Zinc nitrate explained

Zinc nitrate is an inorganic chemical compound with the formula . This colorless, crystalline salt is highly deliquescent. It is typically encountered as a hexahydrate . It is soluble in both water and alcohol.

Synthesis

Zinc nitrate is usually prepared by dissolving zinc metal, zinc oxide, or related materials in nitric acid:

These reactions are accompanied by the hydration of the zinc nitrate.

The anhydrous salt arises by the reaction of anhydrous zinc chloride with nitrogen dioxide:

Reactions

Treatment of zinc nitrate with acetic anhydride gives zinc acetate.[1]

On heating, zinc nitrate undergoes thermal decomposition to form zinc oxide, nitrogen dioxide and oxygen:

Aqueous zinc nitrate contains aquo complexes .[2] and, thus, this reaction may be better written as the reaction of the aquated ion with hydroxide through donation of a proton, as follows.

Applications

Zinc nitrate has no large scale application but is used on a laboratory scale for the synthesis of coordination polymers.[3] Its controlled decomposition to zinc oxide has also been used for the generation of various ZnO based structures, including nanowires.[4]

It can be used as a mordant in dyeing. An example reaction gives a precipitate of zinc carbonate:

Notes and References

  1. Book: O. F. Wagenknecht. R. Juza. Zinc Acetate. Handbook of Preparative Inorganic Chemistry, 2nd Ed. . G. Brauer. Academic Press. 1963. NY, NY. 2. 1087.
  2. Sze, Yu-Keung, and Donald E. Irish. "Vibrational spectral studies of ion-ion and ion-solvent interactions. I. Zinc nitrate in water." Journal of Solution Chemistry 7.6 (1978): 395-415.
  3. Barnett. Sarah A. Champness. Neil R. Structural diversity of building-blocks in coordination framework synthesis—combining M(NO3)2 junctions and bipyridyl ligands. Coordination Chemistry Reviews. November 2003. 246. 1–2. 145–168. 10.1016/S0010-8545(03)00121-8.
  4. Greene. Lori E.. Yuhas. Benjamin D.. Law. Matt. Zitoun. David. Yang. Peidong. Solution-Grown Zinc Oxide Nanowires. Inorganic Chemistry. September 2006. 45. 19. 7535–7543. 10.1021/ic0601900. 16961338 .