Cadmium bromide explained

Cadmium bromide is the inorganic compound with the formula CdBr2. It is a white hygroscopic solid. It also can be obtained as a mono- and tetrahydrate. It has few applications.

Preparation and structure

Cadmium bromide is prepared by heating cadmium with bromine vapor.[1] The tetrahydrate has been obtained by crystallization of the dibromide from aqueous solution. At 3.04 g/cm3, it is much less dense than the anhydrous material. According to X-ray crystallography, the tetrahydrate is a polymer of CdBr2(H2O)2 with bridging bromide ligands. There are two interstitial water molecules[2]

References

  1. Book: F. Wagenknecht. R. Juza. Cadmium bromide. Handbook of Preparative Inorganic Chemistry, 2nd Ed. . G. Brauer. Academic Press. 1963. NY, NY. 2. 1096.
  2. 10.1107/S0567740878002186 . Structure Cristalline de CdBr2.4H2O . 1978 . Leligny . H. . Monier . J. C. . Acta Crystallographica Section B . 34 . 1 . 5–8 . 1978AcCrB..34....5L .