Wakefieldite Explained

Wakefieldite
Category:Rare-earth mineral
Formula:
Imasymbol:Wf[1]
Strunz:8.AD.35
System:Tetragonal
Class:Ditetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Symmetry:I41/amd
Color:Canary-yellow, pale tan (Wakefieldite-(Y)); Dark red to coal-black, pale yellow to bluish gray (Wakefieldite-(Ce)); Light pink, brown (Wakefieldite-(La)
Habit:Prismatic crystals, pulverulent masses
Cleavage:Good on
Tenacity:Very brittle
Mohs:4–5
Diaphaneity:Translucent to opaque
Gravity:4.25 (calculated Wakefieldite-(Y)); 4.74 (meas. Wakefieldite-(Ce)
Opticalprop:Uniaxial (+)
Refractive:nω = 2.000, nε = 2.140

Wakefieldite is an uncommon rare-earth element vanadate mineral. There are four main types described of wakefieldite- wakefieldite-(La), wakefieldite-(Ce), wakefieldite-(Nd), and wakefieldite-(Y), depending upon the dominant rare-earth metal ion present. Wakefieldite has a Mohs hardness ranging from 4 to 5.[2] Wakefieldite forms crystals of tetragonal structure. In terms of crystal structure, it is the vanadate analog of the rare-earth phosphate mineral xenotime. Unlike xenotime, it is more favorable for wakefieldite to contain the lighter rare-earth elements over the heavier ones. Due to the lanthanide contraction, the heavier rare earths have smaller ionic radii than the lighter ones. When the phosphate anion is replaced by the larger vanadate anion, the tetragonal crystal system preferentially accommodates the larger light rare-earth elements.[3]

Wakefieldite was first described for an occurrence in the Evans Lou mine, St. Pierre de Wakefield, Quebec, Canada[4] and later designated Wakefieldite-(Y).[5]

Notes and References

  1. Warr. L.N.. 2021. IMA–CNMNC approved mineral symbols. Mineralogical Magazine. 85. 3. 291–320. 10.1180/mgm.2021.43. 2021MinM...85..291W. 235729616. free.
  2. The Mineral and Locality Database, Wakefieldite-(La).
  3. Miyawaki R., and I. Nakai. (1996). "Crystal Chemical Aspects of Rare Earth Minerals". Ed. Andrian P. Jones, Frances Wall, and C. Terry Williams. Rare Earth Minerals: Chemistry, Origin and Ore Deposits. London: Chapman & Hall. (p. 29–30).
  4. Miles, Norman M., et al., Wakefieldite, Yttrium Vanadate, a New Mineral From Quebec, American Mineralogist, Vol. 56, Mar.–Apr. 1971.
  5. http://www.mindat.org/min-4234.html Mindat, Wakefieldite-(Y)