Allylamine Explained

Allylamine is an organic compound with the formula C3H5NH2. This colorless liquid is the simplest stable unsaturated amine.

Production and reactions

All three allylamines, mono-, di-, and triallylamine, are produced by the treating allyl chloride with ammonia followed by distillation.[1] Or by the reaction of allyl chloride with hexamine.[2] Pure samples can be prepared by hydrolysis of allyl isothiocyanate.[3] It behaves as a typical amine.[4]

Polymerization can be used to prepare the homopolymer (polyallylamine) or copolymers. The polymers are promising membranes for use in reverse osmosis.[1]

Other allylamines

Diallylamine is a precursor to industrial products. Functionalized allylamines have pharmaceutical applications. Pharmaceutically important allylamines include flunarizine and naftifine; the latter spurred the development of Petasis' borono-Mannich reaction. Flunarizine aids in the relief of migraines while naftifine acts to fight common fungus causing infections such as athlete's foot, jock itch, and ringworm.[5]

Safety

Allylamine, like other allyl derivatives is a lachrymator and skin irritant. Its oral is 106 mg/kg for rats.

External links

Notes and References

  1. Encyclopedia: Ludger Krähling. Jürgen Krey. Gerald Jakobson. Johann Grolig. Leopold Miksche. Allyl Compounds. Ullmann's Encyclopedia of Industrial Chemistry. 2002. Wiley-VCH. Weinheim. 10.1002/14356007.a01_425. 3527306730.
  2. Web site: Synthesis of allylamine in ethanol. 2020-06-30. ResearchGate. en.
  3. Organic Syntheses . M. T. Leffler . Allylamine . 18 . 5 . 1938 . 10.15227/orgsyn.018.0005.
  4. Henk de Koning, W. Nico Speckamp "Allylamine" in Encyclopedia of Reagents for Organic Synthesis, 2001, John Wiley & Sons, Weinheim. Article Online Posting Date: April 15, 2001
  5. Beck. John F.. Samblanet, Danielle C.. Schmidt, Joseph A. R.. Palladium catalyzed intermolecular hydroamination of 1-substituted allenes: an atom-economical method for the synthesis of N-allylamines. RSC Advances. 1 January 2013. 3. 43. 20708. 10.1039/c3ra43870h. 2013RSCAd...320708B.