Boehmite Explained

Boehmite
Category:Oxide mineral
Formula:γ-AlO(OH)
Imasymbol:Bhm[1]
Strunz:4.FE.15
Dana:6.1.2.1
System:Orthorhombic
Class:Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Symmetry:Amam
Unit Cell:a = 3.693 Å,
b = 12.221 Å,
c = 2.865 Å; Z = 4
Color:White, pale greyish brown; yellowish or reddish when impure; colorless in thin section
Habit:Tabular crystal rare, fine grained in pisolitic aggregates or disseminated
Cleavage:Very good on, good on, and poor on
Fracture:Uneven
Tenacity:Brittle
Mohs:3.5
Luster:Vitreous, pearly on
Streak:White
Diaphaneity:Translucent
Gravity:3.02–3.05
Opticalprop:Biaxial (+)
Refractive:nα = 1.644 – 1.648 nβ = 1.654 – 1.657 nγ = 1.661 – 1.668
Birefringence:δ = 0.017 – 0.020
2V:Measured: 74° to 88°, Calculated: 80°
Dispersion:weak
References:[2] [3] [4] [5]

Boehmite or böhmite is an aluminium oxide hydroxide (γ-AlO(OH)) mineral, a component of the aluminium ore bauxite. It is dimorphous with diaspore. It crystallizes in the orthorhombic dipyramidal system and is typically massive in habit. It is white with tints of yellow, green, brown or red due to impurities. It has a vitreous to pearly luster, a Mohs hardness of 3 to 3.5 and a specific gravity of 3.00 to 3.07. It is colorless in thin section, optically biaxial positive with refractive indices of nα = 1.644 – 1.648, nβ = 1.654 – 1.657 and nγ = 1.661 – 1.668.

Boehmite occurs in tropical laterites and bauxites developed on alumino-silicate bedrock. It also occurs as a hydrothermal alteration product of corundum and nepheline. It occurs with kaolinite, gibbsite and diaspore in bauxite deposits; and with nepheline, gibbsite, diaspore, natrolite and analcime in nepheline pegmatites.[4] Industrially, it is used as an inexpensive flame retardant additive for fire-safe polymers.

It was first described by J. de Lapparent in 1927 for an occurrence in the bauxites of Mas Rouge, Les Baux-de-Provence, France, and named[6] for the Bohemian-German chemist Johann Böhm (1895–1952) who carried out X-ray studies of aluminium oxide hydroxides in 1925[7] (and not for the German geologist Johannes Böhm (1857–1938) as often stated).[2] [3]

See also

References

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Web site: Boehmite. Webmineral data. 2010-07-10.
  3. Web site: Boehmite. Mindat with location data. 2010-07-10.
  4. http://rruff.geo.arizona.edu/doclib/hom/bohmite.pdf Mineral Data Pub. Handbook of Mineralogy
  5. Web site: The Mineral Boehmite. minerals.net. June 10, 2014.
  6. Natural boehmite single crystals from Ceylon. Contributions to Mineralogy and Petrology. 39. 2. 171. 1973. 1973CoMP...39..171S. Sahama. Th. G.. Lehtinen. Martti. Rehtijärvi. Pentti. 10.1007/BF00375738. 129237343.
  7. 10.1002/zaac.19251490114. Über Aluminium- und Eisenhydroxyde. I. Zeitschrift für anorganische und allgemeine Chemie. 149. 203–216. 1925. Böhm. J..