Clinozoisite Explained

Clinozoisite
Category:Sorosilicates
Epidote group
Formula:Ca2Al3(Si2O7)(SiO4)O(OH)
Imasymbol:Czo[1]
Strunz:9.BG.05a
Dana:58.2.1a.4
System:Monoclinic
Class:Prismatic (2/m)
(same H-M symbol)
Symmetry:P21/m
Unit Cell:a = 8.879, b = 5.583
c = 10.155 [Å]; β = 115.50°; Z = 2
Color:Colorless, green, gray, light green, yellow green, pink
Habit:Elongated primatic crystals, striated; granular to fibrous
Twinning:Lamellar on uncommon
Cleavage:Perfect on
Fracture:Irregular/uneven
Tenacity:Brittle
Mohs:6–7
Luster:Vitreous
Streak:Grayish white
Diaphaneity:Transparent to translucent
Gravity:3.3–3.4
Opticalprop:Biaxial (+)
Refractive:nα = 1.706 – 1.724 nβ = 1.708 – 1.729 nγ = 1.712 – 1.735
Birefringence:δ = 0.006 – 0.011
2V:14 to 90° measured
References:[2] [3] [4]

Clinozoisite is a complex calcium aluminium sorosilicate mineral with formula: Ca2Al3(Si2O7)(SiO4)O(OH). It forms a continuous solid solution series with epidote by substitution of iron(III) in the aluminium (m3 site) and is also called aluminium epidote.[2]

Clinothulite is a manganese bearing variety with a pinkish hue due to substitution of Mn(III) in the aluminium site.[5]

It was originally discovered in 1896 in East Tyrol, Austria, and is so-named because of its resemblance to zoisite and its monoclinic crystal structure.[2]

It occurs in rocks which have undergone low to medium grade regional metamorphism and in contact metamorphism of high calcium sedimentary rocks. It also occurs in saussurite alteration of plagioclase.[3]

Jadeite bearing pyroxene minerals have suggested clinozoisite and paragonite are associated and derived from lawsonite releasing quartz and water via the following reaction:[6]

4CaAl2Si2O8(H2O)2 + NaAlSi2O6 <=> 2Ca2Al3Si3O12(OH) + NaAl3Si3O10(OH)2 + SiO2 + 6H2O

References

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://www.mindat.org/min-1087.html Clinozoisite
  3. Web site: Clinozoisite in the Handbook of Mineralogy . 2014-03-24 . 2015-09-24 . https://web.archive.org/web/20150924052813/http://www.handbookofmineralogy.com/pdfs/clinozoisite.pdf . dead .
  4. http://webmineral.com/data/Clinozoisite.shtml Clinozoisite data on Webmineral
  5. http://www.mindat.org/min-27132.html Clinothulite on Mindat
  6. Book: Deer, William A. . Single-chain Silicates, Volume 2A . 1997 . Geological Society of London. 477.