Barium bromide is the chemical compound with the formula BaBr2. It is ionic and hygroscopic in nature.
BaBr2 crystallizes in the lead chloride (cotunnite) motif, giving white orthorhombic crystals that are deliquescent.[1]
| Ion | Ba2+ | Br- (tetrahedral) | Br- (trigonal) | |
|---|---|---|---|---|
| Coordination sphere | ||||
| Ball-and-stick model | ||||
| Coordination number | 9 | 4 | 3 | |
| Coordination geometry | (7+2) coordination distorted tricapped trigonal prismatic | distorted tetrahedral | trigonal pyramidal |
In aqueous solution BaBr2 behaves as a simple salt.
Solutions of barium bromide reacts with the sulfate salts to produce a solid precipitate of barium sulfate.
BaBr2 + → BaSO4 + 2 Br−Similar reactions occur with oxalic acid, hydrofluoric acid, and phosphoric acid, giving solid precipitates of barium oxalate, fluoride, and phosphate, respectively.
Barium bromide can be prepared by treating barium sulfide or barium carbonate with hydrobromic acid:
BaS + 2 HBr → BaBr2 + H2S
BaCO3 + 2 HBr → BaBr2 + CO2 + H2OBarium bromide crystallizes from concentrated aqueous solution in its dihydrate, BaBr2·2H2O. Heating this dihydrate to 120 °C gives the anhydrous salt.
Barium bromide is a precursor to chemicals used in photography and to other bromides.
Historically, barium bromide was used to purify radium in a process of fractional crystallization devised by Marie Curie. Since radium precipitates preferentially in a solution of barium bromide, the ratio of radium to barium in the precipitate would be higher than the ratio in the solution.
Barium bromide, along with other water-soluble barium salts (e.g. barium chloride), is toxic. However, there is no conclusive data available on its hazards.[4]
The compound appears in the intro title card of Breaking Bad, where the first pairs of letters are replaced with Br35 and Ba56, the symbols and atomic numbers of bromine and barium respectively.
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