Boleite Explained

Boleite
Category:Halide mineral
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Formula:KPb26Ag9Cu24(OH)48Cl62
Imasymbol:Bol[1]
Strunz:3.DB.15
System:Isometric
Class:Hexoctahedral (mm)
H-M symbol: (4/m 2/m)
Symmetry:Pmm
Unit Cell:a = 15.29 Å; Z = 1
Color:Deep Prussian blue to indigo
Habit:Cubic crystals
Cleavage:[001] perfect
Fracture:Uneven
Mohs:3.0 – 3.5
Luster:Vitreous to pearly
Refractive:n = 2.05
Opticalprop:Isotropic
Streak:Greenish blue
Gravity:5.054
Diaphaneity:Translucent
Other: Radioactive 0.36% (K)
References:[2] [3] [4]

Boleite is a complex halide mineral with formula: KPb26Ag9Cu24(OH)48Cl62.[3] It was first described in 1891 as an oxychloride mineral. It is an isometric mineral which forms in deep-blue cubes. There are numerous minerals related to boleite, such as pseudoboleite, cumengite, and diaboleite, and these all have the same complex crystal structure.[5] They all contain bright-blue cubic forms and are formed in altered zones of lead and copper deposits, produced during the reaction of chloride bearing solutions with primary sulfide minerals.[6]

Physical properties

The external property of a boleite crystal structure indicates its cubic structure. It is classified under the isometric crystal class. Boleite has a perfect cleavage in the [001] direction, and has a very dark glossy blue color with a light greenish-blue color streak. Twinning is best shown in this mineral by notches along the interpenetrated angles, which results in a crystal habit of pseudocubic penetration twinning along three different angles perpendicular to one another. Boleite has cubes over half an inch on each side, which consist of pseudo-octahedral tetragonal dipyramids.[7]

Geologic occurrence

Boleite was first collected as a very minor ore of silver, copper and lead at Boleo, Mexico.[6] Boleite was named after its place of discovery, El Boleo mine, on the Baja Peninsula, near Santa Rosalia, Mexico.[3]

Minerals associated with boleite include pseudoboleite, cumengeite, atacamite, anglesite, cerussite, phosgenite and gypsum at the type locality in Boleo, Mexico. In the Mammoth-St. Anthony mine of Arizona associated minerals include pseudoboleite, anglesite, cerussite, atacamite, paratacamite, leadhillite, paralaurionite, caledonite, phosgenite, matlockite and bideauxite.[2]

External links

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://rruff.geo.arizona.edu/doclib/hom/boleite.pdf Handbook of Mineralogy
  3. http://www.mindat.org/min-712.html Mindat.org
  4. http://www.webmineral.com/data/Boleite.shtml Webmineral data
  5. Martens, W., Williams, P.A., Frost, R.L. (2003) "Raman spectroscopy of the minerals boleite, cumengite, diaboleite and phosgenite – implications for the analysis of cosmetics of a antiquity". Mineralogical Magazine. V.67: 103–111 1
  6. Rouse, Roland C. (1973/01). "The Crystal Structure of boleite – A Mineral Containing Silver Atom Clusters". Journal of Solid State Chemistry 6(1): 86–92 2
  7. Weber, Julius (1974). The Formation of Minerals. Van Nostrand Reinhold Company. New York, London. pp. 78–80