Phosphide bromide explained
Phosphide bromides or bromide phosphides are compounds containing anions composed of bromide (Br−) and phosphide (P3−) anions. Usually phosphorus is covalently connected into more complex structures. They can be considered as mixed anion compounds. They are in the category of pnictidehalides. Related compounds include the phosphide chlorides, phosphide iodides, nitride bromides, arsenide bromides, and antimonide bromides.
List
| formula | system | space group | unit cell Å | volume | density | comment | ref |
|---|
| Ca2PBr | cubic | I3d | a=5.96 Z=2 | | | red brown | [1] |
| Ca2PBr | hexagonal | Rm | a=4.23 c=20.9 Z=3 | | | | |
| Cu12P20Br10 | triclinic | P | a = 9.886, b = 13.190, c = 14.763, α = 70.83°, β = 82.68°, γ = 80.13°, Z = 2 | 1786.1 | | | [2] |
| Cu13P15Br12 | | | | | | | [3] |
| Cu6PS5Br | cubic | P3m | a=9.732 Z=4 | 921.8 | 4.701 | red | [4] |
| (CuBr)2P8Se3 | orthorhombic | Pbcm | a=8.761 b=11.957 c=13.858 Z=4 | 1451.8 | | | [5] |
| Sr2PBr | cubic | I3d | a=9.31 Z=2 | | | brown violet | |
| Sr2PBr | hexagonal | Rm | a=4.44 c=22.0 Z=3 | | | dark reddish brown | |
| Sr2P7Br | cubic | P213 | a=9.789 Z=4 | 938.0 | 3.342 | red band gap 2.1 eV | [6] |
| Y2PBr2 | rhombohedral | | a=3.9807 c=29.250 | | | | [7] |
| Ag6PS5Br | cubic | P3m | a=10.3765 Z=4 | 1117.26 | 5.460 | red | |
| Cd5P2Br4 | orthorhombic | Pna21 | a=12.189, b=7.7080, c=13.664 | | | | [8] |
| Sn24P19.3Br8 | | | | | | | [9] |
| Sn17Zn7P22Br8 | cubic | Pmn | a=10.7449 | | | | [10] |
| Sn24−xInxP19.2+0.2x x<16 | cubic | Pmn | | | | | [11] |
| Si30+xP16–xTe8–xBrx x = 1–6.4 | cubic | Pmn | a=9.9720 - 10.0405 | | | | [12] |
| Ba2PBr | hexagonal | Rm | a=4.67 c=23.3 Z=3 | | | | |
| Ba2P7Br | monoclinic | P21/m | a=6.294 b=6.835 c=11.850 β=95.819 Z=2 | 507.2 | 3.742 | orange | [13] |
| La2PBr2 | trigonal | Pm1 | a=4.311 c=11.000 Z=1 | 177.04 | 5.28 | | |
| La3Zn4P6.6Br0.8 | orthorhombic | Cmcm | a=4.099 b=14.229 c=20.388 Z=4 | 1189.0 | 5.290 | black | [14] |
| Eu2PBr | | R3m | a = 4.385, c = 21.90, Z = 3 | | | | [15] |
| W4(PBr)Br10 | monoclinic | C12/m1 | a=14.0933 b=10.3228 c=11.8169 β=93.906 Z=4 | 1715.16 | | dark green | [16] |
| Hg2P3Br | orthorhombic | Pbcn | a = 8.014, b = 8.902, c = 7.823, Z = 4 | | | | [17] |
| Hg7P4Br6 | monoclinic | P21/c | a = 6.0452, b = 19.848, c = 7.5596 β = 104.214° Z=2 | 879.3 | 7.582 | brown | [18] |
| (Hg2P)2HgBr4 | monoclinic | P21 | a=7.776 b=12.226 c=7.930 β=121.34 Z=2 | 643.9 | 7.141 | discovered in 1907; bright yellow; air with light sensitive | [19] |
| [Hg<sub>7</sub>P<sub>4</sub>Br<sub>3</sub>](SnBr3) | cubic | P213 | a=12.490 Z=4 | | | | [20] | |
Notes and References
- Hadenfeldt . Claus . Kosiol . Wilfried . 1975-06-01 . Darstellung und Eigenschaften von Phosphidbromiden des Calciums, Strontiums und Bariums / Preparation and Properties of Phosphide Bromides of Calcium, Strontium, and Barium . Zeitschrift für Naturforschung B . en . 30 . 5–6 . 378–384 . 10.1515/znb-1975-5-616 . 94967271 . 1865-7117. free .
- 1997-02-01 . Freudenthaler . E. . Pfitzner . A. . Crystal structure of Cu 12 P 20 Br 10, a polyphosphide containing a new phosphorus polymer . Zeitschrift für Kristallographie - Crystalline Materials . en . 212 . 2 . 103–109 . 10.1524/zkri.1997.212.2.103 . 1997ZK....212..103F . 2194-4946. Freudenthaler . E. . Pfitzner . A. .
- Freudenthaler . E . November 1997 . Copper(I) halide-phosphorus adducts: a new family of copper(I) ion conductors . Solid State Ionics . en . 101-103 . 1053–1059 . 10.1016/S0167-2738(97)00169-0.
- Gao . Lihua . Wu . Xiaowen . Yang . Daqing . Tian . Xinyu . Xu . Jingjing . Zhang . Bingbing . Wu . Kui . 2021 . M 6 PS 5 X (M = Ag, Cu; X = Cl, Br) chalcohalides exhibiting strong nonlinear optical responses and high laser damage resistances . Dalton Transactions . en . 50 . 48 . 17901–17905 . 10.1039/D1DT03251H . 34851337 . 244148134 . 1477-9226.
- Nilges . S. . Nilges . T. . Haeuseler . H. . Pfitzner . A. . November 2004 . (CuBr)2P8Se3: preparation, structural, and vibrational spectroscopic characterization of an adduct of P8Se3 cages to Cu2Br2 rhombs . Journal of Molecular Structure . en . 706 . 1–3 . 89–94 . 10.1016/j.molstruc.2004.01.037. 2004JMoSt.706...89N .
- Dolyniuk . Juli-Anna . Tran . Nhon . Lee . Kathleen . Kovnir . Kirill . July 2015 . Sr 2 P 7 X (X = Cl, Br, and I): Synthesis, Crystal and Electronic Structures of Double Zintl Salts Containing Heptaphosphanortricyclane, P 7 3-: Double Zintl Salts with Heptaphosphanortricyclane, P 7 3- . Zeitschrift für anorganische und allgemeine Chemie . en . 641 . 8–9 . 1422–1427 . 10.1002/zaac.201500140.
- Oeckler . Oliver . Mattausch . Hansjürgen . Simon . Arndt . 2007-11-01 . Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds . Zeitschrift für Naturforschung B . en . 62 . 11 . 1377–1382 . 10.1515/znb-2007-1105 . 95077294 . 1865-7117. free .
- M.M. . Shatruk . L.N. . Reshetova . A.V. . Shevel'kov . B.A. . Popovkin . 2000 . Cd5P2Br4 - the first cadmium analogue of salts of Millon's base . Cd5P2Br4 - the first cadmium analogue of salts of Millon's base . Zhurnal Neorganicheskoj Khimii . Russian . 45 . 4 . 0044-457X.
- Stefanoski . S. . Reshetova . L. N. . Shevelkov . A. V. . Nolas . G. S. . July 2009 . Low-Temperature Transport Properties of Sn24P19.3Br8 and Sn17Zn7P22Br8 . Journal of Electronic Materials . en . 38 . 7 . 985–989 . 10.1007/s11664-008-0644-8 . 2009JEMat..38..985S . 135898461 . 0361-5235.
- Kovnir . Kirill A. . Shatruk . Mikhail M. . Reshetova . Lyudmila N. . Presniakov . Igor A. . Dikarev . Evgeny V. . Baitinger . Michael . Haarmann . Frank . Schnelle . Walter . Baenitz . Michael . Grin . Yuri . Shevelkov . Andrei V. . August 2005 . Novel compounds Sn20Zn4P22−vI8, Sn17Zn7P22I8, and Sn17Zn7P22Br8: Synthesis, properties, and special features of their clathrate-like crystal structures . Solid State Sciences . en . 7 . 8 . 957–968 . 10.1016/j.solidstatesciences.2005.04.002.
- Reshetova . L. N. . Shevelkov . A. V. . January 2012 . Synthesis and clathrate-type crystal structure of a solid solution in the Sn-In-P-Br system . Russian Chemical Bulletin . en . 61 . 1 . 28–32 . 10.1007/s11172-012-0004-y . 95316491 . 1066-5285.
- Abramchuk . Nikolay S. . Carrillo-Cabrera . Wilder . Veremchuk . Igor . Oeschler . Niels . Olenev . Andrei V. . Prots . Yurii . Burkhardt . Ulrich . Dikarev . Evgeny V. . Grin . Juri . Shevelkov . Andrei V. . 2012-11-05 . Homo- and Heterovalent Substitutions in the New Clathrates I Si 30 P 16 Te 8– x Se x and Si 30+ x P 16– x Te 8– x Br x : Synthesis, Crystal Structure, and Thermoelectric Properties . Inorganic Chemistry . en . 51 . 21 . 11396–11405 . 10.1021/ic3010097 . 23072375 . 0020-1669.
- Dolyniuk . Juli-Anna . Kovnir . Kirill . 2013-08-26 . Zintl Salts Ba2P7X (X = Cl, Br, and I): Synthesis, Crystal, and Electronic Structures . Crystals . en . 3 . 3 . 431–442 . 10.3390/cryst3030431 . 2073-4352 . free.
- Wang . Jian . Kaseman . Derrick . Lee . Kathleen . Sen . Sabyasachi . Kovnir . Kirill . 2016-07-12 . Enclathration of X@La 4 Tetrahedra in Channels of Zn–P Frameworks in La 3 Zn 4 P 6 X (X = Cl, Br) . Chemistry of Materials . en . 28 . 13 . 4741–4750 . 10.1021/acs.chemmater.6b01752 . 0897-4756.
- Hadenfeldt . C. . Held . W. . September 1986 . Darstellung, eigenschaften und kristallstruktur der Europium(ii)-phosphidhalogenide Eu2PCl, Eu2PBr und Eu2PI . Journal of the Less Common Metals . de . 123 . 1–2 . 25–35 . 10.1016/0022-5088(86)90111-6.
- Ströbele . Markus . Eichele . Klaus . Meyer . Hans-Jürgen . 2015-02-02 . Cluster Harvesting in the WBr 6 –P System . Inorganic Chemistry . en . 54 . 3 . 989–992 . 10.1021/ic502333u . 25392957 . 0020-1669.
- 1994-07-01 . Shevelkov . A. V. . Dikarev . E. V. . Popovkin . B. A. . Helical [unk](P 1−) chains in the structures of Hg 2 P 3 Br and Hg 2 P 3 Cl ]. Zeitschrift für Kristallographie - Crystalline Materials . en . 209 . 7 . 583–585 . 10.1524/zkri.1994.209.7.583 . 1994ZK....209..583S . 2194-4946. Shevelkov . A. V. . Dikarev . E. V. . Popovkin . B. A. .
- Shevelkov . A.V. . Dikarev . E.V. . Popovkin . B.A. . June 1993 . Syntheses and Crystal Structure of Hg7P4Br6 . Journal of Solid State Chemistry . en . 104 . 2 . 177–180 . 10.1006/jssc.1993.1151. 1993JSSCh.104..177S .
- Shevelkov . Andrei V. . Mustyakimov . Marat Yu. . Dikarev . Evgeny V. . Popovkin . Boris A. . 1996 . (Hg2P)2HgBr4: a phosphorus analogue of the Millon's base salts . Journal of the Chemical Society, Dalton Transactions . en . 1 . 147–148 . 10.1039/dt9960000147 . 0300-9246.
- A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions. European Journal of Inorganic Chemistry. 2002. 10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N. Olenev. Andrei V.. Baranov. Alexei I.. Shevelkov. Andrei V.. Popovkin. Boris A.. 2002. 3. 547–553.
