Waterhouseite Explained

Waterhouseite
Category:Phosphate mineral
Formula:Mn7(PO4)2(OH)8
Imasymbol:Whs[1]
Strunz:8.BE.85
System:Monoclinic
Class:Prismatic (2/m)
(same H-M symbol)
Symmetry:P21/b
Unit Cell:a = 11.364 Å, b = 5.57 Å
c = 10.455 Å; β = 96.61°; Z = 2
Color:Orange-brown to dark brown
Habit:Bladed crystals
Twinning:Contact twins on
Cleavage:Perfect on, indistinct on
Fracture:Conchoidal
Tenacity:Brittle
Mohs:4
Luster:Vitreous, Pearly on cleavages
Streak:Yellowish Brown
Diaphaneity:Transparent
Gravity:3.55
Opticalprop:Biaxial (-)
Refractive:nα = 1.730
nβ = 1.738
nγ = 1.738
Birefringence:δ = 0.008
Dispersion:absent
References:[2] [3]

Waterhouseite, Mn7(PO4)2(OH)8, is a hydroxy manganese phosphate mineral. It is a medium-soft, brittle mineral occurring in pseudo-orthorhombic monoclinic bladed crystals and orange-brown to dark brown in color. Waterhouseite is on the softer side with a Mohs hardness of 4, has a specific gravity of 3.5 and a yellowish-brown streak. It is named after Frederick George Waterhouse, first director of the South Australian Museum, as well as recognizes the work Waterhouse Club has done in support of the South Australian Museum.[4]

Occurrence

Waterhouseite occurs in divergent sprays of bladed crystals up to 1mm in length and 20 micrometers in thickness.

It is found in South Australia, specifically in the Iron Monarch mine, Iron Knob, Middleback Range, Eyre Peninsula, South Australia.

Waterhouseite is generally found in a carbonate rich cavities with other minerals such as gatehouseite, seamanite, rhodochrosite, shigaite, baryte, hausmannite and hematite.

Crystal structure

Waterhouseite has a unique asymmetrical structure consisting of a dense, complex framework of Mn(O, OH)6 octahedra and PO4 tetrahedra which are linked by both edges and corners. It is highly unusual for the PO4 tetrahedron to share two of its edges with the Mn(O, OH)6 octahedral. There are only two other known arsenates that have the same edge sharing as waterhouseite.

See also

External links

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. http://www.mindat.org/min-27485.html Mindat.org: Waterhouseite
  3. http://webmineral.com/data/Waterhouseite.shtml#.VlTnL-KnDfY Waterhouseite data on Webmineral.com
  4. Pring. Allan. Description and unique crystal structure of waterhouseite, a new hydroxy manganese phosphate from the Iron Monarch deposit, Middleback Ranges, South Australia. The Canadian Mineralogist. 2005. 43. 1401–1410. 10.2113/gscanmin.43.4.1401. 25 November 2015.