Chromium(II) acetylacetonate explained

Chromium(II) acetylacetonate is the coordination compound with the formula Cr(O2C5H7)2. It is the homoleptic acetylacetonate complex of chromium(II). It is an air-sensitive, paramagnetic yellow brown solid. According to X-ray crystallography, the Cr center is square planar.[1] In contrast to the triplet ground state for this complex, the bis(pyridine) adduct features noninnocent acac2- ligand attached to Cr(III).[2]

See also

References

  1. Cotton. F. A.. Rice. C. E.. Rice. G. W.. The Crystal and Molecular Structures of Bis(2,4-pentanedionato)chromium. Inorganica Chimica Acta. 1977. 24. 231-234. 10.1016/S0020-1693(00)93880-5.
  2. 10.1039/d0sc01836h. Ligand field-actuated redox-activity of acetylacetonate . 2020 . Vinum . Morten Gotthold . Voigt . Laura . Hansen . Steen H. . Bell . Colby . Clark . Kensha Marie . Larsen . René Wugt . Pedersen . Kasper S. . Chemical Science . 11 . 31 . 8267–8272 . 34094180 . 8163028 .

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