Beta helix explained

A beta helix is a tandem protein repeat structure formed by the association of parallel beta sheet in a helical pattern with either two[1] or three[2] faces. The beta helix is a type of solenoid protein domain. The structure is stabilized by inter-strand hydrogen bonds, protein-protein interactions, and sometimes bound metal ions. Both left- and right-handed beta helices have been identified. These structures are distinct from jelly-roll folds, a different protein structure sometimes known as a "double-stranded beta helix".[3] [4]

The first beta-helix was observed in the enzyme pectate lyase, which contains a seven-turn helix that reaches 34 Å (3.4 nm) long. The P22 phage tail spike protein, a component of the P22 bacteriophage, has 13 turns and in its assembled homotrimer is 200 Å (20 nm) in length. Its interior is close-packed with no central pore and contains both hydrophobic residues and charged residues neutralized by salt bridges.

Both pectate lyase and P22 tailspike protein contain right-handed helices; left-handed versions have been observed in enzymes such as UDP-N-acetylglucosamine acyltransferase and archaeal carbonic anhydrase.[5] Other proteins that contain beta helices include the antifreeze proteins from the beetle Tenebrio molitor (right-handed)[6] and from the spruce budworm, Choristoneura fumiferana (left-handed),[7] where regularly spaced threonines on the β-helices bind to the surface of ice crystals and inhibit their growth.

Beta helices can associate with each other effectively, either face-to-face (mating the faces of their triangular prisms) or end-to-end (forming hydrogen bonds). Hence, β-helices can be used as "tags" to induce other proteins to associate, similar to coiled coil segments.

Members of the pentapeptide repeat family have been shown to possess a quadrilateral beta-helix structure.[8]

External links

Notes and References

  1. Web site: CATH database - folds and homologous superfamilies within the beta 2-solenoid architecture.. CATH database.
  2. Web site: CATH database - folds and homologous superfamilies within the beta 3-solenoid architecture.. https://web.archive.org/web/20110726124637/http://www.cathdb.info/cathnode/2.160. 26 July 2011. dead. CATH database.
  3. Aik . WeiShen . McDonough . Michael A . Thalhammer . Armin . Chowdhury . Rasheduzzaman . Schofield . Christopher J . Role of the jelly-roll fold in substrate binding by 2-oxoglutarate oxygenases . Current Opinion in Structural Biology . December 2012 . 22 . 6 . 691–700 . 10.1016/j.sbi.2012.10.001. 23142576 .
  4. Web site: Double-stranded beta-helix . SCOPe . 29 November 2021.
  5. Kisker C, Schindelin H, Alber BE, Ferry JG, Rees DC . A left-hand beta-helix revealed by the crystal structure of a carbonic anhydrase from the archaeon Methanosarcina thermophila . EMBO J. . 15 . 10 . 2323–30 . May 1996 . 8665839 . 450161 . 10.1002/j.1460-2075.1996.tb00588.x.
  6. Liou YC, Tocilj A, Davies PL, Jia Z . Mimicry of ice structure by surface hydroxyls and water of a beta-helix antifreeze protein . Nature . 406 . 6793 . 322–4 . July 2000 . 10917536 . 10.1038/35018604 . 2000Natur.406..322L . 4385352 .
  7. Leinala EK, Davies PL, Jia Z . Crystal structure of beta-helical antifreeze protein points to a general ice binding model . Structure . 10 . 5 . 619–27 . May 2002 . 12015145 . 10.1016/s0969-2126(02)00745-1. free .
  8. Vetting MW, Hegde SS, Fajardo JE . Pentapeptide repeat proteins . Biochemistry . 45 . 1 . 1–10 . January 2006 . 16388575 . 2566302 . 10.1021/bi052130w . etal.