Arsenuranospathite Explained

Arsenuranospathite (IMA symbol: Aush[1]) is a rare mineral with the chemical formula Al(UO2)2(AsO4)2F·20H2O.[2] The name "arsenuranospathite" as arsenate analog of uranospathite was first used by Walenta (1963)[3] with reference to a uranyl-arsenate mineral from Black Forest (Schwarzwald) massif, Germany. Later it was undoubtedly demonstrated that the name arsenuranospathite was applied, at least, to two different species – proper arsenuranospathite, ideally Al(UO2)2(AsO4)2F·20H2O, orthorhombic, and its partially dehydrated analogue, Al(UO2)2(AsO4)2F·nH2O (n = 8–10), tetragonal or pseudo-tetragonal.

Properties

Yellow to yellow-greenish, transparent to opaque tabular and prismatic crystals, with perfect cleavage. Transparent to translucent. Hardness = ~2. Radioactive.[4]

Chemical composition

Contents of Al and U are very stable (1±0.05 and 2±0.07 atoms per As+P+U = 4 apfu respectively). Main variations of chemical compositions are connected with the ratio As:P and the content of F.

Occurrences

Sophia Mine, Böckelsbach valley, Wittichen, Schenkenzell, Black Forest, Baden-Württemberg, Germany

Notes and References

  1. Warr. L.N.. 2021. IMA-CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. Web site: Arsenuranospathite, Al(UO2)2(ASO) 2F·20OH2O: Formula revision and relationships with allied uranyl arsenates and phosphates. Chukanov . etal. N.V..
  3. Uranospathite and arsenuranospathite. Mineralogical Magazine. 42. 321. 117–128. 10.1180/minmag.1978.042.321.18. 1978. Walenta. Kurt. 1978MinM...42..117W. 128830032 .
  4. Web site: Arsenuranospathite . 4 October 2023. Handbook of Mineralogy.