Technetium(VII) sulfide explained

Technetium(VII) sulfide is a binary inorganic chemical compound of technetium metal and sulfur with the chemical formula .^{[1] [2] [3] [4]}

Synthesis

Passing hydrogen sulfide through acidic solutions of pertechnetates:^{[5] [6] [7]}

Chemical properties

It is restored by hydrogen at 1000 °C:

Notes and References

1. Saiki . Y. . Fukuzaki . M. . Sekine . T. . Kino . Y. . Kudo . H. . [No title found] ]. . 2003 . 255 . 1 . 101–104 . 10.1023/A:1022283831945 . 23 July 2024.
2. Book: Zolle . Ilse . Technetium-99m Pharmaceuticals: Preparation and Quality Control in Nuclear Medicine . 28 January 2007 . . 978-3-540-33990-8 . 207 . 23 July 2024 . en.
3. Book: Advances in Inorganic Chemistry and Radiochemistry . 1968 . . 978-0-08-057860-6 . 72 . 23 July 2024 . en.
4. Cohen . M. B. . Spolter . L. . Szymendera . J. . Radwan . M. . Rhenium and technetium heptasulfide . Journal of Nuclear Medicine. April 1972 . 13 . 4 . 287–288 . 5011784 . 23 July 2024 . 0161-5505.
5. Book: Boschke . Friedrich L. . Inorganic Chemistry . 31 December 1981 . . 978-3-11-270829-3 . 131 . 23 July 2024 . en.
6. Web site: CharChem. Technetium(VII) sulfide . easychem.org . 23 July 2024.
7. Poineau . Frederic . Burton-Pye . Benjamin P. . Sattelberger . Alfred P. . Czerwinski . Kenneth R. . German . Konstantin E. . Fattahi . Massoud . Speciation and reactivity of heptavalent technetium in strong acids . . 2018 . 42 . 10 . 7522–7528 . 10.1039/c7nj04912a . 23 July 2024.