In organic chemistry, an aminal or aminoacetal is a functional group or type of organic compound that has two amine groups attached to the same carbon atom: . (As is customary in organic chemistry, R can represent hydrogen or an alkyl group). A common aminal is bis(dimethylamino)methane, a colorless liquid that is prepared by the reaction of dimethylamine and formaldehyde:[1]
Aminals are encountered in, for instance, the Fischer indole synthesis. Several examples exist in nature.[2]
Hexahydro-1,3,5-triazine, an intermediate in the condensation of formaldehyde and ammonia, tends to degrade to hexamethylene tetraamine.
Cyclic aminals can be obtained by the condensation of a diamine and an aldehyde.[3] Imidazolidines are one class of these cyclic aminals.