Abundance of elements in Earth's crust explained

The abundance of elements in Earth's crust is shown in tabulated form with the estimated crustal abundance for each chemical element shown as mg/kg, or parts per million (ppm) by mass (10,000 ppm = 1%).

Reservoirs

The Earth's crust is one "reservoir" for measurements of abundance. A reservoir is any large body to be studied as unit, like the ocean, atmosphere, mantle or crust. Different reservoirs may have different relative amounts of each element due to different chemical or mechanical processes involved in the creation of the reservoir.[1]

Difficulties in measurement

Estimates of elemental abundance are difficult because (a) the composition of the upper and lower crust are quite different, and (b) the composition of the continental crust can vary drastically by locality.[2] The composition of the Earth changed after its formation due to loss of volatile compounds, melting and recrystalization, selective loss of some elements to the deep interior, and erosion by water.[3] The lanthanides are especially difficult to measure accurately.[4]

Graphs of abundance vs atomic number

Graphs of abundance against atomic number can reveal patterns relating abundance to stellar nucleosynthesis and geochemistry.The alternation of abundance between even and odd atomic number is known as the Oddo–Harkins rule. The rarest elements in the crust are not the heaviest, but are rather the siderophile elements (iron-loving) in the Goldschmidt classification of elements. These have been depleted by being relocated deeper into the Earth's core; their abundance in meteoroids is higher. Tellurium and selenium are concentrated as sulfides in the core and have also been depleted by preaccretional sorting in the nebula that caused them to form volatile hydrogen selenide and hydrogen telluride.[5]

List of abundance by element

This table gives the estimated abundance in parts per million by mass of elements in the continental crust; values of the less abundant elements may vary with location by several orders of magnitude.[6]

Abundance of chemical elements in Earth's (continental) crust
ZElementSymbolGoldschmidt
classification
data-sort-type=number style="border-right:2px solid #b8b8b8" Abundance (ppm)data-sort-type=number Production
tonnes/year[7]
8oxygenOLithophile data-sort-value=461,000461,000 (46.1%)10,335,000[8]
14siliconSiLithophile data-sort-value=282,000282,000 (28.2%)7,200,000
13aluminiumAlLithophile data-sort-value=82,30082,300 (8.23%)57,600,000
26ironFeSiderophiledata-sort-value=56,30056,300 (5.63%)1,150,000,000
20calciumCaLithophile data-sort-value=41,50041,500 (4.15%)18,000
11sodiumNaLithophile data-sort-value=23,60023,600 (2.36%)255,000,000
12magnesiumMgLithophile data-sort-value=23,30023,300 (2.33%)27,700,000
19potassiumKLithophile data-sort-value=20,90020,900 (2.09%)53,200,000[9]
22titaniumTiLithophile data-sort-value=5,6505,650 (0.565%)6,600,000
1hydrogenHAtmophiledata-sort-value=1,4001,400 (0.14%)75,000,000[10] [11]
15phosphorusPLithophile data-sort-value=1,0501,050 (0.105%)226,000,000[12]
25manganeseMnLithophile data-sort-value=950950 (0.095%)16,000,000
9fluorineFLithophile data-sort-value=585585 (0.0585%)17,000
56bariumBaLithophile data-sort-value=425425 (0.0425%)6,000,000[13]
38strontiumSrLithophile data-sort-value=370370 (0.037%)350,000
16sulfurSChalcophiledata-sort-value=350350 (0.035%)69,300,000
6carbonCAtmophiledata-sort-value=200200 (0.02%)9,700,000,000
40zirconiumZrLithophile data-sort-value=165165 (0.0165%)1,460,000
17chlorineClLithophile data-sort-value=145145 (0.0145%)71,250,000[14]
23vanadiumVLithophile data-sort-value=120120 (0.012%)76,000
24 chromiumCrLithophile data-sort-value=102102 (0.0102%)26,000,000
37rubidiumRbLithophile data-sort-value=9090 (0.009%)2
28nickelNiSiderophiledata-sort-value=8484 (0.0084%)2,250,000
30zincZnChalcophiledata-sort-value=7070 (0.007%)11,900,000
58ceriumCeLithophile data-sort-value=66.566.5 (0.00665%)24,000[15]
29copperCuChalcophiledata-sort-value=6060 (0.006%)19,400,000
60neodymiumNdLithophile data-sort-value=41.541.5 (0.00415%)7,000[16]
57lanthanumLaLithophile data-sort-value=3939 (0.0039%)12,500[17]
39yttriumYLithophile data-sort-value=3333 (0.0033%)6,000
7nitrogenNAtmophiledata-sort-value=1919 (0.0019%)140,000,000
27cobaltCoSiderophiledata-sort-value=2525 (0.0025%)123,000
21scandiumScLithophile data-sort-value=2222 (0.0022%)14[18]
3lithiumLiLithophile data-sort-value=2020 (0.002%)35,000
41niobiumNbLithophile data-sort-value=2020 (0.002%)64,000
31galliumGaChalcophiledata-sort-value=1919 (0.0019%)315
82leadPbChalcophiledata-sort-value=1414 (0.0014%)4,820,000
5boronBLithophile data-sort-value=1010 (0.001%)9,400,000
90thoriumThLithophile data-sort-value=9.69.6 (0.00096%)5,000[19]
59praseodymiumPrLithophile data-sort-value=9.29.2 (0.00092%)2,500[20]
62samariumSmLithophile data-sort-value=7.057.05 (0.000705%)700[21]
64gadoliniumGdLithophile data-sort-value=6.26.2 (0.00062%)400[22]
66dysprosiumDyLithophile data-sort-value=5.25.2 (0.00052%)
68erbiumErLithophile data-sort-value=3.53.5 (0.00035%)500[23]
18argonArAtmophiledata-sort-value=3.53.5 (0.00035%)
70ytterbiumYbLithophile data-sort-value=3.23.2 (0.00032%)
72hafniumHfLithophile data-sort-value=3.03.0 (0.0003%)
55caesiumCsLithophile data-sort-value=3.03.0 (0.0003%)
4berylliumBeLithophile data-sort-value=2.82.8 (0.00028%)220
92uraniumULithophile data-sort-value=2.72.7 (0.00027%)74,119
35bromineBrLithophile data-sort-value=2.42.4 (0.00024%)391,000
50tinSnChalcophiledata-sort-value=9.89.8 (0.00098%)280,000
73tantalumTaLithophile data-sort-value=2.02.0 (0.0002%)1,100
63europiumEuLithophile data-sort-value=2.02.0 (0.0002%)
33arsenicAsChalcophiledata-sort-value=1.81.8 (0.00018%)36,500
32germaniumGeChalcophiledata-sort-value=1.51.5 (0.00015%)155
74tungstenWSiderophiledata-sort-value=1.251.25 (0.000125%)86,400
67holmiumHoLithophile data-sort-value=1.31.3 (0.00013%)
42molybdenumMoSiderophiledata-sort-value=1.21.2 (0.00012%)227,000
65terbiumTbLithophile data-sort-value=1.21.2 (0.00012%)
81thalliumTlChalcophiledata-sort-value=0.850.85 (8.5%)10
71lutetiumLuLithophile data-sort-value=0.80.8 (8%)
69thuliumTmLithophile data-sort-value=0.520.52 (5.2%)
53iodineILithophile data-sort-value=0.450.45 (4.5%)31,600
49indiumInChalcophiledata-sort-value=0.250.25 (2.5%)655
51antimonySbChalcophiledata-sort-value=0.20.2 (2%)130,000
48cadmiumCdChalcophiledata-sort-value=0.150.15 (1.5%)23,000
80mercuryHgChalcophiledata-sort-value=0.0850.085 (8.5%)4,500
47silverAgChalcophiledata-sort-value=0.0750.075 (7.5%)27,000
34seleniumSeChalcophiledata-sort-value=0.050.05 (5%)2,200
46palladiumPdSiderophiledata-sort-value=0.0150.015 (1.5%)208
83bismuthBiChalcophiledata-sort-value=0.00850.0085 (8.5%)10,200
2heliumHeAtmophiledata-sort-value=0.0080.008 (8%)
10neonNeAtmophiledata-sort-value=0.00510.0051 (5.1%)
78platinumPtSiderophiledata-sort-value=0.0050.005 (5%)172
79goldAuSiderophiledata-sort-value=0.0040.004 (4%)3,100
76osmiumOsSiderophiledata-sort-value=0.00150.0015 (1.5%)
52telluriumTeChalcophiledata-sort-value=0.0010.001 (1%)2,200
44rutheniumRuSiderophiledata-sort-value=0.0010.001 (1%)
77iridiumIrSiderophiledata-sort-value=0.0010.001 (1%)
45rhodiumRhSiderophiledata-sort-value=0.0010.001 (1%)
75rheniumReSiderophiledata-sort-value=0.00070.0007 (7%)47.2
36kryptonKrAtmophiledata-sort-value=0.00010.0001 (1%)
54xenonXeAtmophiledata-sort-value=3e-53 (3%)
91protactiniumPatracedata-sort-value=1.4e-61.4 (1.4%)
88radiumRatracedata-sort-value=9e-79 (9%)
84poloniumPotracedata-sort-value=2e-102 (2%)
94plutoniumPutracedata-sort-value=3e-113 (3%)
93neptuniumNptracedata-sort-value=3e-123 (3%)
43technetiumTctracedata-sort-value=1.35e-121.35 (1.35%)
89actiniumActracedata-sort-value=6e-136 (6%)
86radonRntracedata-sort-value=4e-134 (4%)
61promethiumPmtracedata-sort-value=2e-172 (2%)
87franciumFrtracedata-sort-value=1e-181 (1%)
85astatineAttracedata-sort-value=3e-203 (3%)

Further reading

External links

Notes and References

  1. Book: Albarède, Francis . Geochemistry: An Introduction . 2009-06-25 . Cambridge University Press . 978-0-521-88079-4 . 2 . 10.1017/cbo9780511807435.005.
  2. Kring, David A. "Composition of Earth's continental crust as inferred from the compositions of impact melt sheets". 28th Annual Lunar and Planetary Science Conference, March 17–21, 1997, Houston, TX, p. 763. Vol. 28. 1997.
  3. Suess . Hans E. . Abundances of the Elements . Urey . Harold C. . Reviews of Modern Physics . 1956-01-01 . 28 . 53–74 . en . 10.1103/RevModPhys.28.53 . 0034-6861.
  4. Surendra P. Verma, E. Santoyo & Fernando Velasco-Tapia (2002) "Statistical Evaluation of Analytical Methods for the Determination of Rare-Earth Elements in Geological Materials and Implications for Detection Limits", International Geology Review, 44:4, 287–335, (note geochemists refer to lanthanides as rare earth per ref.).
  5. Anderson, Don L.; "Chemical Composition of the Mantle", Theory of the Earth, pp. 147–175
  6. ABUNDANCE OF ELEMENTS IN THE EARTH’S CRUST AND IN THE SEA, CRC Handbook of Chemistry and Physics, 97th edition (2016–2017), sec. 14, pg. 17
  7. 2016 extraction per Commodity Statistics and Information. USGS. All production numbers are for mines, except for Al, Cd, Fe, Ge, In, N, Se (plants, refineries), S (all forms) and As, Br, Mg, Si (unspecified). Data for B, K, Ti, Y are given not for the pure element but for the most common oxide, data for Na and Cl are for NaCl. For many elements like Si, Al, data are ambiguous (many forms produced) and are taken for the pure element. U data is pure element required for consumption by current reactor fleet http://www.world-nuclear.org/info/Facts-and-Figures/World-Nuclear-Power-Reactors-and-Uranium-Requirements/ . WNA.
  8. Web site: Oxygen Supply Chain – Executive Summary . 2024-05-23.
  9. Web site: Canada . Natural Resources . 2018-01-23 . Potash facts . 2024-05-23 . natural-resources.canada.ca.
  10. Web site: 2024-05-29 . Hydrogen . 2024-05-23 . www.irena.org . en.
  11. Web site: Hydrogen Production . 2024-05-23.
  12. Web site: Phosphate rock production capacity worldwide . 2024-05-23 . Statista . en.
  13. Web site: Barium - Element information, properties and uses Periodic Table . 2024-05-23 . www.rsc.org.
  14. Web site: Chlorine global market volume 2030 . 2024-05-23 . Statista . en.
  15. Web site: MMTA . Cerium . 2024-05-23 . MMTA . en-US.
  16. Web site: Neodymium - Elements Database . 2024-05-23 . www.elementsdatabase.com.
  17. Web site: MMTA . Lanthanum . 2024-05-23 . MMTA . en-US.
  18. Exploring global supply and demand of scandium oxide in 2030 . 2023 . 10.1016/j.jclepro.2023.136673 . 2024-05-23 . Phoung . Sinoun . Williams . Eric . Gaustad . Gabrielle . Gupta . Ajay . Journal of Cleaner Production . 401 .
  19. Web site: Emsley2010-09-01T00:00:00+01:00 . John . Thorium . 2024-05-23 . RSC Education . en.
  20. Web site: Praseodymium (Pr) - Chemical properties, Health and Environmental effects . 2024-05-23 . www.lenntech.com.
  21. Web site: MMTA . Samarium . 2024-05-23 . MMTA . en-US.
  22. Web site: Gadolinium (Gd) . 2024-05-23 . RWMM . en.
  23. Web site: Erbium (Er) - Chemical properties, Health and Environmental effects . 2024-05-23 . www.lenntech.com.