Carbide iodide explained

Carbide iodides are mixed anion compounds containing iodide and carbide anions.Many carbide iodides are cluster compounds, containing one, two or more carbon atoms in a core, surrounded by a layer of metal atoms, and encased in a shell of iodide ions. These ions may be shared between clusters to form chains, double chains or layers.

The metal in carbide iodides is most often a rare earth element. Similar formulas tend to have similar structures. Where R is a rare earth element: R₁₂C₆I₁₇ contains chains of R₆ octahedra with a C₂⁶⁻ core and a shell of iodide. R₄I₅C contains similar chains, but with a single C₄⁻ carbide atom. Double chain structures with single carbon atom cores include R₆I₇C₂ and R₃I₃C. Layers of joined octahedra include R₂I₂C₂ with an ethanide C₂⁴⁻ core; R₂I₂C and R₂IC with one carbide per octahedron.^[1]

Related compounds include carbide chlorides, and carbide bromides. Carbon may be substituted by hydrogen, boron or nitrogen in the core of cluster compounds.

This list does not include cyanides, carbonyls, cyanamides or carbido borates, where carbon has bonds to other non-metals. However, there are carbide iodides that also contain nitride, oxide or other halides.

List

Do not confuse Cl for chlorine, and CI for carbon and iodine.

formula	system	space group	unit cell	volume	density	comment	reference
Sc2I3C	triclinic	P	a=10.793, b=10.803, c=13.959, α=87.8, β=73.04, γ=60.8		4,76	black
Sc4C2I6	triclinic	P	a=10.803 b=13.959 c=10.793 α=106.96° β=119.20° γ=87.80° Z=4			linear chains	^[2]
Sc6C2I11	triclinic	P	a=10.046 b=14.152 c=9.030 α=104.36° β=110.45° γ=89.27° Z=2		4.83	black
Sc7CI12	trigonal	R3	a=14.717 c=9.847 Z=3		4.99	dark purple; dissolves in N,N-dimethylacetamide	^[3] ^[4]
Sc24C10I30	trigonal	Pa	a=25.5182, c=25.5182		4.00	black; supertetrahedron of C10	^[5]
Y2C2I2	monoclinic	C12/m1	a=7174, b=3.866, c=10.412 β=92.98,		5.25	bronze; superconductor Tc=9.97K	^[6] ^[7]
Y2I2C	trigonal	Pm1	a=3.922 c=10.404		5.32	olive green
Y4I5C	monoclinc	C2/m	a=18.479 b=3.947 c=8.472 β=103.22°		5.53	dark red; chains	^[8]
Y5C2I9	monoclinic	C12/c1	a=18.479, b=3947, c=8472, β=103.22°		4.97	black
Y6C2I7	monoclinc	C2/m	a=21.557 b=3.909 c=12.374 β=123.55°		5.53	black; twin chain	^[9]
Y10C2I13	monoclinc	C2/m	a=21.317 b=3.95 c=19.889 β=97.40° Z=2			black
Y19C6I34	triclinic	P	a=9.3683,b=10.341, c=22.173, α=79.104, β=88.175, γ=69.277 Z=1	1970.8	5.12	black
Y10C2I13	monoclinic	C12/m1	a=21.317, b=3.957, c19.899, β=97.4°		5.11	black
Y19C6I34	triclinic	P	a=93683, b=10.341, c=22.173, α=79.104°, β=88.175°, γ=69.277°		5.12	black
Y16B4C8I19	triclinic	P	a=12.311, b=13.996, c=19.695, α=74.96, β=89.51, γ=67.03		4.40	blue	^[10]
Y21B7C14I18	triclinic	P	a=10.66, b=15.546, c=18.416, α=82.49, β=85.01, γ=82.92 Z=2	2995	4.87		^[11]
Y6C2I9N	hexagonal	P6	a=20.275, c=13.025		4.91	brown
Y7C2I12N	triclinic	P	a=9.7124, b=10.3038, c=16.7358, α=101.366, β=92.758, γ=112.799		4.84	olive green
Y7C3I6O	orthorhombic	Pmma	a=22.494, b=3.837, c=10.791		5.12	bronze
[Y<sub>9</sub>C<sub>4</sub>O]I8	orthorhombic	Pmmn	a = 29.127, b = 3.8417, c = 10.80.29, Z = 2		5.16	black	^[12] ^[13]
Y16C7I14O2	monoclinic	C2/m	a=51.6, b=3.84, c=10.8, β=93		5.15
YCI0.75l0.25C	monoclinic	C2/m	a=7.127, b=3.839, c=10.441, β=93.84		4.78
YI0.75CBr0.25	monoclinic	C2/m	a=7.131, b=3.847, c=10.358, β=93.73		5.06
Zr6CI12	trigonal	R	a=14.508, c=10.007		5.69
Zr6CI14	orthorhombic	Cmce	a=15.69, b=14.218, c=12.808		5.43
K0.58Zr6CI14	orthorhombic	Cmca	a=15.727, b=14.278, c=12798		5.54
RbZr6I14C	orthorhombic	Cmca	a=15.768, b=14.296, c=12.849		5.55
CsY10C4I18	triclinic	P	a=11.138, b=11.201, c=11.325, α=66.92, β=87.26, γ=60.87 Z=1	1117.2	4.99	black	^[14]
Cs2Zr7I18C	trigonal	Rc	a=10.744, c=29.409		5.42		^[15]
CsZr6I14C	orthorhombic	Cmca	a=15.803, b=14.305, c=12.934		5.61
Cs2Zr7I18C	trigonal	R	a = 10.744, c = 29.409 Z=3		4.99	black	^[16]
LaIC	monoclinic	C12/m1	a=7.619, b=4.1252, c=10.7513, β=93.143		5.47	bronze	^[17]
LaIC	monoclinic	C12/m1	a=7.6132, b=4.1324, c=10.859, β=100.835		5.50	bronze
La3I5C	triclinic	P	a=7.955, b=9.687, c=9.728, α=107.81, β=97.34, γ=105.56		5.28	violet
La3C2I3	orthorhombic	C2221	a=12.026 b=17.739 c=17.735		5.77	black
La4C1.5I5	monoclinic	C2/m	a = 19.849, b = 4.1410, c = 8.956, β = 103.86°		5.62	metallic grey	^[18]
La4C2I5	orthorhombic	Immm	a = 19.907, b = 4.1482, c = 8.963, β = 104.36°
La5C2I9	orthorhombic	Pbca	a = 8.025, b = 16.887, c = 35.886 Z=8	4863	5.08	>850° metallic green	^[19]
La5C2I9	triclinic	P	a = 8.006, b = 10.088, c = 14.383, α = 79.34°, β = 80.75° and γ = 85.07° Z=2	1124.9	5.494	<800 °C; dark red; air sensitive	^[20]
La6I10(C2)	triclinic	P	a = 9.687, b = 9.728, c = 7.955, α = 97.34°, β = 105.56° and γ = 107.81° Z=1	699.33	5.276	violet; air sensitive
La7C3I10	triclinic	P	a=9.761, b=11.79, c=14.055, α=79.6, β=71.49, γ=65.79		5.42	greenish black
La10C4I15	triclinic	P	a=9.747, b=10.655, c=11.736, α=93.68, β=114.44, γ=109.28		5.45	dark red
La10I15(C2)2	triclinic	P	a = 9.747, b = 10.655, c = 11.736, α = 93.68°, β = 114.44° and γ = 109.28° Z=1	1018.39	5.447	dark red; air sensitive
La12I17(C2)3	monoclinic	C12/c1	a= 19.927, b= 12.636, c = 19.399, β = 90.24(1)°, Ζ = 4	4884.6	5.30	black	^[21]
La14(C2)3I20	triclinic	P	a = 9.761, b = 11.790, c = 14.055, α = 79.60°, β = 71.49°, γ = 65.79°			greenish black	^[22]
La4B2I5C	monoclinic		a=23.303, b=4.299, c=18.991, β=126.22		5.30	black
La9B3C6I5	orthorhombic		a=3.9481, b=33.857, c=8.218		6.01
La4I6CN	tetragonal		a=13.953 c=9.811		4.67	olive green	^[23]
LaCI0.75l0.25C	monoclinic	C2/m	a=7.5764, b=4.0758, c=10.7266, β=93.384		5.12	bronze
LaI0.75CBr0.25	monoclinic	C2/m	a=75857, b=4.0981, c=10.6782, β=93.272		5.33	bronze	^[24]
Ce3I5C	triclinic	P	a=7.875, b=9.588, c=9.648, α=107.69, β=97.24, γ=105.32		5.43	violet	^[25]
Ce5C2I9	orthorhombic	Pbca	a = 7.9284, b = 16.714, c = 35.530		5.27	red
Ce6I10C2	triclinic	P	a=9.588 b=9.648 c=7.875 α = 97.24°, β = 105.32° and γ = 107.69 Z=1	652.3	5.432	violet
Ce7C3I10	triclinic	P	a=9.688, b=11.67, c=13.932, α=80.16, β=71.81, γ=65.88		5.57	greenish black
Ce12C6I17	monoclinic	C12/c1	a=19.731, b=12.495, c=19.182, β=90.36		5.49	black; chains
Ce14(C2)3I20	triclinic	P	a = 9.688, b = 11.670, c = 13.932, α = 80.16°, β = 71.81°, γ = 65.88°			greenish back; semiconductor
Ce4B2I5C	monoclinic		a=23.194, b=4.29, c=18.822, β=126.5		5.42	black	^[26]
Ce8I6(C2)(N)2
Ce4I6CN	tetragonal	P42/mnm	a = 13.877, c = 9.665 Z=4	1861.3	4.810	brown	^[27]
Ce6I9C2N	hexagonal	P6/m	a = 41.774, c = 13.719 Z=32	20734	5.179	black; moisture sensitive
Ce6I9C2N	hexagonal	P6/m	a = 20.958, c = 13.793 Z=8	5246	5.117	black
PrI12						black	^[28]
Pr7C3I10	triclinic	P	a=9663, b=11.619, c=13.866, α=80.31, β=71.79, γ=65.9		5.64	black
Pr12(C2)3I17	monoclinic	C2/c	a=19.610, b=12.406, c=19.062, β=90.45°		5.62	metallic grey	^[29]
Nd2C2I2	monoclinic	C2/m				layered	^[30]
Nd12(C2)3I17	monoclinic	C2/c	a=19.574, b=112.393, c=19.003(5) Å, β=90.41°		5.71	black
RbI12	triclinic	P	a = 9.601, b = 9.570, c = 10.034, α = 71.74, β = 70.69, γ = 72.38°, Z = 1	805.6	5.11	black	^[31]
Cs2[Pr<sub>6</sub>(C<sub>2</sub>)]I12	triclinic	P	a=9.481, b=9.536, c=10.052; α=71.01; β=84,68, γ=89.37°; Z=1	515.3	5.16	black	^[32]
Cs4[Pr<sub>6</sub>(C<sub>2</sub>)]I13	tetragonal	I41/amd	a = 18.049; c = 12.595		4.94	blue-black with brassy lustre	^[33]
Gd2IC	hexagonal	P63/mmc	a=3.801, c=14.792		8.14		^[34]
Gd3I3C	monoclinic	P121/m1	a=8.658, b=3.926, c=11.735, β=92.26		7.20	bronze; twin chains
Gd4I5C	monoclinic	C2/m	a=18.587 b=3.978 c=8.561 β=103.3			chains
Gd6C2I7	monoclinic	C2/m	a=21.767 b=3.947 c=12.459 β=123.6			twin chains
Gd7I12C	trigonal	R	a=15.288 c=10.291				^[35]
Gd10C4I16	triclinic	P	a=10.463 b=16.945 c=11.220 α=99.16 β=92.68 γ=88.06		6.18	black	^[36]
Gd12(C2)3I17	monoclinic	C2/c	a = 19.297, b = 12.201, c = 18.635, β = 90.37°		6.13	black; Gd6 octahedra containing C2	^[37]
Gd4I6CN	tetragonal		a=13.578 c=9.313		5.48	brown red; air sensitive
Gd4I6CN	hexagonal		a=40.806 c=9.232		5.65	brown red
Gd19(C2)3I34	triclinic	P	a = 9.4172, b = 10.339, c = 22.371, α = 79.00°, β = 88.32°, γ = 69.25° Z=1	2007.6	6.10	black; air sensitive	^[38]
[Gd<sub>4</sub>(C<sub>2</sub>)](Cl, I)6	tetragonal	P4/mbm	a = 13.475, c = 12.125, Z = 2			black	^[39]
Gd6C3I4.56Cl4.44	tetragonal	P4/mbm	a=13.475, c=12.125		5.18	black	^[40]
Tb2IC	hexagonal	P63/mmc	a=3.7707, c=14.66		8.40
Tb2C2I2	monoclinic	C2/m				layered	^[41]
Dy2I3C	orthorhombic	Pnnm	a=13.622, b=14.335, c=8.396		5.82		^[42]
Dy5C2I9	monoclinic	P121/c1	a=10.47, b=17.152, c=13.983, β=121.14		6.12	black
Dy7C2I12	trigonal	R	a=15.233, c=10.649		6.25	black
Dy12(C2)3I17	monoclinic	C2/c	a=19.149, b=12.069, c=18.595, β=90.54		6.46	black
I18	hexagonal	P6/m	a = 20.2418, c = 12.9921, Z = 8	4610.1	6.22	black	^[43]
I24	triclinic	P	a = 9.730, b = 10.330, c = 16.770, α = 101.42°, β = 92.72°, γ = 112.75°, Z = 2	1509.3	5.94	black
Ho7C2I12N	triclinic	P	a=9.688, b=10.287, c=16.678, α=101.31, β=92.78, γ=112.8		6.06	brown red	^[44]
[Ho<sub>9</sub>C<sub>4</sub>O]I8	orthorhombic	Pmmn	a=3.8157, b=28.867, c=10.748		7.19
Er4I5C	monoclinic	C2m	a=18.521 b=4.015 c=8.478 β=103.07
Er6C2I7	monoclinic	C2/m	a=21.375 b=3.869 c=12.319 β=123.50			twin chains
[Er<sub>9</sub>C<sub>4</sub>O]I8	orthorhombic	Pmmn	a=3.8037, b=28.818, c=10.7381		7.29		^[45]
Cs[Er<sub>6</sub>C]I12	trigonal	R	a=11.120 c=20.638 Z=3	443.71	6.02	black	^[46]
[Er<sub>14</sub>(C<sub>2</sub>)<sub>2</sub>(N)<sub>2</sub>]l24	triclinic	P	a = 9.663, b = 10.276, c = 16.634, α =101.374°, β = 92.85°, γ = 112.83°, Z =2	1477.8	6.14	red brown	^[47]
CsEr10(C2)2I18	triclinic	P	a=11.052 b=11.120 c=11.229 α=66.01° β=87.14° γ=60.80° Z=1	656.6	6.29	black
[Lu<sub>9</sub>C<sub>4</sub>O]I8	orthorhombic	Pmmn	a=3.7575, b=28.333, c=10.6377		7.78		^[48]

Notes and References

1. Simon . Arndt . Borderline of cluster chemistry with lanthanides . Inorganica Chimica Acta . December 1987 . 140 . 57–58 . 10.1016/s0020-1693(00)81050-6.
2. Dudis . Douglas S. . Corbett . John D. . June 1987 . Two scandium iodide carbides containing dicarbon units within scandium clusters: Sc6I11C2 and Sc4I6C2. Synthesis, structure, and the bonding of dicarbon . Inorganic Chemistry . en . 26 . 12 . 1933–1940 . 10.1021/ic00259a025 . 0020-1669.
3. Dudis . Douglas S. . Corbett . John D. . Hwu . Shiou Jyh . September 1986 . Synthesis, characterization, and crystal structures of two scandium cluster carbides and a boride, Sc7X12C (X = I, Br) and Sc7I12B . Inorganic Chemistry . en . 25 . 19 . 3434–3438 . 10.1021/ic00239a023 . 0020-1669.
4. Demir . Selvan . Tyrra . Wieland . Schmitz . Simon . Klein . Axel . Meyer . Gerd H. . 2022 . Pursuing the excision of carbon-centred hexanuclear scandium clusters from solid I12Sc† . Australian Journal of Chemistry . 75 . 9 . 523–531 . en . 10.1071/CH21267 . 247090688 . 0004-9425.
5. Jongen . Liesbet . Mudring . Anja-Verena . Meyer . Gerd . 2006-03-13 . The Molecular Solid Sc24C10I30: A Truncated, Hollow T4 Supertetrahedron of Iodine Filled with a T3 Supertetrahedron of Scandium That Encapsulates the Adamantoid Cluster Sc4C10 . Angewandte Chemie International Edition . en . 45 . 12 . 1886–1889 . 10.1002/anie.200503914 . 16485307 . 1433-7851.
6. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 363 . en.
7. Henn . R. W. . Schnelle . W. . Kremer . R. K. . Simon . A. . 1996-07-08 . Bulk Superconductivity at 10 K in the Layered Compounds Y 2 C 2 I 2 and Y 2 C 2 Br 2 . Physical Review Letters . en . 77 . 2 . 374–377 . 10.1103/PhysRevLett.77.374 . 10062435 . 0031-9007.
8. Kauzlarich . Susan M. . Hughbanks . Timothy . Corbett . John D. . Klavins . Peter . Shelton . Robert N. . May 1988 . Two extended metal chain compounds, yttrium iodide carbides (Y4I5C and Y6I7C2). Synthesis, structure, properties, and bonding . Inorganic Chemistry . en . 27 . 10 . 1791–1797 . 10.1021/ic00283a024 . 0020-1669.
9. Kauzlarich . Susan M. . Payne . Martin W. . Corbett . John D. . September 1990 . Y10I13C2: a novel compound with chains of both carbon-centered and empty clusters . Inorganic Chemistry . en . 29 . 19 . 3777–3781 . 10.1021/ic00344a025 . 0020-1669.
10. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 844 . en.
11. Oeckler . Oliver . Duppel . Viola . Mattausch . Hansjürgen . Simon . Arndt . 1999-04-01 . Y 21 I 18 C 14 B 7 : Synthesis, Average Structure, and Structural Misfit . Inorganic Chemistry . en . 38 . 8 . 1767–1771 . 10.1021/ic981377x . 11670945 . 0020-1669.
12. Meyer . H.-Jürgen . August 1993 . Zur elektronischen Struktur von [Y9C4O]I8 ]. Zeitschrift für anorganische und allgemeine Chemie . de . 619 . 8 . 1389–1392 . 10.1002/zaac.19936190812 . 0044-2313.
13. Mattfeld . Heiner . Krämer . Karl . Meyer . Gerd . August 1993 . [M9C4O]I8 (M = Y, Ho, Er, Lu), reduzierte Selten-Erd-Iodide mit gewellten Metall-Doppelschichten und zwei verschiedenen interstitiellen Atomen ]. Zeitschrift für anorganische und allgemeine Chemie . de . 619 . 8 . 1384–1388 . 10.1002/zaac.19936190811 . 0044-2313.
14. 1995-12-01 . Hinz . D. J. . Meyer . G. . Crystal structure of caesium yttrium carbide iodide (1-10-4-18), Cs[Y 10 (C 2) 2 ]I 18 ]. Zeitschrift für Kristallographie - Crystalline Materials . en . 210 . 12 . 958 . 10.1524/zkri.1995.210.12.958 . 1995ZK....210..958H . 2194-4946 . Hinz . D. J. . Meyer . G. .
15. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 937 . en.
16. Payne . Martin W. . Corbett . John D. . February 1993 . The Synthesis and Structure of a New Zirconium Iodide Carbide Cluster Phase, Cs2Zr7I18C . Journal of Solid State Chemistry . en . 102 . 2 . 553–556 . 10.1006/jssc.1993.1066.
17. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 362 . en.
18. Mattausch . Hansjürgen . Schaloske . Manuel C. . Hoch . Constantin . Zheng . Chong . Simon . Arndt . March 2008 . Seltenerdhalogenide Ln4X5Z. Teil 1: C und/oder C2 in Ln4X5Z . Zeitschrift für anorganische und allgemeine Chemie . de . 634 . 3 . 491–497 . 10.1002/zaac.200700500. free .
19. Mattausch . Hansjürgen . Hoch . Constantin . Simon . Arndt . April 2008 . Das Lanthaniodidethanido-La5I9(C2) – Die orthorhombische Hochtemperaturmodifikation . Zeitschrift für anorganische und allgemeine Chemie . de . 634 . 4 . 641–645 . 10.1002/zaac.200700477.
20. Mattausch . Hansjürgen . Hoch . Constantin . Simon . Arndt . June 2005 . Drei neue Ethanidiodide des Lanthans: La5I9(C2), La6I10(C2) und La10I15(C2)2 . Zeitschrift für anorganische und allgemeine Chemie . de . 631 . 8 . 1423–1429 . 10.1002/zaac.200500022 . 0044-2313.
21. Mattausch . Hj. . Simon . A. . April 2005 . Crystal structure of dodecalanthanum heptadecaiodide triethanide, La12I17(C2)3 . Zeitschrift für Kristallographie - New Crystal Structures . 220 . 1–4 . 319–320 . 10.1524/ncrs.2005.220.14.319 . 201120291 . 2197-4578. free .
22. Mattausch . Hansjürgen . Simon . Arndt . Kienle . Lorenz . Hoch . Constantin . Zheng . Chong . Kremer . Reinhard K. . August 2006 . EYPHKAMEN: Ln-Oktaedertripel in Ln14(C2)3I20 mit Ln = La, Ce . Zeitschrift für anorganische und allgemeine Chemie . de . 632 . 10–11 . 1661–1670 . 10.1002/zaac.200500493 . 0044-2313.
23. Mattausch . Hansjürgen . Borrmann . Horst . Eger . Roland . Kremer . R. K. . Simon . Arndt . November 1994 . Gd4I6CN: Ein Carbidnitrid mit Ketten aus Gd6(C2)-Oktaedern und Gd6N2-Tetraederdoppeln . Zeitschrift für anorganische und allgemeine Chemie . de . 620 . 11 . 1889–1897 . 10.1002/zaac.19946201109 . 0044-2313.
24. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 924 . en.
25. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 352 . en.
26. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 843 . en.
27. Schaloske . Manuel C. . Kienle . Lorenz . Mattausch . Hansjürgen . Duppel . Viola . Simon . Arndt . September 2011 . Disorder in Rare Earth Metal Halide Carbide Nitrides . European Journal of Inorganic Chemistry . en . 2011 . 26 . 4049–4056 . 10.1002/ejic.201100201 . 1434-1948.
28. Meyer . Gerd . February 2008 . Reduced rare-earth iodides without and with carbon . Journal of Alloys and Compounds . en . 451 . 1–2 . 666–668 . 10.1016/j.jallcom.2007.04.083.
29. Ryazanov . Mikhail . Mattausch . Hansjürgen . Simon . Arndt . April 2007 . The extended chain compounds Ln12(C2)3I17 (Ln=Pr, Nd, Gd, Dy): Synthesis, structure and physical properties . Journal of Solid State Chemistry . en . 180 . 4 . 1372–1380 . 10.1016/j.jssc.2007.01.029.
30. Ahn . K. . Gibson . B.J. . Kremer . R.K. . Simon . A. . 2002-12-01 . Magnetic ordering within the layered neodymium carbide iodides, Nd 2 C 2 I 2 . Applied Physics A: Materials Science & Processing . 74 . s920–s922 . 10.1007/s003390101164 . 96028929 . 0947-8396.
31. Wiglusz . Rafał . Pantenburg . Ingo . Meyer . Gerd . August 2007 . RbI 12, an Iodide with a 13-Electron Isolated Octahedral Cluster . Zeitschrift für anorganische und allgemeine Chemie . en . 633 . 9 . 1317–1319 . 10.1002/zaac.200700081 . 0044-2313.
32. Artelt . Holger M. . Meyer . Gerd . January 1993 . Cs2[Pr6(C2)]I12 - das erste quaternäre reduzierte Halogenid mit isolierten [M6(C2)]-Clustern ]. Zeitschrift für anorganische und allgemeine Chemie . de . 619 . 1 . 1–6 . 10.1002/zaac.19936190103 . 0044-2313.
33. Artelt . Holger M. . Schleid . Thomas . Meyer . Gerd . September 1994 . Cs4[Sc6C]Cl13 und Cs4[Pr6(C2)]I13 ? zwei Beispiele für das fehlende Bindeglied bei der Verknüpfung der Baueinheiten [M6Z]X12iX6a ]. Zeitschrift für anorganische und allgemeine Chemie . de . 620 . 9 . 1521–1526 . 10.1002/zaac.19946200905 . 0044-2313.
34. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 360 . en.
35. Book: Handbook on the Physics and Chemistry of Rare Earths volume 15 . . 1991 . 9780444889669 . 195.
36. Simon . Arndt . March 1985 . Empty, filled, and condensed metal clusters . Journal of Solid State Chemistry . en . 57 . 1 . 2–16 . 10.1016/S0022-4596(85)80055-4. 1985JSSCh..57....2S .
37. Simon . A. . Warkentin . E. . February 1983 . Gd 12 C 6 I 17 - eine Verbindung mit kondensierten, C 2 -gefüllten Gd 6 I 12 -Clustern . Zeitschrift für anorganische und allgemeine Chemie . en . 497 . 2 . 79–92 . 10.1002/zaac.19834970208.
38. Schaloske . Manuel C. . Kienle . Lorenz . Duppel . Viola . Mattausch . Hansjürgen . Simon . Arndt . January 2010 . SE 19 (C 2) 3 I 34 (SE = Y, Gd): Verbindungen mit diskreten SE 6 I 12 -Clustern und isolierten SE -Atomen . Zeitschrift für anorganische und allgemeine Chemie . en . 636 . 1 . 188–195 . 10.1002/zaac.200900483. free .
39. Ließ . Henning . Meyer . H.-Jürgen . Meyer . Gerd . March 1996 . [Gd4(C2)](Cl, I)6, an Interstitially Stabilized Heteroleptic Gadolinium Sesquihalide ]. Zeitschrift für anorganische und allgemeine Chemie . de . 622 . 3 . 494–500 . 10.1002/zaac.19966220318 . 0044-2313.
40. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 934 . en.
41. Ahn . K . Gibson . B.J . Kremer . R.K . Mattausch . Hj . Keller . L . Simon . A . July 2001 . Magnetic ordering within the layered terbium carbide iodide, Tb2C2I2 . Journal of Alloys and Compounds . en . 323-324 . 400–403 . 10.1016/S0925-8388(01)01096-9.
42. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 357 . en.
43. Daub . Kathrin . Meyer . Gerd . September 2010 . Isolated and Edge-Connected Tetramers in the Crystal Structures of I24 and I18 . Zeitschrift für anorganische und allgemeine Chemie . en . 636 . 9–10 . 1716–1719 . 10.1002/zaac.201000128. 93581620 .
44. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 947 . en.
45. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 938 . en.
46. Artelt . Holger M. . Meyer . Gerd . 1992 . Synthesis and crystal structures of two new reduced iodides of erbium with isolated monomeric and dimeric clusters, Cs[Er6C]I12 and Cs[Er10(C2)2]I18 ]. Journal of the Chemical Society, Chemical Communications . en . 18 . 1320–1321 . 10.1039/c39920001320 . 0022-4936.
47. Steffen . Frank . Meyer . Gerd . 1995-10-01 . [Er 14 (C 2) 2 (N) 2 ]l 24 – ein Iodid mit einem oligomeren, heterointerstitiellen Cluster / [Er 14 (C 2) 2 (N) 2 ]l 24 – an Iodide with an Oligomeric, Heterointerstitial Cluster . Zeitschrift für Naturforschung B . en . 50 . 10 . 1570–1574 . 10.1515/znb-1995-1024 . 95276145 . 1865-7117. free .
48. Book: Villars . Pierre . Handbook of Inorganic Substances 2015 . Cenzual . Karin . Gladyshevskii . Roman . 2014-12-17 . Walter de Gruyter GmbH & Co KG . 978-3-11-031174-7 . 948 . en.