Arsenide nitride explained
Arsenide nitrides or nitride arsenides are compounds containing anions composed of nitride (N3−) and arsenide (As3−). They can be considered as mixed anion compounds or mixed pnictide compounds. Related compounds include the arsenide phosphides, germanide arsenides, arsenide carbides, and phosphide nitrides.
Arsenide and nitride are quite different in size, so alloys are challenging to produce.[1] They can be produced by heating an arsenide compound with a nitride, under pressure so that nitrogen does not escape.
List
| name | formula | crystalsystem | space group | unit cell Å | volume | density | comment | ref |
|---|
| Mg3AsN | cubic | Pmm | a =4.2148 Z=1 | 74.88 | 3.589 | orange | [2] |
| Ca3AsN | orthorhombic | Pbnm | a=6.725 b=6.7198 c=9.5335 Z=4 | 430.8 | 3.237 | red; moisture sensitive | [3] |
| Ca14As6C0.445N1.135H4.915 | | P4/mbm | a = 15.749 c = 9.1062 | | | red; band gap 1.6 eV | [4] |
| Cr3AsN | tetragonal | I4/mcm | a=5.360 c=8.066 | | | | [5] [6] |
| gallium arsenide nitride | Ga(As,N) | | | | | | | |
| indium gallium arsenide nitride | (In,Ga)(As,N) | | | | | | | |
| aluminium gallium arsenide nitride | (Al,Ga)(As,N) | | | | | | | |
| Sr3AsN | orthorhombic | Pbnm | a=7.1856 b=10.1446 c=7.1464 Z=4 | 520.93 | 4.486 | dark grey | |
| Ba3AsN | orthorhombic | Pbnm | a=7.6741 b=10.7573 c=7.5387 Z=4 | 622.33 | 5.347 | black | |
| LaFe2AsN | orthorhombic | Cmcm | a =3.79932 b =11.11461 c =7.18656 | 303.474 | | | [7] |
| LaCo2AsN | orthorhombic | Cmcm | a =3.75993 b =11.1674 c =7.0185 | 294699 | | | |
| LaNi2AsN | orthorhombic | Cmcm | a =3.71584 b =11.4147 c =6.9786 | 296.004 | | | |
| Th2ONAs | | Pm1 | a=4.041 c=6.979 | | | | [8] |
| ThCrAsN | | | | | | metallic | [9] |
| ThMnAsN | tetragonal | P4/nmm | a =4.0818 b =4.0818 c =8.947 | | | metallic | [10] |
| ThFeAsN | tetragonal | P4/nmm | a = 4.0367 c = 8.5262 | | | superconductor Tc 30 K | [11] |
| ThFe1-xCoxAsN | | | | | | superconductivity lost for x>0.05 | [12] |
| ThNiAsN | tetragonal | P4/nmm | a=4,0804 c=7.9888 | | | superconductor at 4.3K | [13] |
| BaTh2Fe4As4(N0.7O0.3)2 | | | a=3.9886 c=29.853 | | | Tc 22K | [14] |
| U2N2As | | Pm1 | a=3.833 c=6.737 | | | | | |
Notes and References
- Book: Toivonen. J.. Oila. J.. Saarinen. K.. Hakkarainen. T.. Sopanen. M.. Lipsanen. H.. Conference Proceedings. 14th Indium Phosphide and Related Materials Conference (Cat. No.02CH37307) . Vacancy-type defects in GaAsN grown by metalorganic vapor phase epitaxy . 2002. https://ieeexplore.ieee.org/document/1014345. Stockholm, Sweden. IEEE. 245–248. 10.1109/ICIPRM.2002.1014345. 978-0-7803-7320-4. 122733148 .
- Stoiber . Dominik . Niewa . Rainer . 2019-02-15 . Perovskite Distortion Inverted: Crystal Structures of (A 3 N)As (A = Mg, Ca, Sr, Ba): Perovskite Distortion Inverted: Crystal Structures of (A 3 N)As (A = Mg, Ca, Sr, Ba) . Zeitschrift für anorganische und allgemeine Chemie . en . 645 . 3 . 329–334 . 10.1002/zaac.201800295. 219878132 .
- Chern . Ming Y. . Disalvo . F.J. . Parise . J.B. . Goldstone . Joyce A. . February 1992 . The structural distortion of the anti-perovskite nitride Ca3AsN . Journal of Solid State Chemistry . en . 96 . 2 . 426–435 . 10.1016/S0022-4596(05)80277-4. 1992JSSCh..96..426C . free .
- Blankenship . Trevor V. . Wang . Xiaoping . Hoffmann . Christina . Latturner . Susan E. . 2014-10-06 . LiCa 3 As 2 H and Ca 14 As 6 X 7 (X = C, H, N): Two New Arsenide Hydride Phases Grown from Ca/Li Metal Flux . Inorganic Chemistry . en . 53 . 19 . 10620–10626 . 10.1021/ic501722d . 25222291 . 0020-1669.
- Waki . Takeshi . Takao . Kenta . Tabata . Yoshikazu . Ohta . Hiroto . Yajima . Takeshi . Hiroi . Zenji . Nakamura . Hiroyuki . Possible Itinerant-Electron Canted Antiferromagnetism in Tetragonal Antiperovskite Cr 3 AsN . Journal of the Physical Society of Japan . 15 October 2017 . 86 . 10 . 104706 . 10.7566/JPSJ.86.104706. 2017JPSJ...86j4706W .
- Boller . H. . Komplexcarbide und-nitride mit aufgefülltem U3Si-Typ . Monatshefte für Chemie . 1968 . 99 . 6 . 2444–2449 . 10.1007/BF01154362. 97266394 .
- Jeong . Sehoon . Matsuishi . Satoru . Bang . Joonho . Hosono . Hideo . 2015-04-01 . Crystal structure and physical properties of new transition metal based pnictide compounds: La TM 2AsN (TM = Fe, Co, and Ni) . APL Materials . en . 3 . 4 . 041509 . 10.1063/1.4913395 . 2015APLM....3d1509J . 2166-532X. free .
- Benz . R. . Zachariasen . W. H. . 1969-02-15 . Crystal structure of the compounds U2N2X and Th2(N,O)2 with X = P, S, As and Se . Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry . 25 . 2 . 294–296 . 10.1107/S0567740869002135.
- Wang . Zhi-Cheng . Shao . Ye-Ting . Lin . Yi-Qiang . Song . Shi-Jie . Li . Bai-Zhuo . Cheng . Er-Jian . Li . Shi-Yan . Zhu . Qin-Qing . Ren . Zhi . Cao . Guang-Han . 2023-08-09 . Absence of superconductivity in electron-doped chromium pnictides ThCrAsN 1 − x O x . Physical Review B . en . 108 . 6 . 064503 . 10.1103/PhysRevB.108.064503 . 2308.05267 . 2023PhRvB.108f4503W . 260775924 . 2469-9950.
- Zhang . Fuxiang . Li . Baizhuo . Ren . Qingyong . Mao . Huican . Xia . Yuanhua . Hu . Bingfeng . Liu . Zichen . Wang . Zhicheng . Shao . Yeting . Feng . Zhifa . Tan . Shugang . Sun . Yuping . Ren . Zhi . Jing . Qiang . Liu . Bo . 2020-03-02 . ThMnPnN (Pn = P, As): Synthesis, Structure, and Chemical Pressure Effects . Inorganic Chemistry . en . 59 . 5 . 2937–2944 . 10.1021/acs.inorgchem.9b03294 . 32064866 . 211133783 . 0020-1669.
- Wang . Cao . Wang . Zhi-Cheng . Mei . Yu-Xue . Li . Yu-Ke . Li . Lin . Tang . Zhang-Tu . Liu . Yi . Zhang . Pan . Zhai . Hui-Fei . Xu . Zhu-An . Cao . Guang-Han . 2016-02-24 . A New ZrCuSiAs-Type Superconductor: ThFeAsN . Journal of the American Chemical Society . en . 138 . 7 . 2170–2173 . 10.1021/jacs.6b00236 . 26853632 . 1603.01501 . 5393656 . 0002-7863.
- Wang . Jingfeng . Jiao . Fei . Wang . Xianyu . Zhu . Shu . Cai . Lingbo . Yang . Chunhui . Song . Pengwei . Zhang . Fuxiang . Li . Baizhuo . Li . Yunlong . Hu . Jiayuan . Li . Shubin . Li . Yuqiang . Tan . Shugang . Mei . Yuxue . 2020-07-21 . The phase transition of ThFe 1-x Co x AsN from superconductor to metallic paramagnet . EPL (Europhysics Letters) . 130 . 6 . 67003 . 10.1209/0295-5075/130/67003 . 2020EL....13067003W . 225558397 . 1286-4854.
- Wang . Zhi-Cheng . Shao . Ye-Ting . Wang . Cao . Wang . Zhen . Xu . Zhu-An . Cao . Guang-Han . 2017-06-01 . Enhanced superconductivity in ThNiAsN . EPL (Europhysics Letters) . 118 . 5 . 57004 . 10.1209/0295-5075/118/57004 . 2017EL....11857004W . 125752599 . 0295-5075.
- Shao . Ye-Ting . Wang . Zhi-Cheng . Li . Bai-Zhuo . Wu . Si-Qi . Wu . Ji-Feng . Ren . Zhi . Qiu . Su-Wen . Rao . Can . Wang . Cao . Cao . Guang-Han . September 2019 . BaTh$_2$Fe$_4$As$_4$(N$_$O$_$)$_2$: An Iron-Based Superconductor Stabilized by Inter-Block-Layer Charge Transfer . Science China Materials . 62 . 9 . 1357–1362 . 10.1007/s40843-019-9438-7 . 1908.03992 . 164224680 . 2095-8226.
