Ambroxol Explained

Ambroxol is a drug that breaks up phlegm, used in the treatment of respiratory diseases associated with viscid or excessive mucus. Ambroxol is often administered as an active ingredient in cough syrup.

It was patented in 1966 and came into medical use in 1979.[1]

Medical uses

Ambroxol is indicated as "secretolytic therapy in bronchopulmonary diseases associated with abnormal mucus secretion and impaired mucus transport. It promotes mucus clearance, facilitates expectoration and eases productive cough, allowing patients to breathe freely and deeply".

There are many different formulations developed since the first marketing authorisation in 1978. Ambroxol is available as syrup, tablets, pastilles, dry powder sachets, inhalation solution, drops and ampules as well as effervescent tablets.

Ambroxol also provides pain relief in acute sore throat. Pain in sore throat is the hallmark of acute pharyngitis.[2] Sore throat is usually caused by a viral infection. The infection is self limited and the patient recovers normally after a few days. What is most bothering for the patient is the continuous pain in the throat maximized when the patient is swallowing. The main goal of treatment is thus to reduce pain. The main property of ambroxol for treating sore throat is the local anaesthetic effect, described first in the late 1970s,[3] [4] but explained and confirmed in more recent work.

High-dose ambroxol, delivered via intravenous injection, reduces the mortality rate in paraquat poisoning by 31%.[5]

Side effects

Studies and observations to date have not uncovered specific contraindications of ambroxol; however, caution is suggested for patients with gastric ulceration, and usage during the first trimester of pregnancy is not recommended.[6]

Mechanism of action

The substance acts on mucus membranes, restoring the physiological clearance mechanisms of the respiratory tract (which play an important role in the body's natural defence mechanisms) through several mechanisms, including breaking up phlegm, stimulating mucus production, and stimulating synthesis and release of surfactant by type II pneumocytes.[7] [8] Surfactant acts as an anti-glue factor by reducing the adhesion of mucus to the bronchial wall, in improving its transport and in providing protection against infection and irritating agents.[9] [10]

Ambroxol is a potent inhibitor of the neuronal Na+ channels, explaining its anaesthetic effect.[11] This property led to the development of a lozenge containing 20 mg of ambroxol. Many state-of-the-art clinical studies[2] have demonstrated the efficacy of ambroxol in relieving pain in acute sore throat, with a rapid onset of action, with its effect lasting at least three hours.

Ambroxol is also anti-inflammatory, reducing redness in a sore throat. It reduces the release of inflammatory cytokines and histamines in cell cultures. It also acts as an antioxidant, scavenging free radicals and hypochloric acid generated by neutrophils.[12] These two effects explain its effect in treating acute lung injury caused by paraquat.[5]

Ambroxol has recently been shown to increase activity of the lysosomal enzyme glucocerebrosidase. Because of this it may be a useful therapeutic agent for both Gaucher disease and Parkinson's disease.[13] It was also recently shown that ambroxol triggers exocytosis of lysosomes by releasing calcium from acidic cellular calcium stores. This occurs by diffusion of ambroxol into lysosomes and lysosomal pH neutralization.[8] This mechanism is most likely responsible for the mucolytic effects of the drug, but may also explain the reported activity in Gaucher and Parkinson's disease.

Both ambroxol and its parent drug bromhexine have been shown to induce autophagy in several cell types, and ambroxol was shown to potentiate rifampicin therapy in a model of tuberculosis through host directed effects.[14] [15] Ambroxol also enhances lung levels of a wide range of antibiotics.[16]

Brand names

Ambroxol is the active ingredient of Muciclar (Italy), Mucosolvan, Mucobrox (Spain), Bisolvon (Switzerland), Cloxan (Mexico), Mucol, Lasolvan, Mucoangin, Surbronc, Brontex (Lithuania), Ambro (Kazakhstan), Ambolar, Inhalex, Mucolite (India), Fluibrox (Greece) and Lysopain.[17] Despite approval of ambroxol as a safe and effective substance in the European Medicines Agency, ambroxol has not been approved in the USA by the Food and Drug Administration. [18] Ambroxol is also not registered for use in Australia. [19]

Notes and References

  1. Book: Fischer J, Ganellin CR . Analogue-based Drug Discovery . 2006 . John Wiley & Sons . 9783527607495 . 544 . en.
  2. de Mey C, Peil H, Kölsch S, Bubeck J, Vix JM . Efficacy and safety of ambroxol lozenges in the treatment of acute uncomplicated sore throat. EBM-based clinical documentation . Arzneimittel-Forschung . 58 . 11 . 557–68 . 2008 . 19137906 . 10.1055/s-0031-1296557 . 10201086 .
  3. Püschmann S, Engelhorn R . [Pharmacological study on the bromhexine metabolite ambroxol (author's transl)] . Arzneimittel-Forschung . 28 . 5a . 889–98 . 1978 . 581987 .
  4. Klier KF, Papendick U . [The local anesthetic effect of NA872-containing eyedrops] . Medizinische Monatsschrift . 31 . 12 . 575–8 . December 1977 . 593223 .
  5. Wang J, Yu W, Wu N, Gitonga EN, Shen H . Efficacy of high-dose ambroxol for paraquat poisoning: A meta-analysis of randomized controlled trials . Journal of Research in Medical Sciences . 25 . 1 . 67 . 2020 . 33088304 . 7554424 . 10.4103/jrms.JRMS_484_19 . free .
  6. Web site: Ambroxol . Drugs.com . 21 January 2014 .
  7. Seifart C, Clostermann U, Seifart U, Müller B, Vogelmeier C, von Wichert P, Fehrenbach H . Cell-specific modulation of surfactant proteins by ambroxol treatment . Toxicology and Applied Pharmacology . 203 . 1 . 27–35 . February 2005 . 15694461 . 10.1016/j.taap.2004.07.015 .
  8. Fois G, Hobi N, Felder E, Ziegler A, Miklavc P, Walther P, Radermacher P, Haller T, Dietl P . A new role for an old drug: Ambroxol triggers lysosomal exocytosis via pH-dependent Ca²⁺ release from acidic Ca²⁺ stores . Cell Calcium . 58 . 6 . 628–37 . December 2015 . 26560688 . 10.1016/j.ceca.2015.10.002 .
  9. Sanderson RJ, Paul GW, Vatter AE, Filley GF . Morphological and physical basis for lung surfactant action . Respiration Physiology . 27 . 3 . 379–92 . September 1976 . 989610 . 10.1016/0034-5687(76)90066-9 .
  10. Kido H, Okumura Y, Yamada H, Mizuno D, Higashi Y, Yano M . Secretory leukoprotease inhibitor and pulmonary surfactant serve as principal defenses against influenza A virus infection in the airway and chemical agents up-regulating their levels may have therapeutic potential . Biological Chemistry . 385 . 11 . 1029–34 . November 2004 . 15576322 . 10.1515/bc.2004.133 . 43633056 .
  11. Weiser T . Comparison of the effects of four Na+ channel analgesics on TTX-resistant Na+ currents in rat sensory neurons and recombinant Nav1.2 channels . Neuroscience Letters . 395 . 3 . 179–84 . March 2006 . 16293367 . 10.1016/j.neulet.2005.10.058 . 45844891 .
  12. Malerba M, Ragnoli B . Ambroxol in the 21st century: pharmacological and clinical update . Expert Opinion on Drug Metabolism & Toxicology . 4 . 8 . 1119–1129 . August 2008 . 18680446 . 10.1517/17425255.4.8.1119 .
  13. McNeill A, Magalhaes J, Shen C, Chau KY, Hughes D, Mehta A, Foltynie T, Cooper JM, Abramov AY, Gegg M, Schapira AH . Ambroxol improves lysosomal biochemistry in glucocerebrosidase mutation-linked Parkinson disease cells . Brain . 137 . Pt 5 . 1481–95 . May 2014 . 24574503 . 3999713 . 10.1093/brain/awu020 .
  14. Choi SW, Gu Y, Peters RS, Salgame P, Ellner JJ, Timmins GS, Deretic V . Ambroxol Induces Autophagy and Potentiates Rifampin Antimycobacterial Activity . Antimicrobial Agents and Chemotherapy . 62 . 9 . AAC.01019–18 . September 2018 . 30012752 . 6125555 . 10.1128/AAC.01019-18 . free .
  15. Chauhan S, Ahmed Z, Bradfute SB, Arko-Mensah J, Mandell MA, Won Choi S, Kimura T, Blanchet F, Waller A, Mudd MH, Jiang S, Sklar L, Timmins GS, Maphis N, Bhaskar K, Piguet V, Deretic V . Pharmaceutical screen identifies novel target processes for activation of autophagy with a broad translational potential . Nature Communications . 6 . 8620 . October 2015 . 26503418 . 4624223 . 10.1038/ncomms9620 . 2015NatCo...6.8620C .
  16. Deretic V, Timmins GS . Enhancement of lung levels of antibiotics by ambroxol and bromhexine . Expert Opinion on Drug Metabolism & Toxicology . 15 . 3 . 213–8 . March 2019 . 30721101 . 6947664 . 10.1080/17425255.2019.1578748 .
  17. 6 May 2024 . Ambroxol (International) . Drugs.com . 2024-05-29 . Drugs.com.
  18. 14 November 2023 . The Next Insulin Scandal . Health and Social Policy . 2024-05-29 . The American Prospect.
  19. June 2016 . Bromhexine-containing cough and cold medicines – risk of allergy and skin reactions . Medicines Safety Update . 7 . 3 . 2023-05-09 . Therapeutic Goods Administration.