromate, lead chromate, tin(IV) oxide, bismuth(III) oxide, barium sulfate (for high-temperature compositions), potassium perchlorate (usually used in small amount together with other oxidizers), etc.
• Additives to cool down the flame and slow down the reaction can be employed; inert materials or coolants like titanium dioxide, ground glass, chalk, sodium bicarbonate, etc. are common.

The burn rates are dependent on: http://www.allbusiness.com/north-america/canada/689991-1.html

• nature of fuel - fuels that release more heat burn faster
• nature of oxidizer - oxidizers that require less heat to decompose burn faster
• the composition ratio - stoichiometric mixtures burn the fastest, also slight excess of metallic fuel also increases burn rate, probably due to heat transfer
• particle sizes - smaller particles burn faster, but too small particles may lead to incomplete or interrupted burn due to too narrow heating zone
• mechanical assembly and housing - charge diameter and thermal conductivity of housing influence lateral heat losses
• ambient temperature - ideally this dependence is very low but extremely low or extremely high temperatures may have influence

Examples of some compositions are: http://www.freepyroinfo.com/Pyrotechnic/pyro_html/Explosives.htm

• black powder with addition of inert material, e.g. chalk or sodium bicarbonate
• lead(II) oxide with silicon, burning at 1.5–2 cm/s
• red lead with silicon, burning at intermediate rate
• lead(IV) oxide with silicon, burning at 5–6 cm/s
• potassium permanganate with antimony, very slow
• Manganese Delay Composition: manganese with lead chromate and barium chromate (lead chromate is the principal oxidizer, barium chromate acts as burning rate modifier, the more of it the slower the reaction) http://sciencelinks.jp/j-east/article/200109/000020010901A0317367.php^[1]
• Tungsten Delay Composition: tungsten with barium chromate and potassium perchlorate http://www.palmerpatent.com/patent_with_highlight.html?patent_num=4963204&q=additionally^[2]
• Zirconium Nickel Alloy Delay Composition: zirconium-nickel alloy with barium chromate and potassium perchlorate.^[3]
• boron with barium chromate http://www.energetic-materials.org.cn/english/ennews.asp?newsid=10

Notes and References

1. Web site: PYROTECHNIC CHEMISTRY . 2014-06-07 . https://web.archive.org/web/20140508095954/http://www.islandgroup.com/military/pyrotechnic_chemistry.php . 2014-05-08 . dead .
2. Web site: PYROTECHNIC CHEMISTRY . 2014-06-07 . https://web.archive.org/web/20140508095954/http://www.islandgroup.com/military/pyrotechnic_chemistry.php . 2014-05-08 . dead .
3. Web site: PYROTECHNIC CHEMISTRY . 2014-06-07 . https://web.archive.org/web/20140508095954/http://www.islandgroup.com/military/pyrotechnic_chemistry.php . 2014-05-08 . dead .