Nitride chloride explained

A chloride nitride is a mixed anion compound containing both chloride (Cl−) and nitride ions (N3−). Another name is metallochloronitrides. They are a subclass of halide nitrides or pnictide halides.[1]

The group 4 element chloride nitrides can be intercalated by alkali metals that supply extra electrons, and other molecules such as from solvents like tetrahydrofuran, yielding layered substances that are superconductors. A superconductor transition temperature Tc of 25.5K has been achieved.[2]

Production

Nitride chlorides may be produced by heating metal nitrides with metal chlorides. The ammonolysis process heats a metal chloride with ammonia.[3] A related method heats a metal or metal hydride with ammonium chloride. The nitrogen source could also be an azide or an amide.

List

nameformulaformula
weight		crystal
system		space
group		unit cell Åvolumedensitycommentsref
Li4NClhexagonalR3a=366.225 c=1977.18 Z=3[4]
Li1.8N0.4Cl0.6Li ion conductor[5]
Cyanogen chlorideClCNmolecular
Magnesium nitride chlorideMg2NClhexagonalRma = 3.2994 c = 17.857[6]
phosphonitrilic chloride cyclic trimerP3N3Cl6molecular
trithiazyl trichlorideS3N3Cl3cas 5964-00-1[7]
Ca2NClhexagonalRma 3.6665 c 19.7187[8]
Sc2Cl2NPm1a = 3:517 c = 8.813layered
Sc4Cl6NorthorhombicPbama = 11.625, b = 12.118, c = 3.5447
Sc5Cl8NC2/ma = 17.85, b = 3.5505, c = 12.090, β = 130.13
Sc7Cl12NR3a = 12.990, c = 8.835Sc6N clusters
Titanium nitride chlorideTiNClorthorhombicPmmna=3.275 b=3.967 c=8.402a = 3.937, b = 3.258, c = 7.803109.2black[9]
Li0.6TiNCl
Cl3VNCltriclinicPa = 7.64, b = 7.14, c = 5.91, α = 94.9, β = 112.4, γ = 107.8V=NCl complex
Zn2NCl180.20orthorhombicPna21a=6.137 b=7.394 c=5.940 Z=4269.54.441band gap 3.21 eV[10]
Zn2NClorthorhombicPnmaZ=16predicted[11]
Zn2NClhexagonalRmpredicted
Sr2BN2Cl[12]
α-Y2Cl3NorthorhombicPbcna = 12.761, b = 6.676, c = 6.1000
β-Y2Cl3NC2/ma = 15.248, b = 3.8520, c = 10.157, β = 118.41
α-ZrNClorthorhombicPmmna = 3.937, b = 3.258, c = 7.803pale yellow-green
β-zirconium nitride chlorideβ-ZrNClhexagonalRma = 3.6031, c = 27.672yellow-green;semiconductor; layers of Cl–Zr–N–N–Zr–Cl[13]
Zr6Cl15NcubicIa3da = 21.171
Lithium-intercalated β-zirconium nitride chlorideLixZrNClblack; superconductor Tc=12.5 K[14]
NaxZrNClsuperconductor Tc 15 K
KxZrNClsuperconductor Tc 15 K
molybdenum nitride chlorideMoNCl3triclinicPa = 9.14, b = 7.67, c = 8.15, α = 108.8, β = 99.3, γ= 108.6
Mo2NCl7triclinicPa = 9.057, b = 9.754, c = 12.834, α = 103.13, β = 109.83, γ = 98.58
Mo2NCl8monoclinicP2/ca = 9.961, b = 6.294, c = 17.808, β = 101.82
Phenyldiazonium tetrachloronitridomolybdateC6H5N2[MoNCl<sub>4</sub>]monoclinicP21/ca = 12.83, b = 11.70, c = 19.22 β = 94.11 Z=2dark red[15]
Technetium chloride nitrideTcCl3Nblack; cas 154525-32-3
(Ph4As)[TcNCl<sub>4</sub>][16]
[Se<sub>3</sub>N<sub>2</sub>Cl]+SbCl6-triclinicP1a=6.982 b=6.997 c=15.105 α = 89.45°, β = 86.18°, γ = 68.22° Z=2red[17]
Ba2NClhexagonalRm
Ba3Si3N5OClP2ca=9.560 c=5.552[18]
Ba25Nb5N19Cl18
LiBa4[Mo<sub>2</sub>N<sub>7</sub>]BaCl2
La2NCl3orthorhombicIbama = 13.758, b = 6.922, c = 6.185[19]
La2Cl(CN2)NorthorhombicCmmma = 13.340, b = 9.5267, c = 3.9402, Z=4[20]
La6N3S4ClorthorhombicPnmaa = 11.597; b = 4.1095; c = 27.568 Z=4[21]
CeNCltetragonalP4/nmma=4.079 c=6.837 Z=black[22]
Cerium(III) nitride chlorideCe2NCl3orthorhombicIbama = 13.6021 b=6.8903 c= 6.1396 Z=4575.424.624Light yellow[23]
Ce2Cl(CN2)NorthorhombicCmmma = 13.3914, b = 9.6345, c = 3.9568, Z=4
Ce6Cl12N21294.1monoclinicP21/ca=11.233 b=16.527 c=10.798 β =90.15 Z=419884.324yellow
Na2[{(ON)Ce<sub>4</sub>}Cl<sub>9</sub>]monoclinicP21/ma = 8.1321, b = 11.4613, c = 9.4286 and β = 107.504° Z=2[24]
Pr2NCl3orthorhombicIbama = 13.531, b = 6.8512, c = 6.1072
Pr5N3S2Cl2monoclinicC2/ma = 15.402; b = 4.0092; c = 16.563; β = 101.24°, Z = 4[25]
Pr6N3S4ClorthorhombicPnmaa=11.3987 b=4.0235 c=26.999 Z=41238.3reddish-brown[26]
Nd2NCl3orthorhombicPbcna = 13.382, b = 6.8462, c = 6.1815
Nd3NCl6orthorhombicPbcaa = 10.4971, b = 11.0683, c = 16.211; Z = 8[27]
Nd4NS3Cl3hexagonalP63mca = 9.2278, c = 6.8306; Z = 2
Nd6N3S4ClorthorhombicPnmaa = 11.371; b = 3.9934; c = 26.876
Na2Nd4ONCl9monoclinicP21/ma = 8.0354, b = 11.3426, c = 9.2831 and β = 107.109°[28]
Trigadolinium hexachloride nitrideGd3Cl6N698.485triclinicPa = 7.107, b = 8.156, c = 9.707, α = 75.37°, β = 109.10°, γ = 114.64° Z=2478.84.84colourless; water sensitive; biaxial (−)[29]
Gd2NCl3orthorhombicPbcna=13.017 b=6.7310 c=6.1403
Gd2N2CltetragonalP4mma = 4.25 c = 5.92[30]
α-HfNClorthorhombicPmmna = 4.130, b = 3.497, c = 8.070[31]
β-HfNClhexagonalRma = 3.5744, c = 27.7075colourless
NaxHfNClsuperconductor Tc 25 K[32]
Ba3Ta3N6ClP2ca =10.1455 c =5.9770
Ba3Cl2TaN3hexagonalP63cma = 15.0739, c = 6.3298; Z = 6light yellow[33]
Ba15Ta15N33Cl4P2ca =10.1545 c =29.917
W2NCl8triclinicPa = 6.2423, b = 6.309, c = 6.931, α = 89.76, β = 81.51, γ = 82.68
W2NCl9P21/ca = 8.421, b = 16.786, c = 11.930, β = 134.74°
[WNCl<sub>3</sub> • POCl<sub>3</sub>]4 • 2 POCl3triclinicPa = 12.257 b = 11.851 c = 19.27.0 α = 102.6° β= 108.4° γ = 94.8° Z=2[34]
Ba4[WN<sub>4</sub>]Cl2
ReNCl4tetragonalI4a=8.278 b=8.281 c=4.057 Z=2brown[35] [36]
ReNCl4·H2OorthorhombicPnmaa = 10.754, b = 11.085, c = 547.7 Z=4red
[NBu<sub>4</sub>][ReNCl<sub>4</sub>]orthorhombicP4/na 11.795 b 11.795 c 8.466ReN triple bond in complex[37]
K2OsNCl5orthorhombicPnmaa = 13.27, b = 9.85, c = 6.84
KleiniteHg2N(Cl,SO4)•n(H2O)hexagonalC63/mmca = 13.56 c = 11.13 Z = 181,772.338.01yellow[38]
MosesiteHg2N(Cl,SO4,MoO4,CO3)•(H2O)cubicF3ma = 9.524, Z = 8863.897.71yellow; refractive index 2.065[39]
ThNCltetragonalP4/nmma =4.09486 c =6.9013[40]
Uranium nitride chlorideUNCltetragonalP4/nmma=3.97 c=6.81 Z=2[41]

Notes and References

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  38. Web site: Kleinite Mineral Data . 2023-08-31 . www.webmineral.com.
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